ChemicalBook
Chinese Japanese Germany

4,4'-Oxydianiline

4,4'-Oxydianiline
4,4'-Oxydianiline
CAS No.
101-80-4
Chemical Name:
4,4'-Oxydianiline
Synonyms
ODA;ODC;Dadpe;4,4'-ODA;4,4'-DPE;4,4'-DADPE;NCI-C50146;Oxydianiline;4,4'-Diamino;4-AMinophenyle
CBNumber:
CB1689134
Molecular Formula:
C12H12N2O
Formula Weight:
200.24
MOL File:
101-80-4.mol

4,4'-Oxydianiline Properties

Melting point:
188-192 °C(lit.)
Boiling point:
190 °C (0.1 mmHg)
Density 
1.1131 (rough estimate)
vapor pressure 
10 mm Hg ( 240 °C)
refractive index 
1.6660 (estimate)
Flash point:
426 °F
storage temp. 
Store below +30°C.
form 
Solid
color 
White
Water Solubility 
Insoluble. <0.01 g/100 mL at 15 ºC
BRN 
475735
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents. Hygroscopic.
InChIKey
HLBLWEWZXPIGSM-UHFFFAOYSA-N
CAS DataBase Reference
101-80-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzenamine, 4,4'-oxybis-(101-80-4)
EPA Substance Registry System
Benzenamine, 4,4'-oxybis-(101-80-4)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,N
Risk Statements  45-46-23/24/25-51/53-62-36/37/38-22-50/53-43
Safety Statements  53-45-61-36/37-26-20-60
RIDADR  UN 3077 9/PG 3
WGK Germany  3
RTECS  BY7900000
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29222900
Hazardous Substances Data 101-80-4(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H340 May cause genetic defects Germ cell mutagenicity Category 1A, 1B Danger
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P311 Call a POISON CENTER or doctor/physician.
P391 Collect spillage. Hazardous to the aquatic environment
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P501 Dispose of contents/container to..…

4,4'-Oxydianiline price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 247278 4,4′-Oxydianiline zone-refined, purified by sublimation, ≥99% 101-80-4 1g $41.1 2018-11-13 Buy
Sigma-Aldrich 247278 4,4′-Oxydianiline zone-refined, purified by sublimation, ≥99% 101-80-4 5g $136 2018-11-13 Buy
TCI Chemical O0088 4,4'-Diaminodiphenyl Ether >98.0%(GC)(T) 101-80-4 25g $26 2018-11-22 Buy
TCI Chemical O0088 4,4'-Diaminodiphenyl Ether >98.0%(GC)(T) 101-80-4 500g $164 2018-11-22 Buy
Alfa Aesar A16815 Bis(4-aminophenyl) ether, 98% 101-80-4 100g $48.9 2018-11-13 Buy

4,4'-Oxydianiline Chemical Properties,Uses,Production

Chemical Properties

Colorless crystalline

Chemical Properties

4-Aminophenyl ether is a resin used in the manufacture of a variety of industrial products. For example as, insulating varnishes, flame-retardant fi bers, wire enamels, coatings, and fi lms. It is also used for the manufacture of other fi re-resistant products.

Chemical Properties

4,40′-Oxydianiline is a white crystalline solid, or a beige powder.

Uses

Bis(p-aminophenyl) Ether is a reagent used in the preparation of polyimide-silica composite membranes for gas separation techniques. In addition, it is used in the synthesis of polymer films for elect rolyte membranes.

Uses

4,4'-diaminodiphenylether be used for preparation polyimide and epoxy resin material.

General Description

Odorless colorless crystals or an odorless fine, beige powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4,4'-Oxydianiline oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. A mixture of liquid air and diethyl ether exploded spontaneously [MCA Case History 616(1960)].

Health Hazard

4-Aminophenyl ether is highly toxic to animals. There is suffi cient evidence as a carcinogenicity and has caused adenomas and carcinomas in the thyroid and liver of experimental rats.

Fire Hazard

4,4'-Oxydianiline is combustible.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx

Potential Exposure

Intermediate in the manufacture of high-temperature-resistant, straight polyimide and poly (esterimide) resins capable of withstanding temperatures of Up to 480°C for short periods or 260°C for prolonged periods of time. Some p-phenylenediamine compounds have been used as rubber components, and DFG warns of danger of skin sensitization.

First aid

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth methods if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device? Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In the case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.
Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24-48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.

Shipping

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Slowly hydrolyzes in water, releasing ammonia, and forming acetate salts. Decomposes at 265C releasing toxic oxides of nitrogen, sulfur, and carbon. Decomposed by strong ultraviolet light.

Waste Disposal

Incineration with provision for nitrogen oxides removal from flue gases.

4,4'-Oxydianiline Preparation Products And Raw materials

Raw materials

Preparation Products


4,4'-Oxydianiline Suppliers

Global( 267)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22049 58
Dalian Richfortune Chemicals Co., Ltd
86-411-84820922, 84821539
86-411-84821380 sales@richfortunechem.com China 362 57
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32651 55
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 marketing@haihangchem.com CHINA 4535 58
Jilin Province Yanshen Technology Co., Ltd.
17743007828
Extension@san-bangchem.com CHINA 637 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 10967 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19990 58
Changzhou Sunchem Pharmaceutical Chemical Material Co.,Ltd. 0519-85269522;13660798926
013660798926 850311@sunkechem.com China 100 60
Changzhou GuangJia Chemical Co. Ltd. 86-0519-85267898 18015075973 13775212501
86-0519-85267898 sales@guanjiachem.net China 17 55
Changzhou josenchem Pharmaceutical Chemical Material Co.,Ltd. +86-519-8528 6950 (0)13338194135
+86-519-85286950 info@josenchem.com China 80 58

View Lastest Price from 4,4'-Oxydianiline manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-08-03 4,4'-Oxydianiline
101-80-4
US $100.00 / KG 1KG 99% Customized career henan chemical co

4,4'-Oxydianiline Spectrum


101-80-4(4,4'-Oxydianiline)Related Search:


Copyright 2017 © ChemicalBook. All rights reserved