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ETHYLENE structure
Chemical Name:
Molecular Formula:
Formula Weight:
MOL File:

ETHYLENE Properties

Melting point:
−169 °C(lit.)
Boiling point:
−104 °C(lit.)
vapor density 
0.97 (vs air)
vapor pressure 
35.04 atm ( 20 °C)
refractive index 
Flash point:
-100 °C
explosive limit
Stable. Highly flammable - note wide explosion limits. Incompatible with strong oxidizing agents. Readily forms explosive mixtures with air.
CAS DataBase Reference
74-85-1(CAS DataBase Reference)
NIST Chemistry Reference
EPA Substance Registry System
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  F+,F
Risk Statements  12-67
Safety Statements  9-16-33-46-45
RIDADR  UN 1962 2.1
WGK Germany  -
RTECS  KU5340000
Autoignition Temperature 842 °F
HazardClass  2.1
HS Code  29012100
Hazardous Substances Data 74-85-1(Hazardous Substances Data)
Toxicity LC for mice in air: 950,000 ppm (Flury)
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H220 Extremely flammable gas Flammable gases Category 1 Danger P210, P377, P381, P403
H280 Contains gas under pressure; may explode if heated Gases under pressure Compressed gas
Liquefied gas
Dissolved gas
Warning P410+P403
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 Eliminate all ignition sources if safe to do so.
P410+P403 Protect from sunlight. Store in a well-ventilated place.

NFPA 704

Diamond Hazard Value Description
Flammability   4 Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Includes pyrophoric substances. Flash point below room temperature at 22.8 °C (73 °F). (e.g. acetylene, propane, hydrogen gas)
Instability   2 Undergoes violent chemical change at elevated temperatures and pressures, reacts violently with water, or may form explosive mixtures with water (e.g. white phosphorus, potassium, sodium)

(NFPA, 2010)

ETHYLENE price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 295329 Ethylene ≥99.5% 74-85-1 110g $361 2018-11-20 Buy
Sigma-Aldrich 536164 Ethylene 99.99% 74-85-1 110g $826 2018-11-20 Buy
Sigma-Aldrich 00489 Ethylene puriss., ≥99.95% (GC) 74-85-1 11l $71.5 2018-11-23 Buy

ETHYLENE Chemical Properties,Uses,Production


Ethylene is a colorless, odorless gas that is the simplest alkene hydrocarbon. It is a natural plant hormone and is produced synthetically from natural gas and petroleum. The double bond in ethylene makes this compound highly reactive, and the volume of ethylene used in the chemical industry is greater than any other organic compound.

Chemical Properties

colourless gas

Chemical Properties

Ethylene, an alkene is a colorless gas (at room temperature). Sweet odor. Minimum detectable odor 5 260 ppm.


Ethylene occurs in petroleum gases, in illuminatinggas, and in ripening fruits. It is made by dehydrating alcohol. It is used in oxyethyleneflame for welding and cutting metals; inthe manufacture of polyethylene, polystyrene,and other plastics; in making ethylene oxide;and as an inhalation anesthetic.


Oxyethylene welding and cutting metals; manufacture of alcohol, mustard gas, and many other organics. manufacture of ethylene oxide (for plastics), "Polythene", polystyrene and other plastics. Plant growth regulator; used commercially to accelerate the ripening of various fruits.


Ethylene is highly reactive and is one of the most important compounds for the chemical industry. The highest use of ethylene is in polymerization reactions. Polyethylene polymers are linear, but they contain side branchings of methyl groups. Among these are several groups defi ned by their density produced under different pressure regimens.
The second highest use of ethylene involves oxidation to ethylene oxide and its derivative ethylene glycol (HO-CH2-CH2-OH). Ethylene glycol is used mainly as antifreeze and in the production of polyesters. Other important compounds produced through oxidation of ethylene are acetaldehyde (H3C-CH = O) and vinyl acetate (CH2 = CH-O-CO-CH2). Ethylene may also be halogenated to produce a number of other compounds.

Production Methods

Ethylene is primarily obtained from the ethane and propane components of natural gas andfrom the naphtha, kerosene, and gas oil components of crude oil. It can also be synthesizedthrough the dehydration of ethanol (C2H5OH). The production of ethylene from hydrocarbonfeedstocks involves mixing with steam and then subjecting the hydrocarbons to thermalor catalytic cracking. Cracking is a process in which organic molecules are broken down intosmaller molecules. Thermal cracking involves the use of heat and pressure. Catalytic crackinguses various catalysts to reduce the amount of heat and pressure required in the process.Th ermal cracking of hydrocarbons to ethylene occurs between approximately 650°C and800°C (1200°F and 1500°F). After hydrocarbons are cracked, a mixture containing ethyleneand other gases such as methane, ethane, and propane is obtained. Ethylene is separated fromthese through physical processes such as fractional distillation, refrigeration, absorption, oradsorption.


ethylene: A colourlessflammable gaseous hydrocarbon,C2H4; m.p. –169°C; b.p. –103.7°C. It isthe first member of the alkene seriesof hydrocarbons. It is made bycracking hydrocarbons from petroleumand is now a major raw materialfor making other organicchemicals (e.g. ethanal, ethanol,ethane-1,2-diol). It can be polymerizedto polyethene. It occurs naturallyin plants, in which it acts as agrowth substance promoting theripening of fruits.

General Description

A colorless gas with a sweet odor and taste. ETHYLENE is lighter than air. ETHYLENE is easily ignited and a flame can easily flash back to the source of the leak. Under prolonged exposure to fire or heat the containers may rupture violently and rocket. Can cause explosion.

Air & Water Reactions

Highly flammable.

Reactivity Profile

Peroxidizable monomer may initiate exothermic polymerization of the bulk material [Bretherick 1979. p. 160]. ETHYLENE in the presence of aluminum chloride may undergo a violent reaction [J. Inst. Pet. 33:254. 1947]. Ozone and ETHYLENE react explosively [Berichte 38:3837]. ETHYLENE can polymerize at low pressure if catalyzed by titanium halides. (Sundaram, K. M, M. M. Shreehan, E. F. Olszewski. thylene. Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. 2001.)


Highly flammable, dangerous fire and explosion risk; explosive limits in air 3–36% by volume. Simple asphyxiant; questionable carcinogen.

Health Hazard

Moderate concentration in air causes drowsiness, dizziness, and unconsciousness. Overexposure causes headache, drowsiness, muscular weakness.

Health Hazard

Exposure to ethylene atmosphere can causeasphyxiation. At high concentrations it is anarcotic and can cause unconsciousness.

Fire Hazard

Flammable gas; burns with a luminous flame; autoignition temperature 490°C (914°F) (NFPA 1997), 543°C (1009°F) (Merck 1996); fire-extinguishing measure: shut off the flow of gas; use a water spray to keep fire-exposed containers cool.
Ethylene forms explosive mixtures in air; the LEL and UEL values are 2.7% and 36% by volume of air, respectively. Its reaction with fluorine is explosively violent (△H=- 112 kcal/mol), and violent with chlorine (△H=- 36 kcal/mol). In the presence of sunlight or UV light, an ethylene– chlorine mixture will explode spontaneously. The reaction is explosive at room temperature over the oxides of mercury or silver (Mellor 1946, Suppl. 1956). Ethylene reacts vigorously with oxidizing substances. It reacts with ozone to form ethylene ozonide, H2C(O3)CH2, which is unstable and explodes on mechanical shock. Acidcatalyzed addition of hydrogen peroxide may produce ethyl hydroperoxide, which is unstable and explodes on heat or shock:.

Industrial uses

Ethylene, also called ethane, is a colorless,inflammable gas, CH2:CH2, produced in thecracking of petroleum. Ethylene liquefies at–68.2°C. Ethylene is the largest-volume organicchemical produced today, and is the basic buildingblock of the petrochemical industry. Polymerizationof ethylene is its largest use. Whenethylene is reacted in the presence of transitionmetal catalysts, such as Mo2O5 or Cr2O3, at highpressures, it forms low-density polyethylene(LDPE); at lower pressures, high-density polyethylene(HDPE) is produced. Recently, lowpressures have been employed for making a newvariant, linear low-density polyethylene(LLDPE). Ethylene is now used to produce ethylalcohol, acrylic acid, and styrene, and it is thebasis for many types of reactive chemicals.
Trichloroethylene is a colorless liquid ofpleasant odor of the composition CHCl:CCl2,also known as westrosol. Its boiling point is87°C and its specific gravity 1.471. It is insolublein water and is unattacked by dilute acidsand alkalis. It is non flammable and is less toxicthan tetrachlorethane. Trichloroethylene is apowerful solvent for fats, waxes, resins, rubber,and other organic substances, and is employedfor the extraction of oils and fats, for cleaningfabrics, and for degreasing metals preparatoryto plating. The freezing point is –88°C, and itis also used as a refrigerant. It is also used insoaps employed in the textile industry fordegreasing.

Safety Profile

Suspected carcinogen. A simple asphyxiant. High concentrations cause anesthesia. A common air contaminant. It is phytotoxic. A very dangerous fire hazard when exposed to heat or flame. Moderate explosion hazard when exposed to flame. A flammable gas. To figh fire, stop flow of gas, use Co2, dry chemical, or fine water spray. Mixtures with aluminum chloride explode in the presence of nickel catalysts, methyl chloride, or nitromethane. Explosive reaction with bromotrichloromethane (at 120℃/51 bar), carbon tetrachloride (25-100°C/30 bar). Explosive reaction with chlorine catalyzed by sunlight or UV light or in the presence of mercury(I) oxide, mercury(Ⅱ) oxide, or silver oxide. Mixtures with chlorotrifluoroethylene polymerize explosively when exposed to 50 kV gamma rays at 308 krad/hr. Has been involved in industrial accidents. Violent polymerization is catalyzed by copper above 4OO0C/54 bar. Incompatible with AlCl3, (CC4 + benzoyl peroxide), (bromotrichloromethane + NCh), 03, CCl4, Cl2, NOx, tetrafluoroethylene trifluorohypofluorite. When heated to decomposition it emits acrid smoke and irritating fumes

Potential Exposure

Ethylene is used in production of fabricated plastics, antifreeze; making fibers; to manufacture ethylene oxide, polyethylene for plastics, alcohol, mustard gas and other organics. It is used to accelerate ripening of fruit; as an anesthetic; and for oxyethylene welding and cutting of metals

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. If frostbite has occurred, seek medical attention immediately; do NOT rub the affected areas or flush them with water. In order to prevent further tissue damage, do NOT attempt to remove frozen clothing from frostbitten areas. If frostbite has NOT occurred, immediately and thoroughly wash contaminated skin with soap and water.


Ethylene is stored in a cool, well-ventilatedarea isolated from oxygen, chlorine, andflammable and oxidizing substances. It isprotected against lightning, statical electricity,heat, and physical damage. It is shippedin steel pressure cylinders and tank barges.


UN1962 Ethylene, Hazard Class: 2.1; Labels: 2.1-Flammable gas; UN1038 Ethylene, refrigerated liquid (cryogenic liquid), Hazard Class: 2.1; Labels: 2.1- Flammable gas. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.

Purification Methods

Purify ethylene by passage through a series of towers containing molecular sieves or anhydrous CaSO4 or a cuprous ammonia solution, then conc H2SO4, followed by KOH pellets. Alternatively, it has been condensed in liquid nitrogen, with melting, freezing and pumping to remove air before passage through an activated charcoal trap, followed by a further condensation in liquid air. A sputtered sodium trap was used to remove oxygen. [Beilstein 1 IV 677.]


A highly flammable gas at room temperature. Contact with oxidizers may cause explosive polymerization and fire. May be spontaneously explosive in sunlight or ultraviolet light when mixed with chlorine. Reacts violently with mixtures of carbon tetrachloride and benzoyl peroxide; bromotrichloromethane; aluminum chloride and ozone. Incompatible with acids, halogens, nitrogen oxides; hydrogen bromide; aluminum chloride; chlorine dioxide; nitrogen dioxide. May accumulate static electrical charges, and may cause ignition of its vapors.

Waste Disposal

Return refillable compressed gas cylinders to supplier

ETHYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

ETHYLENE Suppliers

Global( 53)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
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Henan Tianfu Chemical Co.,Ltd.
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Mainchem Co., Ltd.
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Hubei Jusheng Technology Co.,Ltd.
86-188-71490254 CHINA 20094 58
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
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Energy Chemical 021-58432009 / 400-005-6266
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Shanghai Hanhong Scientific Co.,Ltd. 021-54306202,021-54308259
+86-21-54291107 China 43266 64
Chengdu Ai Keda Chemical Technology Co., Ltd. 4008-755-333 ; 028-86676798 ; 028-86757656
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Cheng Du Micxy Chemical Co.,Ltd 028-85632863 028-64559668 18048500443
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Quzhou Juhua Friendship Co., Ltd 0570-3066667,3062502
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