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(+)-DIOP

(+)-DIOP Structure
(+)-DIOP structure
CAS No.
37002-48-5
Chemical Name:
(+)-DIOP
Synonyms
(S)-DIOP;(+)-DIOP;(+)-DIOP;(S,S)-DIOP;idene-2,3-butanedioL;phosphino)-2,3-O-isopropyL;(2S,3S)-(+)-1,4-Bis(diphenyL;(4S,5S)-(+)-4,5-BIS(DIPHENYLPHOSPHINOMET;4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxalan;(+)-2,2-dimethyl-4,5-((diphenylphosphino)dimethyl)dioxolane
CBNumber:
CB1393749
Molecular Formula:
C31H32O2P2
Molecular Weight:
498.54
MDL Number:
MFCD00009760
MOL File:
37002-48-5.mol
MSDS File:
SDS
Last updated:2023-08-15 13:09:01
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(+)-DIOP Properties

Melting point 86-88 °C(lit.)
alpha +26° (c 2.0, CHCl3)
Boiling point 590.3±25.0 °C(Predicted)
storage temp. Store below +30°C.
form Powder
color White
Water Solubility Sparingly soluble in water at 25°C 2.1E-5 g/L.
Sensitive Air Sensitive
BRN 1630280
InChIKey VCHDBLPQYJAQSQ-LOYHVIPDSA-N
CAS DataBase Reference 37002-48-5
FDA UNII 5P52K0IJ7T

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3
F  10-23
HS Code  29319090
NFPA 704
1
2 0

(+)-DIOP price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B1112 (2S,3S)-(+)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol >95.0%(GC)(T) 37002-48-5 1g $122 2021-12-16 Buy
Alfa Aesar B21013 (+)-DIOP, 98% 37002-48-5 1g $108 2021-12-16 Buy
Alfa Aesar B21013 (+)-DIOP, 98% 37002-48-5 0.25g $47.2 2021-12-16 Buy
Strem Chemicals 15-2960 (4S,5S)-(+)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane, 99.5% (S,S)-DIOP 37002-48-5 250mg $57 2024-03-01 Buy
Strem Chemicals 15-2960 (4S,5S)-(+)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane, 99.5% (S,S)-DIOP 37002-48-5 1g $139 2024-03-01 Buy
Product number Packaging Price Buy
B1112 1g $122 Buy
B21013 1g $108 Buy
B21013 0.25g $47.2 Buy
15-2960 250mg $57 Buy
15-2960 1g $139 Buy

(+)-DIOP Chemical Properties,Uses,Production

Chemical Properties

white powder

Uses

It is employed as a ligand for the in situ preparation of chiral hydrogenation catalysts. It also finds it application for the in situ preparation of chiral hydrogenation catalysts, ligand for Rh(I)-catalyzed asymmetric hydrogenation of enamides, 1,4-disilylation of α,β-unsaturated ketones, Heck reaction of alkenyl iodides, and hydroformylation of olefins.

Purification Methods

It has been recrystallised from *C6H6/pet ether. After 2 recrystallisations from EtOH, it was pure by TLC on silica gel using Me2CO/hexane as solvent. [Kagan & Dang J Am Chem Soc 94 6429 1972.] Lanthanide shift reagents See in “Aliphatic Compounds”, Chapter 4, europium (III) acetate above and Eu(tmc)3 and Eu(tfc)3 below.

(+)-DIOP Preparation Products And Raw materials

Raw materials

L(+)-Diethyl L-tartrate p-Toluenesulfonic acid Triethyl orthoformate Sodium Methanesulfonyl chloride
Tetrahydrofuran Ethyl acetate Lithium Aluminum Hydride Dichloromethane L(+)-Tartaric acid
Triphenylphosphine PETROLEUM ETHER Lithium

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Preparation Products

(+)-DIOP Suppliers

Global( 104)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd 		+8613288715578 sales@hbmojin.com China 12457 58
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Shenzhen Nexconn Pharmatechs Ltd 		+86-755-89396905 +86-15013857715 admin@nexconn.com China 10248 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28180 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Shaanxi Dideu Medichem Co. Ltd 		18192627656 1012@dideu.com China 3453 58
Hefei TNJ Chemical Industry Co.,Ltd. 		0551-65418671 sales@tnjchem.com China 34572 58
Dayang Chem (Hangzhou) Co.,Ltd. 		571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
GIHI CHEMICALS CO.,LIMITED 		+8618058761490 info@gihichemicals.com China 49999 58
Shaoxin Catsyn Co., Ltd. 		+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6116 58
Supplier Advantage
Hebei Mojin Biotechnology Co., Ltd 		58
career henan chemical co 		58
Shenzhen Nexconn Pharmatechs Ltd 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Chongqing Chemdad Co., Ltd 		58
Shaanxi Dideu Medichem Co. Ltd 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
GIHI CHEMICALS CO.,LIMITED 		58
Shaoxin Catsyn Co., Ltd. 		58

View Lastest Price from (+)-DIOP manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(+)-DIOP pictures 2023-08-15 (+)-DIOP
37002-48-5
 US $10.00 / KG 1KG 99% 5000000kg Hebei Mojin Biotechnology Co., Ltd
(+)-DIOP pictures 2023-01-11 (+)-DIOP
37002-48-5
 US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Guanlang Biotechnology Co., Ltd.
(2S,3S)-(+)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol pictures 2020-03-16 (2S,3S)-(+)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol
37002-48-5
 US $1.00-0.00 / KG 1KG 99% 20 Tons Shaanxi Dideu Medichem Co. Ltd
  • (+)-DIOP pictures
  • (+)-DIOP
    37002-48-5
  • US $10.00 / KG
  • 99%
  • Hebei Mojin Biotechnology Co., Ltd
  • (+)-DIOP pictures
  • (+)-DIOP
    37002-48-5
  • US $0.00-0.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.

(+)-DIOP Spectrum

(+)-DIOP(37002-48-5)MS(+)-DIOP(37002-48-5)1HNMR(+)-DIOP(37002-48-5)IR1(+)-DIOP(37002-48-5)IR2(+)-DIOP(37002-48-5)Raman

37002-48-5((+)-DIOP)Related Search:

Amino-2-propanol Flexol plasticizer diop (-)-DIOP,(4R,5R)-(-)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane,99.5%(R,R)-DIOP,(R,R)-DIOP 4-METHYL-1,3-DIOXOLANE 2-METHYL-1,3-DIOXOLANE
ETHYLDIPHENYLPHOSPHINE 2,2-DIMETHYL-1,3-DIOXOLANE 1,4-Bis(diphenylphosphino)butane 1,3-Dioxolane 2,2,4-TRIMETHYL-1,3-DIOXOLANE
2,4-DIMETHYL, 1,3-DIOXALONE (+)-DIOP 2,2-Diethoxypropane DIPHENYL-N-PROPYLPHOSPHINE Diphenylphosphine
BUTYLDIPHENYLPHOSPHINE 1,4-BIS(DIMETHYLPHOSPHINO)BUTANE (-)-MOD-DIOP

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(4S,5S)-(+)-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane (+)-DIOP (2S,3S)-(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane (+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosp (S)-DIOP (S,S)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane 1,1'-[[(4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diyl]bis(methylene)]bis[1,1-diphenyl-Phosphine (4S,5S)-(+)-4,5-Bis(diphenylphosphinoMethyl)-2,2-diMethyl-1,3-dioxolane,(S,S)-DIOP. (+)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane [(4S,5S)-5-(diphenylphosphanylmethyl)-2,2- dimethyl-1,3-dioxolan-4-yl]methyl-diphenylphosphane (4S,5S)-(+)-4,5-Bis(diphenylphosphinomethyl)-2,2- dimethyl-1,3-dioxolane for synthesis (S,S)-DIOP (+)-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BIS(DIPHENYLPHOSPHINO)BUTANE (+)-1,4-BIS(DIPHENYLPHOSPHINO)-1,4-DIDEOXY-2,3-O-ISOPROPYLIDENE-D-THREITOL 4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxalan (+)-DIOP, (S,S)-DIOP, (4S,5S)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane, (4S-trans)-[(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene)]bis(diphenylphosphine) (4S-TRANS)-[(2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIYL)BIS(METHYLENE)]BIS(DIPHENYLPHOSPHINE) (4S,5S)-(+)-4,5-BIS(DIPHENYLPHOSPHINOMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (4S,5S)-4,5-BIS(DIPHENYLPHOSPHINO-METHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (4S 5S)-(+)-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BIS(DIPHENYLPHOSPHINO)BUTANE (4S,5S)-(+)-BIS(DIPHENYLPHOSPHINOMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (+)-DIOP (2S,3S)-(+)-1,4-BIS(DIPHENYLPHOSPHINO)-2,3-O-ISOPROPYLIDENE-2,3-BUTANEDIOL (2S,3S)-(+)-2,3-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BIS(DIPHENYLPHOSPHINO)BUTANE (+)-2,3-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BIS(DIPHENYLPHOSPHINO)BUTANE (4S,5S)-(+)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane,99.5%(S,S)-DIOP Phosphine, (4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diylbis(methylene)bisdiphenyl- (+)-DIOP, (S,S)-DIOP, (+)-1,4-Bis(diphenylphosphino)-1,4-dideoxy-2,3-O-isopropylidene-D-threitol, (4S,5S)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane, (4S-trans)-[(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene)]bis(diphenylphosphine) (4S,5S)-2,2-Dimethyl-4,5-bis(diphenylphosphinomethyl)-1,3-dioxolane (4α,5β)-2,2-Dimethyl-4,5-bis(diphenylphosphinomethyl)-1,3-dioxolane [(4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl]bis(methylene)bis(diphenylphosphine) [(4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl]bismethylenebis(diphenylphosphine) [[(4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl]bis(methylene)]bis(diphenylphosphine) (4S,5S)-(+)-4,5-Bis(diphenylphosphinoMethyl)-2,2-diMethyl-1,3-dioxolane,99% (S,S)-DIOP (+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane,98% (S,S)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane (2S,3S)-(+)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol > (2S,3S)-(+)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol[(+)-DIOP] (4S,5S)-(+)-4,5-BIS(DIPHENYLPHOSPHINOMET Phosphine, 1,1'-[[(4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diyl]bis(methylene)]bis[1,1-diphenyl- (+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino) (2S,3S)-(+)-1,4-Bis(diphenyL idene-2,3-butanedioL phosphino)-2,3-O-isopropyL (((4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphane) (+)-2,2-dimethyl-4,5-((diphenylphosphino)dimethyl)dioxolane (+)-2,3-o-Isopropylidene-2,3-Dihydroxy-1,4-Bis(Diphenylphosphino)Butane (+)-DIOP (S,S)-DIOP/(4S,5S)-(+)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane (+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosp 37002-48-5 Phosphine Ligands Dioxanes & Dioxolanes Asymmetric Synthesis Dioxolanes Chiral Catalysts, Ligands, and Reagents Privileged Ligands organophosphine ligand Phosphine Ligands Asymmetric Synthesis