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4-Bromobenzoic acid

4-Bromobenzoic acid
4-Bromobenzoic acid structure
CAS No.
586-76-5
Chemical Name:
4-Bromobenzoic acid
Synonyms
'LGC' (4008);AKOS BBS-00003716;4-bromo-benzoicaci;p-bromo-benzoicaci;RARECHEM AL BO 0052;P-BROMOBENZOIC ACID;4-BroMo bezoic acid;4-BROMOBENZOIC ACID;4-Bromobenzoic aicd;4-Brom-benzoic acid
CBNumber:
CB1490484
Molecular Formula:
C7H5BrO2
Formula Weight:
201.02
MOL File:
586-76-5.mol

4-Bromobenzoic acid Properties

Melting point:
252-254 °C(lit.)
Boiling point:
116 °C(Press: 15-16 Torr)
Density 
1,894 g/cm3
refractive index 
1.6080 (estimate)
storage temp. 
-20°C
solubility 
ethanol: soluble5%
pka
3.96(at 25℃)
form 
Crystals or Powder
color 
White to beige to pink-brownish
Water Solubility 
SOLUBLE IN HOT WATER
Merck 
14,1408
BRN 
1906923
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
TUXYZHVUPGXXQG-UHFFFAOYSA-N
CAS DataBase Reference
586-76-5(CAS DataBase Reference)
EWG's Food Scores
1
FDA UNII
6992P6102O
NIST Chemistry Reference
Benzoic acid, 4-bromo-(586-76-5)
EPA Substance Registry System
4-Bromobenzoic acid (586-76-5)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P280a-P304+P340-P405-P501a-P261-P305+P351+P338-P264-P270-P280-P301+P312+P330-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P501
Hazard Codes  Xn,Xi
Risk Statements  22-36/37/38-36-37/38
Safety Statements  26-36-24/25-22-37/39
WGK Germany  3
RTECS  DG4448050
Hazard Note  Irritant
TSCA  Yes
HS Code  29163900

4-Bromobenzoic acid price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 108510 4-Bromobenzoic acid 98% 586-76-5 25g $41.8 2019-12-02 Buy
Sigma-Aldrich 108510 4-Bromobenzoic acid 98% 586-76-5 100g $119 2019-12-02 Buy
TCI Chemical B0553 4-Bromobenzoic Acid >98.0%(GC)(T) 586-76-5 25g $32 2020-06-24 Buy
TCI Chemical B0553 4-Bromobenzoic Acid >98.0%(GC)(T) 586-76-5 100g $95 2020-06-24 Buy
Alfa Aesar A12518 4-Bromobenzoic acid, 98+% 586-76-5 25g $41.8 2020-06-24 Buy

4-Bromobenzoic acid Chemical Properties,Uses,Production

Chemical Properties

White to light yellow crystal powder

Definition

ChEBI: A bromobenzoic acid carrying a single bromo subsituent at the 4-position.

General Description

Colorless to red crystals.

Reactivity Profile

Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in 4-Bromobenzoic acid to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.

Health Hazard

ACUTE/CHRONIC HAZARDS: Explodes above its melting point.

Purification Methods

Crystallise the acid from MeOH, or MeOH/water mixture, 90% EtOH and Et2O. The methyl ester has m 81o from Et2O or dilute MeOH. The anilide has m 197o (from EtOH). [Male & Thorp J Am Chem Soc 35 269 1913, Lamneck J Am Chem Soc 76 406 1954, Vandenbelt et al. Anal Chem 26 926 1954, Beilstein 9 IV 1017.]

4-Bromobenzoic acid Preparation Products And Raw materials

Raw materials

Preparation Products


4-Bromobenzoic acid Suppliers

Global( 357)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Springchem New Material Technology Co.,Limited
86-21-51752791
86-21-51752789 info@spring-chem.com China 1765 57
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0086 158 5814 5714 (Mobile
+86-571-56059825 fandachem@gmail.com CHINA 3269 55
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View Lastest Price from 4-Bromobenzoic acid manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2020-07-06 4-Bromobenzoic Acid;p-Bromobenzoic Acid;p-bromobenzenecarboxylicacid
586-76-5
US $0.00 / Kg/Bag 1KG 99% 1000kg QINGDAO HONG JIN CHEMCIAL CO.,LTD.
2019-07-12 4-Bromobenzoic acid
586-76-5
US $8.80 / KG 1KG 97%-99% 100kg career henan chemical co

4-Bromobenzoic acid Spectrum


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