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4-Bromobenzoic acid

4-Bromobenzoic acid
4-Bromobenzoic acid
Chemical Name:
4-Bromobenzoic acid
'LGC' (4008);AKOS BBS-00003716;p-bromo-benzoicaci;4-bromo-benzoicaci;4-Brom-benzoic acid;4-Bromobenzoic aicd;4-BroMo bezoic acid;P-BROMOBENZOIC ACID;RARECHEM AL BO 0052;4-BROMOBENZOIC ACID
Molecular Formula:
Formula Weight:
MOL File:

4-Bromobenzoic acid Properties

Melting point:
252-254 °C(lit.)
1,894 g/cm3
refractive index 
1.6080 (estimate)
storage temp. 
ethanol: soluble5%
Crystals or Powder
3.96(at 25℃)
White to beige to pink-brownish
Water Solubility 
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
586-76-5(CAS DataBase Reference)
NIST Chemistry Reference
Benzoic acid, 4-bromo-(586-76-5)
EPA Substance Registry System
Benzoic acid, 4-bromo-(586-76-5)
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xn,Xi
Risk Statements  22-36/37/38-36-37/38
Safety Statements  26-36-24/25-22-37/39
WGK Germany  3
RTECS  DG4448050
Hazard Note  Irritant
HS Code  29163900
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P501 Dispose of contents/container to..…

4-Bromobenzoic acid price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 108510 4-Bromobenzoic acid 98% 586-76-5 25g $41.3 2018-11-13 Buy
Sigma-Aldrich 108510 4-Bromobenzoic acid 98% 586-76-5 100g $117 2018-11-13 Buy
TCI Chemical B0553 4-Bromobenzoic Acid >98.0%(GC)(T) 586-76-5 25g $31 2018-11-22 Buy
TCI Chemical B0553 4-Bromobenzoic Acid >98.0%(GC)(T) 586-76-5 100g $94 2018-11-22 Buy
Alfa Aesar A12518 4-Bromobenzoic acid, 98+% 586-76-5 100g $116 2018-11-13 Buy

4-Bromobenzoic acid Chemical Properties,Uses,Production

Chemical Properties

White to light yellow crystal powder


ChEBI: A bromobenzoic acid carrying a single bromo subsituent at the 4-position.

General Description

Colorless to red crystals.

Reactivity Profile

Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in 4-Bromobenzoic acid to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.

Health Hazard

ACUTE/CHRONIC HAZARDS: Explodes above its melting point.

Purification Methods

Crystallise the acid from MeOH, or MeOH/water mixture, 90% EtOH and Et2O. The methyl ester has m 81o from Et2O or dilute MeOH. The anilide has m 197o (from EtOH). [Male & Thorp J Am Chem Soc 35 269 1913, Lamneck J Am Chem Soc 76 406 1954, Vandenbelt et al. Anal Chem 26 926 1954, Beilstein 9 IV 1017.]

4-Bromobenzoic acid Preparation Products And Raw materials

Raw materials

Preparation Products

4-Bromobenzoic acid Suppliers

Global( 306)Suppliers
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Henan DaKen Chemical CO.,LTD.
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4-Bromobenzoic acid Spectrum

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