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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

Reaction
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
CAS No.
95464-05-4
Chemical Name:
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
Synonyms
1,1'Pd(dppf)2Cl2;PdCl2(dppf)DCM;Pd(dppf)Cl2 DCM;Pd(dppf)Cl2.CH2Cl2;[PdCl2(dppf)]CH2Cl2;Palladium[PdCl2(dppf)]CH2Cl2;1,1'-Bis(diphenylphosphino)fer;DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)F;cyclopenta-2,4-dien-1-yl(diphenyl)phosphane
CBNumber:
CB1347621
Molecular Formula:
C35H30Cl4FeP2Pd 10*
Formula Weight:
816.64
MOL File:
95464-05-4.mol

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Properties

Melting point:
275-280 °C(lit.)
Density 
1 g/cm3
form 
Powder
color 
orange-red
Water Solubility 
Insoluble in water.
CAS DataBase Reference
95464-05-4(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38-40-67-48/20/22
Safety Statements  23-24/25-26-36/37
WGK Germany  3
HS Code  28439000
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P501 Dispose of contents/container to..…

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 379670 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane 95464-05-4 1g $47.2 2018-11-13 Buy
Sigma-Aldrich 379670 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane 95464-05-4 5g $140 2018-11-13 Buy
TCI Chemical B2064 [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct >98.0%(T) 95464-05-4 1g $50 2018-11-22 Buy
TCI Chemical B2064 [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct >98.0%(T) 95464-05-4 5g $78 2018-11-22 Buy
Alfa Aesar 041225 Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane (1:1), Pd 13% 95464-05-4 1g $46.8 2018-11-16 Buy

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Chemical Properties,Uses,Production

Reaction

  1. Catalyst for the borylation of aryl halides.
  2. β-Alkyl Suzuki-Miyaura cross-coupling reactions with potassium alkyltrifluoroborates.
  3. Catalyst for modified Negishi coupling.
  4. Synthesis of polyheterocycles by a Pd-catalyzed intramolecular N-arylation/C-H bond activation/aryl-aryl bond-forming domino process.
  5. Catalyst for Stille allylation.
  6. Catalyst for the amination of aryl bromides.

Chemical Properties

orange/red solid

Uses

suzuki reaction

Uses

(1,1'-Bis(diphenylphosphino)ferrocene)dichloropalladium-dichloromethane is used in the preparation of imidazoles, benzimidazoles, and tetrahydropyrimidines.

Uses

Used as a catalyst for Suzuki and Stile couplings.

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Preparation Products And Raw materials

Raw materials

Preparation Products


1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Suppliers

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View Lastest Price from 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-07-23 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
95464-05-4
US $100.00 / KG 5KG 97% 50tons career henan chemical co

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