ChemicalBook >> CAS DataBase List >>1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
- CAS No.
- 95464-05-4
- Chemical Name:
- 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
- Synonyms
- Pd（dppf）2Cl2;Pd(dppf)Cl2.CH2Cl2;PdCl2(dppf)DCM;[PdCl2(dppf)]CH2Cl2;Palladium[PdCl2(dppf)]CH2Cl2;[1,1-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane PdCl2(dppf)CH2Cl2;CHEMDOSE;ex with dichL;adium(II),compL;Pd(dppf)Cl2 DCM
- CBNumber:
- CB1347621
- Molecular Formula:
- C34H28Cl2FeP2Pd.CH2Cl2
- Molecular Weight:
- 816.63
- MDL Number:
- MFCD00792899
- MOL File:
- 95464-05-4.mol
- MSDS File:
- SDS
Last updated:2023-12-25 13:23:17
| Melting point | 275-280 °C(lit.) |
|---|---|
| Density | 1 g/cm3 |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Powder |
| color | orange-red |
| Water Solubility | Insoluble in water. |
| Stability | Light Sensitive |
| CAS DataBase Reference | 95464-05-4(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H312+H332-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20/21/22-36/37/38-40-67-48/20/22 | |||||||||
| Safety Statements | 23-24/25-26-36/37 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HS Code | 28439000 | |||||||||
| NFPA 704 |
|
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex price More Price(61)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 379670 | [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane | 95464-05-4 | 1g | $64.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | 379670 | [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane | 95464-05-4 | 5g | $160 | 2024-03-01 | Buy |
| TCI Chemical | B2064 | [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct >98.0%(T) | 95464-05-4 | 1g | $58 | 2024-03-01 | Buy |
| TCI Chemical | B2064 | [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct >98.0%(T) | 95464-05-4 | 5g | $174 | 2024-03-01 | Buy |
| Alfa Aesar | 041225 | Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane (1:1), Pd 13% | 95464-05-4 | 1g | $59.9 | 2023-06-20 | Buy |
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Chemical Properties,Uses,Production
Reaction
- Catalyst for the borylation of aryl halides.
- β-Alkyl Suzuki-Miyaura cross-coupling reactions with potassium alkyltrifluoroborates.
- Catalyst for modified Negishi coupling.
- Synthesis of polyheterocycles by a Pd-catalyzed intramolecular N-arylation/C-H bond activation/aryl-aryl bond-forming domino process.
- Catalyst for Stille allylation.
- Catalyst for the amination of aryl bromides.
Chemical Properties
orange/red solid
Uses
suzuki reaction
Uses
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is used in the preparation of imidazoles, benzimidazoles, and tetrahydropyrimidines,it is also used as a catalyst for Suzuki and Stile couplings.
Application
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is an organometallic compound that can be used as a noble metal catalyst for carbonylation reactions, cross-coupling reactions, Suzuki reaction.
Synthesis
1. Dissolve 2.00 grams of sodium palladium chloride in 30mL of anhydrous ethanol to obtain the ethanol solution of sodium palladium chloride;
2. Dissolve 4.15 grams of 1,1 '-bis (diphenylphosphine) ferrocene in 41mL dichloromethane to obtain 1,1' -bis (diphenylphosphine) ferrocene dichloromethane solution;
3. Under stirring conditions, add the ethanol solution of sodium palladite chloride in step 1 to dichloromethane solution of 1, 1 '-bis (diphenylphosphine) ferrocene in step 2. Stir and react for 1h at 25℃. 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex crystal, yield 90.46%.
In this method, the target product 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex was synthesized directly with dichloromethane as the solvent in one step, eliminating the synthesis process of precursor PDCl2 (DPPF). The reaction process is simple, the synthesis cycle is short, easy to operate, and the purity of the synthesized product is 99.4%.
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 425)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Wuhan Huahan Dingcheng New Material Technology Co., Ltd | +undefined-027-81388558 +undefined086-1878077615 | huahandingcheng@sina.com | China | 342 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7845 | 58 |
| Frapp's ChemicalNFTZ Co., Ltd. | +86 (576) 8169-6106 | sales@frappschem.com | China | 885 | 50 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| AB PharmaTech,LLC | 323-480-4688 | United States | 989 | 55 |
View Lastest Price from 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-01-23 | 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
95464-05-4
|
US $0.00 / KG | 1KG | 98% | 100KG /month | Shanghai Daken Advanced Materials Co.,Ltd | |
 |
2023-12-26 | 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
95464-05-4
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2023-03-06 | 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromet
95464-05-4
|
US $8.70 / g | 10g | 99.95% | 10000kg | Hebei Guanlang Biotechnology Co,.LTD |
-
- 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
95464-05-4
- US $0.00 / KG
- 98%
- Shanghai Daken Advanced Materials Co.,Ltd
-
- 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
95464-05-4
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromet
95464-05-4
- US $8.70 / g
- 99.95%
- Hebei Guanlang Biotechnology Co,.LTD
95464-05-4(1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex)Related Search:
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