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2,2'-BITHIOPHENE

CAS No.
492-97-7
Chemical Name:
2,2'-BITHIOPHENE
Synonyms
Dithienyl;2T;2TH;S1020;2,2-DITHIENYL;2,2’-dlthienyl;2,2'-BITHIENYL;2,2'-DITHIENYL;2,2'-Bithienyl;2,2'-Bithiophen
CBNumber:
CB1388493
Molecular Formula:
C8H6S2
Molecular Weight:
166.26
MDL Number:
MFCD00005414
MOL File:
492-97-7.mol
Last updated:2023-10-20 13:11:28

2,2'-BITHIOPHENE Properties

Melting point 32-33 °C (lit.)
Boiling point 260 °C (lit.)
Density 1.2455 (rough estimate)
refractive index 1.6210 (estimate)
Flash point >230 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
form powder to lump to clear liquid
color White or Colorless to Light yellow to Green
Water Solubility Insoluble in water.
Sensitive Light Sensitive
BRN 3039
InChIKey OHZAHWOAMVVGEL-UHFFFAOYSA-N
LogP 3.750
CAS DataBase Reference 492-97-7(CAS DataBase Reference)
FDA UNII 8CTS9HJ7L6
EPA Substance Registry System 2,2'-Bithiophene (492-97-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H332-H335
Precautionary statements  P261-P280-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  20/21/22-36/37/38
Safety Statements  22-24/25-36-26
WGK Germany  3
10-23
TSCA  T
HazardClass  IRRITANT
HS Code  29309090
NFPA 704
1
1 0

2,2'-BITHIOPHENE price More Price(49)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 241636 2,2′-Bithiophene 99% 492-97-7 10g $172 2024-03-01 Buy
TCI Chemical B1276 2,2'-Bithiophene >98.0%(GC) 492-97-7 1g $23 2024-03-01 Buy
TCI Chemical B1276 2,2'-Bithiophene >98.0%(GC) 492-97-7 25g $100 2024-03-01 Buy
Alfa Aesar A12335 2,2'-Bithiophene, 98% 492-97-7 1g $30.65 2024-03-01 Buy
Alfa Aesar A12335 2,2'-Bithiophene, 98% 492-97-7 5g $91.2 2024-03-01 Buy
Product number Packaging Price Buy
241636 10g $172 Buy
B1276 1g $23 Buy
B1276 25g $100 Buy
A12335 1g $30.65 Buy
A12335 5g $91.2 Buy

2,2'-BITHIOPHENE Chemical Properties,Uses,Production

Description

2,2'-bithiophene is an intermediate widely used for the synthesis of small molecules or polymer semiconductors in application of organic electronics.?It has proven that?2,2'-bithiophene exists as a mixture of the cis-like and the trans-like planar structures. 5,5'-positions of?2,2'-bithiophene are easily accessible for bromination and stannylation to give 5,5'-dibromo-2,2'-bithiophene or 5,5'-trimethylstannyl-2,2'-bithiophene, which can be used for direct arylation reactions.

Chemical Properties

white to light yellow crystal powder

Uses

2,2′-Bithiophene can be polymerized to form poly(2,2′-Bithiophene) which can be electrodeposited on indium tin oxide (ITO) substrates for the fabrication of electrochromic devices. It can also be used in the formation of electrode material for the development of supercapacitors.

Uses

2,2’Bithiophene is a reactant in the preparation of thienophenyl compounds.

Uses

2,2'-Bithiophene is used as a precursor in the preparation of 5,5'-bis(trimethylstannyl)-2,2'-bithiophene , which is used for the synthesis of small molecules and polymer semiconductors for organic field-effect transistor (OFETs), organic light-emitting diode (OLED), Plastic Light Emitting Diode (PLED) and Organic Photovoltaic (OPV) applications. It is associated with aryl iodides and involved in rhodium catalyzed arylation of heteroarenes.

Definition

ChEBI: A thiophene derivative that consists of two thiophene rings connected by a 2,2'-linkage.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 2627, 1986 DOI: 10.1021/jo00364a002
Synthetic Communications, 19, p. 307, 1989 DOI: 10.1080/00397918908050983

General Description

2,2′-Bithiophene is an electron transporting material with the π-electrons present in the system that facilitate charge mobility.

Global( 358)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai UCHEM Inc.
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Henan Fengda Chemical Co., Ltd
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Shandong chuangyingchemical Co., Ltd.
18853181302 sale@chuangyingchem.com CHINA 5909 58

View Lastest Price from 2,2'-BITHIOPHENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,2'-Bithiophene pictures 2024-02-23 2,2'-Bithiophene
492-97-7
US $10.00-182.00 / g 25g 0.98 25kg Shanghai UCHEM Inc.
2,2'-Bithiophene pictures 2024-01-02 2,2'-Bithiophene
492-97-7
US $200.00-1.00 / KG 1KG 99%, 99.5% Sublimated g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
2,2'-BITHIOPHENE pictures 2023-01-04 2,2'-BITHIOPHENE
492-97-7
US $26.00 / kg 1kg 0.99 1000kg Hebei Duling International Trade Co. LTD
  • 2,2'-Bithiophene pictures
  • 2,2'-Bithiophene
    492-97-7
  • US $200.00-1.00 / KG
  • 99%, 99.5% Sublimated
  • Henan Fengda Chemical Co., Ltd
  • 2,2'-BITHIOPHENE pictures
  • 2,2'-BITHIOPHENE
    492-97-7
  • US $26.00 / kg
  • 0.99
  • Hebei Duling International Trade Co. LTD
2,2'-Bithiophene,98% 2,2'-Bithiophen 2,2μ-Bithienyl, 2,2μ-Dithienyl 2-(2'-Thieno)thiophene 2,2'-Bithiophene,97% 2,2zzhlxy-Bithiophene 2,2’-dlthienyl 2,2'-Dithiophene 2-(Thiophen-2yl) thiophene 2,2′-Bithiophene, >=99% 2,2'-BITHIOPHENE 2,2'-BITHIENYL [2,2']BITHIOPHENYL 2,2'-DITHIENYL 2,2-DITHIENYL 2-(2-Thienyl)thiophen 2TH 2,2'-Bithiophene > 2,2'-BITHIOPHENE ISO 9001:2015 REACH S1020 2T Dithienyl 2,2'-Bithiophene (6CI, 7CI, 8CI, 9CI, ACI) 2,2'-Bisthiophene 2,2'-Bithiophene 2,2'-Bisthiophene 2,2'-Bithienyl 492-97-7 492-97-9 C4H3S2 C8H6S2 Reagents for Conducting Polymer Research Thiophene Derivatives (for Conduting Polymer Research) Building Blocks Heterocyclic Building Blocks Thiophenes pharmacetical Functional Materials Reagents for Conducting Polymer Research Thiophene Derivatives (for Conduting Polymer Research) Thiophen Thiophenes Heterocycle-oher series Thiophene Series