(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride
- CAS No.
- 158515-16-3
- Chemical Name:
- (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride
- Synonyms
- Rac-(DimethyL;ene) Bis (2-MethyL;(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zircon;Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride;Rac-(Dimethylsilylene) Bis (2-Methyl-4-Phenylindenyl) Zirconium Dichloride;Dichloro[(dimethylsilylene)bis[(1,2,3,3a,7a-η)-2-methyl-4-phenyl-1H-inden-1-ylidene]]zirconium
- CBNumber:
- CB13309628
- Molecular Formula:
- C34H32Cl2SiZr-2
- Molecular Weight:
- 630.83338
- MDL Number:
- MFCD31731386
- MOL File:
- 158515-16-3.mol
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS05 |
---|---|
Signal word | Danger |
Hazard statements | H314 |
Precautionary statements | P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501 |
(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Chemical Properties,Uses,Production
Uses
Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride can be used as organic synthesis intermediate and pharmaceutical intermediate, mainly used in laboratory research and development process.
Synthesis
To a solution of (2-methyl-4-phenylindenyl) silane ether / hexane = 1/1 (12.4 mmol) in 240 mL of n-butyllithium(2.5 M in hexane) was slowly added dropwise at -78 ° C. After that, the mixture was stirred at room temperature for one day, filtered and vacuum dried to obtain a pale yellow solid. A ligand salt synthesized in a glove box and bis (N, N'-diphenyl-1,3-propanediamido)Dichloro zirconium bis (tetrahydrofuran) was weighed in a Schlenk flask, ether was slowly added dropwise at -78 ° C, and the mixture was stirred at room temperature for one day.The red solution was separated by filtration, dried in vacuo, and a toluene / ether = 1/2 solution was added to obtain a clear red solution. 1.5-2 equivalents of HCl ether solution (1M) was slowly added dropwise at -78 ° C, followed by stirring at room temperature for 3 hours. After filtration and vacuum drying, (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride was obtained in a yield of 70% (racemic only).
storage
Pay attention to sealed storage, and the storage place should be cool and dry. Keep away from water.
(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Preparation Products And Raw materials
Raw materials
Preparation Products
(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
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WUXI HONOR SHINE CHEMICAL CO.,LTD | +86-0510-83593312 +8619805123561 | sales@honorshinechem.com | China | 67 | 58 |
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Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20205 | 58 |
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Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39927 | 58 |
Hangzhou Collab Medicine Co.,Ltd. | +8615936229464 | candice@collab-med.com | China | 811 | 58 |
Beijing HwrkChemical Technology Co., Ltd | 18515581800 18501085097 | sales.bj@hwrkchemical.com | China | 9373 | 55 |
Sinocompound Catalysts Co., Ltd. | 0512-67216630 67216634 | sales@sinocompound.com | China | 281 | 64 |
WUXI HONORSHINE CHEMICAL CO.,LTD. | 0510-83593312 13665125081 | sales@honorshinechem.com | China | 52 | 60 |
Shanghai Macklin Biochemical Co.,Ltd. | 15221275939 | shenlinxing@macklin.cn | China | 15874 | 55 |
View Lastest Price from (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2025-02-19 | (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride | US $0.00 / Kg/Drum | 25Kg/Drum | >98% | 200tons | WUXI HONOR SHINE CHEMICAL CO.,LTD |
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- (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride
- US $0.00 / Kg/Drum
- >98%
- WUXI HONOR SHINE CHEMICAL CO.,LTD