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MOLYBDENUM(V) CHLORIDE

Physical Properties Preparation
MOLYBDENUM(V) CHLORIDE
MOLYBDENUM(V) CHLORIDE structure
CAS No.
10241-05-1
Chemical Name:
MOLYBDENUM(V) CHLORIDE
Synonyms
MoCl5;ybdenum(V) chL;MOLYBDENUM CHLORIDE;MOLYBDENUMCHLORIDE(V);MOLYBDENUM(V) CHLORIDE;MOLYBDENUM(+5)CHLORIDE;MOLYBDENUM PENTACHLORIDE;molybdenumchloride(mocl5);Molybdenum(V)pentachloride;Molybdenum(V) chloride,95%
CBNumber:
CB1320424
Molecular Formula:
Cl5Mo
Formula Weight:
273.2
MOL File:
10241-05-1.mol

MOLYBDENUM(V) CHLORIDE Properties

Melting point:
194 °C (lit.)
Boiling point:
268 °C (lit.)
Density 
2.928 g/mL at 25 °C (lit.)
vapor pressure 
1.75 mm Hg ( 25 °C)
solubility 
Soluble in dry ether, dry alcohol, organic solvents and chlorinated solvents.
form 
powder
color 
White to gray
Specific Gravity
2.928
Water Solubility 
soluble in dry ether and dry alcohol, in other organic solvents [HAW93]
Sensitive 
Moisture Sensitive
Stability:
Stable, but moisture and air-sensitive. Contact with water liberates toxic gas. Incompatible with water, strong oxidizing agents.
CAS DataBase Reference
10241-05-1(CAS DataBase Reference)
EWG's Food Scores
1
FDA UNII
BB0UFP2VO5
EPA Substance Registry System
Molybdenum chloride (MoCl5) (10241-05-1)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS05,GHS08
Signal word  Danger
Hazard statements  H314-H351-H318
Precautionary statements  P260h-P301+P330+P331-P303+P361+P353-P405-P501a-P280-P305+P351+P338-P310
Hazard Codes  C
Risk Statements  29-34-48/20/22-40
Safety Statements  26-36/37/39-43-45
RIDADR  UN 2508 8/PG 3
WGK Germany  3
RTECS  QA4690000
1-3-10
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  28273985

MOLYBDENUM(V) CHLORIDE price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 208353 Molybdenum(V) chloride 95% 10241-05-1 25g $80.3 2021-03-22 Buy
Sigma-Aldrich 208353 Molybdenum(V) chloride 95% 10241-05-1 100g $196 2021-03-22 Buy
Alfa Aesar 011832 Molybdenum(V) chloride, 99.6% (metals basis) 10241-05-1 5g $34.2 2020-06-24 Buy
Alfa Aesar 011832 Molybdenum(V) chloride, 99.6% (metals basis) 10241-05-1 1kg $1561 2020-06-24 Buy
Strem Chemicals 42-1390 Molybdenum(V) chloride, anhydrous, 99.6% 10241-05-1 250g $746 2021-03-22 Buy

MOLYBDENUM(V) CHLORIDE Chemical Properties,Uses,Production

Physical Properties

Greenish-black monoclinic crystals or dark red as liquid or vapor; paramagnetic; hygroscopic; critical temperature 577°C; critical volume 369 cm3/mol; soluble in dry ether, dry alcohol and many other organic solvents; reacts with water.

Preparation

Molybdenum pentachloride may be prepared by heating molybdenite in chlorine. Sulfur chloride formed in the reaction is removed by distillation:
2MoS2 + 7Cl2 → 2MoCl5 + 2S2Cl2
Also, the compound may be prepared by the action of chlorine on molybdenum metal at elevated temperatures (500°C):
2Mo + 5Cl2 → 2MoCl5
The pentachloride may be obtained from the tetrachloride, MoCl4. The latter, when heated in a sealed tube sublimes, and upon cooling, disproportionates to MoCl5 and the trichloride, MoCl3:
2MoCl4 → MoCl5 + MoCl3

Chemical Properties

Green-black solid, dark red as liquid orvapor.Hygroscopic,reacting with water and air. Soluble in dry ether,dry alcohol, and other organic solvents.

Uses

Chlorination catalyst, vapor-deposited molyb-denum coatings, component of fire-retardant resins,brazing and soldering flux, intermediate fororganometallic compounds, e.g., molybdenum hex-acarbonyl.

Uses

Molybdenum pentachloride (MoCl5) is used as a brazing and soldering flux and to make fire-retardant resins.

Uses

Molybdenum pentachloride MoCl5 is used as a catalyst for several polymerization reactions involving olefins, vinyl monomers, trioxane, ethylene, vinylcyclohexane, cyclopentene, and butadiene.

Air & Water Reactions

MOLYBDENUM(V) CHLORIDE may react with water to produce corrosive hydrochloric acid and toxic fumes.

Reactivity Profile

MOLYBDENUM(V) CHLORIDE is a corrosive, hygroscopic solid, on contact with water or steam MOLYBDENUM(V) CHLORIDE decomposes to form hydrochloric acid. When heated to decomposition MOLYBDENUM(V) CHLORIDE emits toxic fumes of molybdenum chlorides and metallic molybdenum [Lewis, 3rd ed., 1993, p. 892]. Explodes on contact with finely divided sodium [Berry D. H., Chem. Eng. News, 1989, 67(47), p. 2]. Reaction with finely divided sodium sulfide is violent, may lead to autoignition [Kaner, R. B., Nature, 1991, 349, p. 510].

Hazard

Irritant.

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Contact with molten substance may cause severe burns to skin and eyes. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Combustible material: may burn but does not ignite readily. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

A poison. A corrosive irritant to skin, eyes, and mucous membranes. Reacts with moisture to form hydrochloric acid. When heated to decomposition it emits toxic fumes of Mo and Cl-.

MOLYBDENUM(V) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products


MOLYBDENUM(V) CHLORIDE Suppliers

Global( 106)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
career henan chemical co
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sales@coreychem.com CHINA 29954 58
Hubei xin bonus chemical co. LTD
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027-59338440 linda@hubeijusheng.com CHINA 23035 58
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
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CONIER CHEM AND PHARMA LIMITED
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Zhuozhou Wenxi import and Export Co., Ltd
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Fuxin Pharmaceutical
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Zhengzhou Alfa Chemical Co.,Ltd
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8618991951683 mcbio_sales@163.com CHINA 2307 58
Baoji Guokang Healthchem co.,ltd
09178656283
cngksw@aliyun.com CHINA 9474 58

View Lastest Price from MOLYBDENUM(V) CHLORIDE manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-08-12 MOLYBDENUM(V) CHLORIDE
10241-05-1
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2019-09-02 MOLYBDENUM(V) CHLORIDE
10241-05-1
US $1.00 / KG 1KG 85.0-99.8% 200kg career henan chemical co

MOLYBDENUM(V) CHLORIDE Spectrum


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