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Zineb

Zineb
Zineb structure
CAS No.
12122-67-7
Chemical Name:
Zineb
Synonyms
ZEB;zidan;aspor;cineb;Zineb;tsineb;unizeb;zebtox;daisen;dipher
CBNumber:
CB1497049
Molecular Formula:
C4H6N2S4Zn
Formula Weight:
275.75
MOL File:
12122-67-7.mol

Zineb Properties

Melting point:
157°C (rough estimate)
Flash point:
90℃
storage temp. 
2-8°C
form 
Water-Insoluble Powder
Merck 
13,10220
BRN 
4165797
InChIKey
AMHNZOICSMBGDH-UHFFFAOYSA-L
CAS DataBase Reference
12122-67-7(CAS DataBase Reference)
EPA Substance Registry System
Zinc, [[2-[(dithiocarboxy)amino] ethyl]carbamodithioato(2-)-. kappa.S,.kappa.S']-(12122-67-7)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi
Risk Statements  37-43
Safety Statements  8-24/25-46
RIDADR  UN 3077 9 / PGIII
WGK Germany  3
RTECS  ZH3325000
HS Code  29309090
Hazardous Substances Data 12122-67-7(Hazardous Substances Data)
Toxicity LD50 orally in rats: >5000 mg/kg (Gaines)
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Zineb price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 45707 Zineb technical mixture 12122-67-7 250mg $22.2 2018-11-20 Buy

Zineb Chemical Properties,Uses,Production

Description

Zineb is a light-coloured powder/crystal and insoluble in water. Zineb is one of the nonsystemic (surface-acting) fungicides of the group ethylenebisdithiocarbamates (EBDCs). Zineb is a polymer of ethylene (bis)thiocarbamate units linked with zinc and used for the control and prevention of crop damage in the field and also to protect harvested crops from deterioration during storage or transport. Zineb was used to protect fruit and vegetable crops from a wide range of foliar and other diseases. It was available in the United States as wettable powder and dust formulations. Zineb can be formed by combining nabam and zinc sulphate in the spray tank.

Chemical Properties

Light-tan solid. Insoluble in water; soluble in pyridine; decomposes on heating.

Uses

Agricultural fungicide.

Definition

ChEBI: A polymeric complex of zinc with the ethylene bis(dithiocarbamate) anionic ligand. Formerly used as an agricultural fungicide for the control of downy mildews and rusts, its use is no longer permitted in the US or the EU.

General Description

An off-white powder. Used as a fungicide.

Air & Water Reactions

Decomposes gradually, accelerated by exposure to air, moisture, and heat. Insoluble in water. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.

Reactivity Profile

Zineb is a zinc salt of a dithiocarbamic acid. May generate flammable gases with aldehydes, nitrides, and hydrides. Incompatible with acids, peroxides, and acid halides.

Hazard

Toxic by inhalation and ingestion; irritant to eyes and mucous membranes. Questionable carcinogen.

Fire Hazard

Flash point data for Zineb are not available, but Zineb is probably combustible.

Contact allergens

Zineb is a pesticide of the dithiocarbamate group. Sensitization can occur in gardeners and florists.

Purification Methods

Crystallise this herbicide several times from hot toluene or from hot CHCl3 by addition of EtOH. It is a skin irritant. [Beilstein 4 III 149, 4 IV 234.]

Zineb Preparation Products And Raw materials

Raw materials

Preparation Products


Zineb Suppliers

Global( 84)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21830 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20676 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32452 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 25796 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23957 58
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20084 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 8267 58
Shandong chuangyingchemical Co., Ltd.
13156170209
sale@chuangyingchem.com CHINA 2717 58
WUXI HONORSHINE CHEMICAL CO.,LTD. +86-0510-83593312 13665125081
+86-0510-83574508 sales@honorshinechem.com China 58 60
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96512 76

View Lastest Price from Zineb manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-20 Zineb
12122-67-7
US $1.00 / kg 1kg 99% Customized career henan chemical co

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