Pyridinium tribromide
- CAS No.
- 39416-48-3
- Chemical Name:
- Pyridinium tribromide
- Synonyms
- PYRIDINIUM BROMIDE PERBROMIDE;PYRIDINIUM HYDROBROMIDE PERBROMIDE;PHBP;PYRIDINE HYDROBROMIDE PERBROMIDE;Pyridinium perbromide;PVPHP;PYRIDINIUM TRIBROMIDE;Pyridinium tribromider;pyridin-1-iuM tribroMide;Pyridinium Tribromide (>
- CBNumber:
- CB1478015
- Molecular Formula:
- C5H6Br3N-2
- Molecular Weight:
- 319.82
- MDL Number:
- MFCD00013223
- MOL File:
- 39416-48-3.mol
- MSDS File:
- SDS
Melting point | 127-133 °C |
---|---|
Density | 2.9569 (rough estimate) |
refractive index | 1.6800 (estimate) |
storage temp. | Store at <= 20°C. |
solubility | soluble in Methanol |
form | Powder, Crystals and/or Chunks |
color | Red-orange to red to brown |
Water Solubility | decomposes |
Sensitive | Lachrymatory |
Merck | 14,7973 |
BRN | 3690144 |
Stability | Stable. Incompatible with strong oxidizing agents, strong bases. |
InChIKey | YPCPFIMBGJOEKU-UHFFFAOYSA-O |
CAS DataBase Reference | 39416-48-3(CAS DataBase Reference) |
FDA UNII | W0AF353S0O |
EPA Substance Registry System | Pyridinium hydrogen tribromide (39416-48-3) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
|||||||||
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Signal word | Warning | |||||||||
Hazard statements | H315-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P304+P340+P312 | |||||||||
Hazard Codes | C,Xi | |||||||||
Risk Statements | 37/38-34-36 | |||||||||
Safety Statements | 26-36/37/39-45-24/25-27 | |||||||||
RIDADR | UN 3261 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 3 | |||||||||
Hazard Note | Lachrymatory | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29333100 | |||||||||
NFPA 704 |
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Pyridinium tribromide price More Price(36)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 133248 | Pyridinium tribromide technical grade, 90% | 39416-48-3 | 25g | $57.3 | 2024-03-01 | Buy |
Sigma-Aldrich | 8.14345 | Pyridinium bromide-perbromide for synthesis | 39416-48-3 | 50g | $107 | 2024-03-01 | Buy |
Sigma-Aldrich | 133248 | Pyridinium tribromide technical grade, 90% | 39416-48-3 | 100g | $114 | 2024-03-01 | Buy |
TCI Chemical | P0825 | Pyridinium Bromide Perbromide >85.0%(T) | 39416-48-3 | 25g | $36 | 2024-03-01 | Buy |
TCI Chemical | P0825 | Pyridinium Bromide Perbromide >85.0%(T) | 39416-48-3 | 100g | $95 | 2024-03-01 | Buy |
Pyridinium tribromide Chemical Properties,Uses,Production
Chemical Properties
red crystals
Uses
In small-scale brominations, where it is much more convenient and agreeable to measure and use than elemental bromine.
Uses
Pyridinium Tribromide is a reagent used in the α-thiocyanation of ketones and has also been applied to the synthesis of β-adrenergic blocking agents (also known as β-blockers) for patients with heart failure.
Uses
Pyridine hydrobromide perbromide is used as a brominating reagent in alfa-bromination and alfa-thiocyanation of ketones, phenols, unsaturated and aromatic ethers. It is used as a raw material in the preparation of beta-adrenergic blocking agents. Furthermore, it is used as an analytical reagent.
Purification Methods
It is a very good brominating agent-liberating one mol of Br2. Purify it by recrystallisation from glacial acetic acid (33g from 100mL of AcOH) to give orange-red crystals. [Fieser & Fieser Reagents for Organic Chemistry 1 967 1967, Englert & McElvain J Am Chem Soc 51 865 1929, Beilstein 20 II 103, 20/5 V 181.]
Pyridinium tribromide Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Nanjing Shunxiang Pharmaceutical Technology Co.,Ltd. | +86-86-02586819868 +8613913839793 | sales@jinchemical.com | China | 23 | 58 |
Changshu New Venture Imp.&Exp. Co.,Ltd. | 0512-52678575 13776233393 | nvchem_deng@163.com | China | 209 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
Hebei Saisier Technology Co., LTD | +86-18400010335 +86-13102810335 | admin@hbsaisier.cn | China | 747 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
NINGBO INNO PHARMCHEM CO., LTD. | 13867897135 | sales@nbinno.com | CHINA | 925 | 58 |
View Lastest Price from Pyridinium tribromide manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-04-18 | Pyridinium tribromide
39416-48-3
|
US $6.00 / KG | 1KG | More than 99% | 2000KG/MONTH | Hebei Saisier Technology Co., LTD | ||
2023-12-25 | Pyridinium tribromide
39416-48-3
|
US $0.00 / kg | 1kg | 99% | 1000000 | Hebei Jingbo New Material Technology Co., Ltd | ||
2023-08-18 | Pyridinium tribromide
39416-48-3
|
US $60.00 / KG | 25KG | 99.99% | 200ton | Hebei Mojin Biotechnology Co., Ltd |
- Pyridinium tribromide
39416-48-3
- US $6.00 / KG
- More than 99%
- Hebei Saisier Technology Co., LTD
- Pyridinium tribromide
39416-48-3
- US $0.00 / kg
- 99%
- Hebei Jingbo New Material Technology Co., Ltd
- Pyridinium tribromide
39416-48-3
- US $60.00 / KG
- 99.99%
- Hebei Mojin Biotechnology Co., Ltd