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2-CHLOROPHENYLZINC IODIDE

CAS No.
148651-35-8
Chemical Name:
2-CHLOROPHENYLZINC IODIDE
Synonyms
2-CHLOROPHENYLZINC IODIDE;2-chlorophenylzinc iodide solution;2-Chlorophenylzinc iodide solution 0.5 in THF;2-Chlorophenylzinc iodide solution 0.5M in THF;2-Chlorophenylzinc iodide 0.5 M in Tetrahydrofuran;2-CHLOROPHENYLZINC IODIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;2-Chlorophenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles;2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
CBNumber:
CB1436675
Molecular Formula:
C6H4ClIZn
Molecular Weight:
303.84
MDL Number:
MFCD01863648
MOL File:
148651-35-8.mol
Last updated:2023-05-27 08:28:43

2-CHLOROPHENYLZINC IODIDE Properties

Density 0.973 g/mL at 25 °C
Flash point 1 °F
storage temp. 2-8°C
Sensitive Air & Light Sensitive
Exposure limits ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
CAS DataBase Reference 148651-35-8

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS02,GHS07,GHS08
Signal word  Danger
Hazard statements  H261-H314-H318-H333-H225-H302-H319-H335-H351
Precautionary statements  P223-P303+P361+P353-P405-P501a-P210-P280-P301+P312+P330-P305+P351+P338-P370+P378-P403+P235
Hazard Codes  F,Xn
Risk Statements  11-19-22-36/37/38-40-36/37
Safety Statements  16-26-33-36-36/37
RIDADR  UN 2056 3/PG 2
WGK Germany  1
HazardClass  4.3
NFPA 704
3
3 2
W

2-CHLOROPHENYLZINC IODIDE price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 499803 2-Chlorophenylzinc iodide solution 0.5M in THF 148651-35-8 50ml $273 2023-06-20 Buy
Alfa Aesar H58383 2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles 148651-35-8 50ml $216 2021-12-16 Buy
Rieke Metals 2135 2-Chlorophenylzinciodide 148651-35-8 100mL $755 2021-12-16 Buy
American Custom Chemicals Corporation ING0005751 2-CHLOROPHENYLZINC IODIDE 95.00% 148651-35-8 50ML $2760.45 2021-12-16 Buy
American Custom Chemicals Corporation ING0005751 2-CHLOROPHENYLZINC IODIDE 95.00% 148651-35-8 100ML $3106.95 2021-12-16 Buy
Product number Packaging Price Buy
499803 50ml $273 Buy
H58383 50ml $216 Buy
2135 100mL $755 Buy
ING0005751 50ML $2760.45 Buy
ING0005751 100ML $3106.95 Buy

2-CHLOROPHENYLZINC IODIDE Chemical Properties,Uses,Production

Uses

2-Chlorophenylzinc iodide is an organozinc compound, which can be used as a reactant in Negishi cross-coupling reaction to construct carbon-carbon bonds by reacting with organic halides using nickel or palladium catalysts.
It can also be utilized as a reactant to prepare:

  • Arylmethanes via rhodium-catalyzed cross-coupling reaction with methyl halides.
  • (2-chlorobenzyl)trimethylsilane by Rh-catalyzed cross-coupling reaction with (iodomethyl)trimethylsilane.
  • Dichloro biphenyl by palladium catalyzed oxidative homocoupling reaction using N-chlorosuccinimide (NCS) or O2 as the oxidant.

615-41-8
7440-66-6
148651-35-8
Synthesis of 2-CHLOROPHENYLZINC IODIDE from 1-Chloro-2-iodobenzene and ZINC

2-CHLOROPHENYLZINC IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

2-CHLOROPHENYLZINC IODIDE Suppliers

Global( 16)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30132 84
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696; info@hanhongsci.com China 42982 64
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Infinity SCI 400-400-1062016 17800804092 admin@infsci.com China 719 55
Shenzhen Polymeri Biochemical Technology Co., Ltd. +86-400-002-6226 13028896684 sales@rrkchem.com China 55717 58
Guangdong Wengjiang Chemical Reagent Co., Ltd. 0751-2886766 13927870850 3001267247@qq.com China 10067 58
Energy Chemical 021-58432009 400-005-6266 marketing1@energy-chemical.com China 44894 58
Huangshi Bo’Er Chemical Co., Ltd. 0714-6401888 18671400300 273568016@qq.com China 519 58
Baoji Didu Pharmaceutical and Chemical Co., Ltd 17691182729 15991417702 1065@dideu.com China 10011 58
2-CHLOROPHENYLZINC IODIDE 2-CHLOROPHENYLZINC IODIDE, 0.5M SOLUTION IN TETRAHYDROFURAN 2-chlorophenylzinc iodide solution 2-Chlorophenylzinc iodide solution 0.5 in THF 2-Chlorophenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles 2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles 2-Chlorophenylzinc iodide solution 0.5M in THF 2-Chlorophenylzinc iodide 0.5 M in Tetrahydrofuran 148651-35-8 ClC6H4ZnI Aryl Organozinc Halides Organometallic Reagents Reike and Organozinc Reagents Aryl Organozinc Halides Reike and Organozinc Reagents