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(R)-VAPOL

CAS No.
147702-15-6
Chemical Name:
(R)-VAPOL
Synonyms
(R)-VAPOL;(S)-VAPOL;(S)-VAPOL 97%;(S)-VAPOL,99%e.e.;(S)-2,2'-DIPHENYL-(4-BIPHENANTHROL);(R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL);(3S)-2,2'-Diphenyl[3,3'-biphenanthrene]-4,4'-diol;(3S)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol;(3S)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol;3,3'-Biphenanthrene]-4,4'-diol, 2,2'-diphenyl-, (3S)-
CBNumber:
CB1450750
Molecular Formula:
C40H26O2
Molecular Weight:
538.63
MDL Number:
MFCD08459339
MOL File:
147702-15-6.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

(R)-VAPOL Properties

Melting point 185-191 °C
alpha +125.0° (c 1.0, THF)
Boiling point 712.2±60.0 °C(Predicted)
Density 1.286±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka 8.37±0.30(Predicted)
form Powder
color white to pale yellow
optical activity [α]20/D 128°, c = 1 in chloroform
InChIKey FXFOHEGGSYVOKR-UHFFFAOYSA-N
CAS DataBase Reference 147702-15-6

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08
Signal word  Warning
Hazard statements  H315-H319-H351
Precautionary statements  P201-P302+P352-P305+P351+P338-P308+P313
Hazard Codes  Xn
Risk Statements  37/38-40-41
Safety Statements  26-36/37/39-36/37-24/25-23
WGK Germany  3

(R)-VAPOL price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 675334 (S)-VAPOL 97% 147702-15-6 100mg $84 2024-03-01 Buy
Sigma-Aldrich 675334 (S)-VAPOL 97% 147702-15-6 500mg $400.2 2024-03-01 Buy
Strem Chemicals 08-1706 (3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (S)-VAPOL 147702-15-6 100mg $255 2024-03-01 Buy
Strem Chemicals 08-1706 (3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (S)-VAPOL 147702-15-6 500mg $1021 2024-03-01 Buy
Ambeed A929782 (3S)-2,2'-Diphenyl[3,3'-biphenanthrene]-4,4'-diol 98%99%ee 147702-15-6 1g $970 2021-12-16 Buy
Product number Packaging Price Buy
675334 100mg $84 Buy
675334 500mg $400.2 Buy
08-1706 100mg $255 Buy
08-1706 500mg $1021 Buy
A929782 1g $970 Buy

(R)-VAPOL Chemical Properties,Uses,Production

Reactions

  1. Chiral ligand in asymmetric autoinduction of Diels-Alder reactions.
  2. Chiral ligand used in catalytic asymmetric aziridination.
  3. Chiral ligand used in catalytic asymmetric imino aldol reaction.
  4. Chiral ligand used in catalytic asymmetric Petasis reaction. 
Reactions of 147702-15-6

Uses

VAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

(R)-VAPOL Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-VAPOL Suppliers

Global( 30)Suppliers
Supplier Tel Email Country ProdList Advantage
CR Corporation Lomited
fred.wen@crcorporation.cn CHINA 12069 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503259 +86-19930503259 cherry@crovellbio.com China 18457 58
LEAPCHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 43348 58
Aladdin Scientific
+1-833-552-7181 sales@aladdinsci.com United States 57511 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006608290; 18621169109 market03@meryer.com China 40241 62
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 6818 65
Shanghai Aladdin Bio-Chem Technology Co.,LTD 400-6206333 18521732826; market@aladdin-e.com China 25015 65
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41438 60
(3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT (3S)-(+)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT (R)-VAPOL (S)-2,2'-DIPHENYL-(4-BIPHENANTHROL) (S)-VAPOL (R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL) (3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-dioldichloromethaneadduct,min.98%(S)-VAPOL (3S)-(+)-2,2''-DIPHENYL-[3,3''-BIPHENANTHRENE]-4,4''-DIOL DICHLOROMETHANE ADDUCT (S)-VAPOL (S)-VAPOL 97% (S)-VAPOL,99%e.e. (3S)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane:3-(4-hydroxy-2-phenylphenanthren-3-yl)-2-phenylphenanthren-4-ol 3,3'-Biphenanthrene]-4,4'-diol, 2,2'-diphenyl-, (3S)- (3S)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol (3S)-2,2'-Diphenyl[3,3'-biphenanthrene]-4,4'-diol 147702-15-6 C40H26O2 BINOL Series Chiral Oxygen