(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL

CAS No.
137365-09-4
Chemical Name:
(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL
Synonyms
(-)-DINOL;(4R-TRANS)-2 2-DI-ME-A A A' A'-TETRA-2-&;(4R-trans)-2,2-di-me-A,A,A,A-tetra-2-nap -dioxo;(-)-2,3-o-Isopropylidene-1,1,4,4-tetra(2-naph.)-L-threitol;2,2-dimethyltetra(2-naphthyl)-1,3-dioxolane-4,5-dimethanol;(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL;(R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL;(4r,5r)-2,2-dimethyl-α,α,α',α'-tetra(2-naphthyl)dioxolane-4,5-dimethanol;(4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra(2-naphthyl)dioxolane-4,5-dimethanol;(-)-DINOL, (-)-2,3-O-Isopropylidene-1,1,4,4-tetra(2-naphthyl)-L-threitol
CBNumber:
CB1492655
Molecular Formula:
C47H38O4
Molecular Weight:
666.8
MDL Number:
MFCD00142337
MOL File:
137365-09-4.mol
MSDS File:
SDS

(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL Properties

Melting point 213-216 °C (lit.)
storage temp. 2-8°C
optical activity [α]20/D 116±2°, c = 1% in ethyl acetate
BRN 6168481

SAFETY

Risk and Safety Statements

WGK Germany  3
10

(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 59490 (4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetra(2-naphthyl)dioxolane-4,5-dimethanol ≥99.0%(sumofenantiomers,HPLC) 137365-09-4 1g $180 2024-03-01 Buy
TRC D479455 (4R,5R)-2,2-Dimethyl-α,α,α'',α''-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol 137365-09-4 1g $190 2021-12-16 Buy
TRC D479455 (4R,5R)-2,2-Dimethyl-α,α,α'',α''-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol 137365-09-4 5g $920 2021-12-16 Buy
American Custom Chemicals Corporation CRB0000036 (-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA (2-NAPHTHYL)-L-THREITOL 95.00% 137365-09-4 1G $904.71 2021-12-16 Buy
Crysdot CD11270048 ((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-2-yl)methanol) 95+% 137365-09-4 10g $1439 2021-12-16 Buy
Product number Packaging Price Buy
59490 1g $180 Buy
D479455 1g $190 Buy
D479455 5g $920 Buy
CRB0000036 1G $904.71 Buy
CD11270048 10g $1439 Buy

(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL Chemical Properties,Uses,Production

Uses

(4R,5R)-2,2-Dimethyl-α,α,α'',α''-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol, is a privileged ligand analogue of TADDOLs. It can be broadly used in asymmetric synthesis. It is also shown that the titanium TADDOLate catalysts have broad application towards carbonyl addition and cycloaddition.

(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL Preparation Products And Raw materials

Raw materials

Preparation Products

(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL Suppliers

Global( 28)Suppliers
Supplier Tel Email Country ProdList Advantage
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
Aladdin Scientific
+1-833-552-7181 sales@aladdinsci.com United States 52927 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94838 76
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Adamas Reagent, Ltd. 400-6009262 16621234537 zhangsn@titansci.com China 14113 59
Tianjin Derchemist Science & Technology Co., Ltd. 22-58627059 13920586291 zdcomcon@126.com China 2918 50
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Shanghai Chiral bio-compound co., Ltd. 021-5068 3667/17749785980/1029026415; 17749785980 1029026415@qq.com China 2790 58
Shandong Ono Chemical Co., Ltd. 0539-6362799 20) China 9998 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 021-88888888 420970979@qq.com China 2806 58
(R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL (-)-DINOL (4R-TRANS)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(2-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOL (4R,5R)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(2-NAPHTHYL)DIOXOLANE-4,5-DIMETHANOL (-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRA(2-NAPHTHYL)-L-THREITOL (4R-trans)-2,2-di-me-A,A,A,A-tetra-2-nap -dioxo (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(2-naphthyl)dioxolane-4,5-di (4R-TRANS)-2 2-DI-ME-A A A' A'-TETRA-2-& (-)-2,3-o-Isopropylidene-1,1,4,4-tetra(2-naph.)-L-threitol (4R,5R)-2,2-DiMethyl-α,α,α`,α`-tetra(2-naphthyl)-1,3-dioxolane-4,5-diMethanol (4r,5r)-2,2-dimethyl-α,α,α',α'-tetra(2-naphthyl)dioxolane-4,5-dimethanol 2,2-dimethyltetra(2-naphthyl)-1,3-dioxolane-4,5-dimethanol (-)-DINOL, (-)-2,3-O-Isopropylidene-1,1,4,4-tetra(2-naphthyl)-L-threitol (4R,5R)-2,2-DiMethyl-α,α,α',α'-tetra-2-naphthalenyl-1,3-dioxolane-4,5-diMethanol (4R,5R)-2,2-dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-1,3-Dioxolane-4,5-dimethanol ((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-2-yl)methanol) 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-, (4R,5R)- (4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra(2-naphthyl)dioxolane-4,5-dimethanol "(4R,5R)-2,2-Dimethyl-a,a,a,a-tetra-2-naphthalenyl-1,3-dioxolane-4,5-dimethanol" (4R,5R)-2,2-dimethyl-α4,α4,α5,α5-tetra-2-naphthalenyl-1,3-Dioxolane-4,5-dimethanol 137365-09-4 C47H38O4 Asymmetric Synthesis TADDOLs Privileged Ligands Chiral Catalysts, Ligands, and Reagents