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Nickel carbonate

Nickel carbonate
Nickel carbonate structure
CAS No.
3333-67-3
Chemical Name:
Nickel carbonate
Synonyms
ci77779;c.i.77779;cino77779;NICKEL CARBONATE;Nickel(II)Carbona;nickelmonocarbonate;nickel(2+)carbonate;NICKELOUS CARBONATE;nickelcarbonate(1:1);NICKEL(II) CARBONATE
CBNumber:
CB1374836
Molecular Formula:
CNiO3
Formula Weight:
118.7
MOL File:
3333-67-3.mol

Nickel carbonate Properties

Melting point:
decomposes [CRC10]
Density 
4.390
form 
Solid
color 
Light Green
Water Solubility 
Soluble in dilute acids. Insoluble in cold water.
Solubility Product Constant (Ksp)
pKsp: 6.85
Stability:
Stable. Incompatible with strong acids.
CAS DataBase Reference
3333-67-3(CAS DataBase Reference)
EWG's Food Scores
6-7
FDA UNII
WM50SQU829
Proposition 65 List
Nickel Carbonate
EPA Substance Registry System
Nickel carbonate (3333-67-3)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07,GHS08,GHS09
Hazard statements  H302-H315-H317-H332-H334-H341-H350-H360-H372-H400-H410
Precautionary statements  P201-P260-P280-P284-P405-P501a
Hazard Codes  Xn,N
Risk Statements  22-40-43-50/53
Safety Statements  22-36/37-60-61
RIDADR  UN3077
RTECS  QR6200000
TSCA  Yes
HazardClass  9
PackingGroup  III
NFPA 704
0
2 0

Nickel carbonate price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Alfa Aesar 022897 Nickel(II) carbonate, anhydrous, 98% 3333-67-3 50g $44.6 2020-06-24 Buy
Alfa Aesar 022897 Nickel(II) carbonate, anhydrous, 98% 3333-67-3 250g $143 2020-06-24 Buy

Nickel carbonate Chemical Properties,Uses,Production

Chemical Properties

Nickel carbonate is a light green crystalline substance, which is almost insoluble (0.093 g/L) in water (25°C), nonsoluble in hot water, and soluble in acids. Nickel carbonate is available primarily as basic nickel carbonate (NiCO3· 2Ni(OH)2 · 4H2O), which is not soluble in water and soluble in ammonia and dilute acids. In the natural environment, nickel carbonate tetrahydrate can be found as zaratite.
Nickel carbonate

Physical properties

NiCO3: Light green rhombohedral crystals; decomposes on heating; practically insoluble in water, 93 mg/L at 25°C; dissolves in acids.
2NiCO3?3Ni(OH)2?4H2O: Light green crystals or brown powder; decomposes on heating; insoluble in water; decomposes in hot water; soluble in acids and in ammonium salts solutions.
Zaratite: Emerald greed cubic crystals; density 2.6 g/cm3; insoluble in water; soluble in ammonia and dilute acids.

Uses

Nickel carbonate is used to prepare nickel catalysts and several specialty compounds of nickel. It also is used as a neutralizing agent in nickel plating solutions. Other applications are in coloring glass and in the manufacture of ceramic pigments.

Preparation

Anhydrous nickel carbonate is produced as a precipitate when calcium carbonate is heated with a solution of nickel chloride in a sealed tube at 150°C. Alternatively, treating nickel powder with ammonia and carbon dioxide followed by boiling off ammonia yields pure carbonate.
When sodium carbonate is added to a solution of Ni(II) salts, basic nickel carbonate precipitates out in impure form.

Reactions

Nickel carbonate is the starting material for preparing many nickel salts. It reacts with dilute acids evolving carbon dioxide, and upon evaporation of the solution corresponding nickel salts are formed. The nitrate, sulfate and phosphate salts are prepared from carbonate. Similarly, reactions with hydrofluoric, hydrochloric, hydrobromic, or hydriodic acids yield hydrated nickel halides: namely NiF2•4H2O, NiCl2•6H2O, NiBr2•6H2O, and NiI2•6H2O, respectively:
NiCO3 + HCl → NiCl2•6H2O + CO2
NICKEL CARBONATE 611Nickel carbonate decomposes to nickel oxide when strongly ignited:
NiCO3 → NiO + CO2
Nickel carbonate, when dissolved in aqueous thiocyanic acid, yields a yellow brown precipitate of hydrated nickel thiocyanate:
2 NiCO3 + 2HSCN → Ni(SCN)2 + CO2 + H2O
Nickel carbonate forms many double salts, such as, Na2CO3•NiCO3•10H2O with alkali metal carbonates. However, such double carbonates usually are prepared by mixing an alkali metal or ammonium bicarbonate solution with a nickel salt solution, followed by crystallization.

Hazard

Confirmed carcinogen.

Safety Profile

Confirmed human carcinogen. When heated to decomposition it emits toxic vapors of nickel.

Nickel carbonate Preparation Products And Raw materials

Raw materials

Preparation Products


Nickel carbonate Suppliers

Global( 161)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22624 55
Hefei TNJ Chemical Industry Co.,Ltd.
86-0551-65418684 18949823763
86-0551-65418684 info@tnjchem.com China 2754 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 30039 58
Zhonglan Industry Co., Ltd.
(86) 531-82956570
(86) 531-82956571 sales@zhonglanindustry.com CHINA 4895 58
Shandong chuangyingchemical Co., Ltd.
18853181302
sale@chuangyingchem.com CHINA 5917 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 35434 58
SIMAGCHEM CORP
13806087780 +86 13806087780
shaobowang@simagchem.com CHINA 17852 58
Mainchem Co., Ltd. +86-0592-6210733
+86-0592-6210733 sale@mainchem.com CHINA 32444 55
Chemwill Asia Co.,Ltd. 86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23977 58
Wuhan yuqing jiaheng pharmaceutical co. LTD 13545340383 027-83855389-
027-83855389 2586905842@qq.com China 1020 58

View Lastest Price from Nickel carbonate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-24 Nickel carbonate
3333-67-3
US $1.00 / kg 1kg 99% as request career henan chemical co

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