ChemicalBook >> CAS DataBase List >>(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride

(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride

CAS No.
158515-16-3
Chemical Name:
(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride
Synonyms
Rac-(DimethyL;ene) Bis (2-MethyL;(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zircon;Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride;Rac-(Dimethylsilylene) Bis (2-Methyl-4-Phenylindenyl) Zirconium Dichloride;Dichloro[(dimethylsilylene)bis[(1,2,3,3a,7a-η)-2-methyl-4-phenyl-1H-inden-1-ylidene]]zirconium
CBNumber:
CB13309628
Molecular Formula:
C34H32Cl2SiZr-2
Molecular Weight:
630.83338
MDL Number:
MFCD31731386
MOL File:
158515-16-3.mol
Last updated:2025-07-04 14:22:59

(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Properties

InChI InChI=1S/2C16H13.C2H6Si.2ClH.Zr/c2*1-12-10-14-8-5-9-15(16(14)11-12)13-6-3-2-4-7-13;1-3-2;;;/h2*2-11H,1H3;1-2H3;2*1H;/q2*-1;;;;+2/p-2
InChIKey LKOFYLBQNPTWPS-UHFFFAOYSA-L

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501

(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Chemical Properties,Uses,Production

Uses

Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride can be used as organic synthesis intermediate and pharmaceutical intermediate, mainly used in laboratory research and development process.

Synthesis

To a solution of (2-methyl-4-phenylindenyl) silane ether / hexane = 1/1 (12.4 mmol) in 240 mL of n-butyllithium(2.5 M in hexane) was slowly added dropwise at -78 ° C. After that, the mixture was stirred at room temperature for one day, filtered and vacuum dried to obtain a pale yellow solid. A ligand salt synthesized in a glove box and bis (N, N'-diphenyl-1,3-propanediamido)Dichloro zirconium bis (tetrahydrofuran) was weighed in a Schlenk flask, ether was slowly added dropwise at -78 ° C, and the mixture was stirred at room temperature for one day.The red solution was separated by filtration, dried in vacuo, and a toluene / ether = 1/2 solution was added to obtain a clear red solution. 1.5-2 equivalents of HCl ether solution (1M) was slowly added dropwise at -78 ° C, followed by stirring at room temperature for 3 hours. After filtration and vacuum drying, (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride was obtained in a yield of 70% (racemic only).

storage

Pay attention to sealed storage, and the storage place should be cool and dry. Keep away from water.

(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Preparation Products And Raw materials

Raw materials

Preparation Products

(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Suppliers

Global( 23)Suppliers
Supplier Tel Email Country ProdList Advantage
WUXI HONOR SHINE CHEMICAL CO.,LTD
+86-0510-83593312 +8619805123561 sales@honorshinechem.com China 67 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418684 +8618949823763 sales@tnjchem.com China 25356 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20205 58
SHANGHAI KEAN TECHNOLOGY CO., LTD.
+8613817748580 cooperation@kean-chem.com China 40066 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39927 58
Hangzhou Collab Medicine Co.,Ltd.
+8615936229464 candice@collab-med.com China 811 58
Beijing HwrkChemical Technology Co., Ltd 18515581800 18501085097 sales.bj@hwrkchemical.com China 9373 55
Sinocompound Catalysts Co., Ltd. 0512-67216630 67216634 sales@sinocompound.com China 281 64
WUXI HONORSHINE CHEMICAL CO.,LTD. 0510-83593312 13665125081 sales@honorshinechem.com China 52 60
Shanghai Macklin Biochemical Co.,Ltd. 15221275939 shenlinxing@macklin.cn China 15874 55

View Lastest Price from (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride pictures 2025-02-19 (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride
US $0.00 / Kg/Drum 25Kg/Drum >98% 200tons WUXI HONOR SHINE CHEMICAL CO.,LTD
Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Rac-(Dimethylsilylene) Bis (2-Methyl-4-Phenylindenyl) Zirconium Dichloride Dichloro[(dimethylsilylene)bis[(1,2,3,3a,7a-η)-2-methyl-4-phenyl-1H-inden-1-ylidene]]zirconium ene) Bis (2-MethyL Rac-(DimethyL (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zircon 158515-16-3