ChemicalBook >> CAS DataBase List >>DIMETHYLTHEXYLSILYL CHLORIDE
DIMETHYLTHEXYLSILYL CHLORIDE
- CAS No.
- 67373-56-2
- Chemical Name:
- DIMETHYLTHEXYLSILYL CHLORIDE
- Synonyms
- TDSCL;Chloro(dimethyl)thexylsilane 95%;Chloro(2,3-diMethylbutan-2-yl)diMethylsilane;TDSCI;DK359;THEXYLDIMETHYLCHLOROSILANE;Thexyldimethylsilylchlorid;Chlorothexyldimethylsilane;n-diMethylhexylchlorosilane;DIMETHYL-THEXYLCHLOROSILANE
- CBNumber:
- CB1485754
- Molecular Formula:
- C8H19ClSi
- Molecular Weight:
- 178.77
- MDL Number:
- MFCD00012175
- MOL File:
- 67373-56-2.mol
- MSDS File:
- SDS
Last updated:2023-06-08 17:06:38
| Melting point | 15 °C |
|---|---|
| Boiling point | 55-56 °C10 mm Hg(lit.) |
| Density | 0.909 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 125 °F |
| storage temp. | Sealed in dry,2-8°C |
| solubility | sol in THF, DMF, CH2Cl2. |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Specific Gravity | 0.911 |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| Sensitive | Moisture Sensitive |
| BRN | 3647960 |
| InChIKey | KIGALSBMRYYLFJ-UHFFFAOYSA-N |
| CAS DataBase Reference | 67373-56-2(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H314 | |||||||||
| Precautionary statements | P210-P233-P240-P280-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 10-34-37 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 2986 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| TSCA | No | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
DIMETHYLTHEXYLSILYL CHLORIDE price More Price(13)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 302449 | Chloro(dimethyl)thexylsilane 95% | 67373-56-2 | 25g | $105 | 2024-03-01 | Buy |
| Sigma-Aldrich | 302449 | Chloro(dimethyl)thexylsilane 95% | 67373-56-2 | 100g | $211.8 | 2024-03-01 | Buy |
| TCI Chemical | T2116 | Chloro(dimethyl)thexylsilane >95.0%(GC) | 67373-56-2 | 5g | $117 | 2024-03-01 | Buy |
| TCI Chemical | T2116 | Chloro(dimethyl)thexylsilane >95.0%(GC) | 67373-56-2 | 25g | $239 | 2023-01-07 | Buy |
| TRC | D461043 | DimethylthexylsilylChloride | 67373-56-2 | 500mg | $75 | 2021-12-16 | Buy |
DIMETHYLTHEXYLSILYL CHLORIDE Chemical Properties,Uses,Production
Chemical Properties
clear colorless to almost colorless liquid
Physical properties
mp 14–15 °C; bp 55–56 °C/10 mmHg; d 0.909 g cm?3.
Uses
Silylating reagent for the protection of 1? and 2? alcohols and N-silylation of amines and amides; used in the preparation of thexyldimethylsilyl triflate; formation of α-silyl hydrazones; formylation of polyfluoroalkyl halides. Thexyldimethylsilyl chloride (TDS-Cl) was first introduced as a more easily prepared alternative to the more commonly used t-butyldimethylsilyl chloride for the protection of alcohols.
Uses
Protecting reagent for alcohols and other functional groups. Employed in the synthesis of silicon naphthocyanine and cyclodextrin derivatives, which are useful as antitumor dyes and chiral stationary phases, respectively.
Preparation
To a mixture of dimethylchlorosilane (10 mL, 92 mmol) and AlCl3 (0.680 g, 5 mmol) at 25°Cwas added 2,3-dimethyl-2-butene (11 mL, 91 mmol). After stirring for 4 h at ambient temperature, the mixture was filtered and distilled to yield 15.2 g of TDS-Cl (93%).
Purification Methods
Purify it by fractional distillation and store it in small aliquots in sealed ampoules. It is very sensitive to moisture and is estimated by dissolving an aliquot in excess of 0.1M NaOH and titrating with 0.1M HCl using methyl red as indicator [Szabó et al. Helv Chim Acta 67 2128 1984].
DIMETHYLTHEXYLSILYL CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 126)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 47465 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
| SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | contact@trustwe.com | China | 5738 | 58 |
| WinWin Chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 13854 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | CHINA | 52867 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25363 | 58 |
View Lastest Price from DIMETHYLTHEXYLSILYL CHLORIDE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-02-05 | DIMETHYLTHEXYLSILYL CHLORIDE
67373-56-2
|
US $1.00 / KG | 1KG | 98%-99.9%HPLC | 100KG | Career Henan Chemical Co |
-
- DIMETHYLTHEXYLSILYL CHLORIDE
67373-56-2
- US $1.00 / KG
- 98%-99.9%HPLC
- Career Henan Chemical Co
67373-56-2(DIMETHYLTHEXYLSILYL CHLORIDE)Related Search:
CHLOROMETHYLPHENYLSILANE
N-BUTYLDIMETHYLCHLOROSILANE
ALLYLDIMETHYLCHLOROSILANE
Chloro(chloromethyl)dimethylsilane
n-Octyldimethylchlorosilane
Chlorodimethyloctadecylsilane
1H,1H,2H,2H-PERFLUOROOCTYLDIMETHYLCHLOROSILANE
Chlorodimethylpentafluorophenylsilane
Chlorodimethylphenylsilane
tert-Butyldimethylsilyl chloride
1of4
Chlorodimethyl(1,1,2-trimethylpropyl)silane
Dimethylthexylsilyl Chloride
n-diMethylhexylchlorosilane
Dimethyl(1,1,2-trimethylpropyl)silyl chloride
Chloro(dimethyl)thexylsilane(Dimethylthexylsilyl chloride、TDSCI)
TDSCI
THEXYLDIMETHYLCHLOROSILANE
THEXYLDIMETHYLSILYL CHLORIDE
DIMETHYL-THEXYLCHLOROSILANE
DIMETHYLTHEXYLSILYL CHLORIDE
DIMETHYL-(2,3-DIMETHYL-2-BUTYL)CHLOROSILANE
CHLORO-DIMETHYL-THEXYLSILANE
CHLORODIMETHYL(1,1,2-TRIMETHYLPROPYL)SILANE
Thexyldimethylsilylchlorid
Chlorodimethylthexylsilane~Dimethyl(2,3-dimethylbutyl)chlorosilane~Dimethylthexylsilylchloride
Thexyldimethylchlorosilane,95%
ThexyldimethylchlorosilaneTDSCl
Silane, chlorodimethyl(1,1,2-trimethylpropyl)-
dimethyl(2,3-dimethylbutyl)chlorosilane
Chloro-dimethyl-(2,3-dimethyl-2-butyl)-silane
Chlorodimethyl(1,1,2-trimethylpropyl)silane, Dimethyl-(2,3-dimethyl-2-butyl)chlorosilane, Dimethyl-thexylchlorosilane, Dimethylthexylsilyl chloride, TDSCl, Thexyldimethylsilyl chloride
Chlorothexyldimethylsilane
Chlorodimethylthexylsilane,95%
Chloro(2,3-diMethylbutan-2-yl)diMethylsilane
Chloro(dimethyl)thexylsilane 95%
TDSCL
DK359
67373-56-2
CH32CHCCH32SiCH32Cl
Protecting and Derivatizing Reagents
Protection and Derivatization
Silicon-Based
Synthetic Reagents