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α-Methylcinnamaldehyde

CAS No.
101-39-3
Chemical Name:
α-Methylcinnamaldehyde
Synonyms
α-Methylcinnamaldehyde;a-Methyl-trans-cinnaMaldehyde;A-METHYLCINNAMALDEHYDE;FEMA 2697;alpha-Methylzimtaldehyd;METHYL CINNAMIC ALDEHYDE;2-methyl-3-phenyl-2-propenal;METHYLZIMTALDEHYD;AKOS BBS-00003193;α-MethylcinnaMalde
CBNumber:
CB1694703
Molecular Formula:
C10H10O
Molecular Weight:
146.19
MDL Number:
MFCD00006976
MOL File:
101-39-3.mol
MSDS File:
SDS
Last updated:2023-09-27 18:48:59

α-Methylcinnamaldehyde Properties

Boiling point 148-149 °C27 mm Hg(lit.)
Density 1.047 g/mL at 25 °C(lit.)
refractive index n20/D 1.605(lit.)
FEMA 2697 | ALPHA-METHYLCINNAMALDEHYDE
Flash point 175 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform, Methanol (Slightly)
form Oil
color Colourless
Odor at 100.00 %. sweet cinnamon spicy cassia
Odor Type spicy
Water Solubility <0.1 g/100 mL at 21 ºC
Sensitive Air Sensitive
JECFA Number 683
BRN 507514
Stability Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.
InChIKey VLUMOWNVWOXZAU-VQHVLOKHSA-N
LogP 2.68
CAS DataBase Reference 101-39-3(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) ALPHA-METHYLCINNAMALDEHYDE
FDA 21 CFR 172.515
FDA UNII 1C647N9853
NIST Chemistry Reference 2-Propenal, 2-methyl-3-phenyl-(101-39-3)
EPA Substance Registry System .alpha.-Methylcinnamaldehyde (101-39-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H227-H335-H315-H319
Precautionary statements  P210e-P261-P280a-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  24/25
WGK Germany  1
RTECS  GD6600000
TSCA  Yes
HS Code  29122900
NFPA 704
2
2 0

α-Methylcinnamaldehyde price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 112275 α-Methyl-trans-cinnamaldehyde 98% 101-39-3 50g $45.6 2024-03-01 Buy
Sigma-Aldrich W269700 α-Methylcinnamaldehyde ≥97%,FCC,FG 101-39-3 10Kg $273 2023-01-07 Buy
Sigma-Aldrich W269700 α-Methylcinnamaldehyde ≥97%, FCC, FG 101-39-3 sample-k $52 2022-05-15 Buy
TCI Chemical M0584 alpha-Methylcinnamaldehyde >95.0%(GC) 101-39-3 25g $86 2024-03-01 Buy
TCI Chemical M0584 alpha-Methylcinnamaldehyde >95.0%(GC) 101-39-3 500g $345 2024-03-01 Buy
Product number Packaging Price Buy
112275 50g $45.6 Buy
W269700 10Kg $273 Buy
W269700 sample-k $52 Buy
M0584 25g $86 Buy
M0584 500g $345 Buy

α-Methylcinnamaldehyde Chemical Properties,Uses,Production

Description

α-Methylcinnamaldehyde has a characteristic cinnamon-type odor with a soft, spicy flavor. May be synthesized by condensing benzaldehyde with propionic aldehyde in the presence of a 1% caustic soda solution; also by the controlled hydrogenation of α-methylcinnamic aldehyde.

Chemical Properties

α-Methylcinnamaldehyde has a characteristic cinnamon-type odor and a soft, spicy flavor.

Chemical Properties

yellow liquid

Occurrence

Reported found in peppermint oil, sherry and mint

Uses

alpha-Methyl-trans-cinnamaldehyde is a compound with antifungal activity for proteomics research use.

Preparation

By condensing benzaldehyde with propionic aldehyde in the presence of a 1% caustic soda solution; also by the controlled hydrogenation of α-methylcinnamic aldehyde

Taste threshold values

Taste characteristics at 30 ppm: spice, cinnamon, sweet, woody with a slight pungent and hot bite

Synthesis Reference(s)

The Journal of Organic Chemistry, 55, p. 2878, 1990 DOI: 10.1021/jo00296a059
Tetrahedron Letters, 28, p. 1263, 1987 DOI: 10.1016/S0040-4039(00)95341-3

General Description

Clear yellow liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

alpha-Methylcinnamaldehyde is incompatible with strong oxidizing agents and strong bases.

Fire Hazard

alpha-Methylcinnamaldehyde is combustible.

Biochem/physiol Actions

α-Methyl trans cinnamaldehyde has antifungal activity. It is self coupled and complexed with Co(II) and Ni(II) to synthesize ligand and complexes.

Safety Profile

Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.

α-Methylcinnamaldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 431)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
career henan chemical co
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SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293 sales@sdzschem.com China 2931 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Jinan Finer Chemical Co., Ltd
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Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845 sales@amoychem.com China 6387 58

View Lastest Price from α-Methylcinnamaldehyde manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
alpha-Methylcinnamaldehyde pictures 2023-09-27 alpha-Methylcinnamaldehyde
101-39-3
US $0.00-0.00 / kg 1kg 0.99 50000kg Hebei Yibangte Import and Export Co. , Ltd.
α-Methylcinnamaldehyde pictures 2023-08-26 α-Methylcinnamaldehyde
101-39-3
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
alpha-Methylcinnamaldehyde pictures 2023-04-14 alpha-Methylcinnamaldehyde
101-39-3
US $67.00 / kg 1kg 99% 5000 Ton Hebei Duling International Trade Co. LTD
2-methyl-3-phenyl-2-propena METHYL CINNAMIC ALDEHYDE, ALPHA LABOTEST-BB LT00928083 3-PHENYLMETHACROLEIN 3-Phenyl-2-methyl acrolein ALPHA-METHYLCINNAMALDEHYDE ALPHA-METHYL CINNAMIC ALDEHYDE 2-METHYL CINNAMIC ALDEHYDE 2-METHYL-3-PHENYL-2-PROPEN-1-AL 2-METHYL-3-PHENYLPROPENAL 2-METHYL-3-PHENYLACROLEIN a-Methyl Cinnamic Aldehyde ALPHA-METHYL-TRANS-CINNAMALDEHYDE 97+%& ALFA-METHYLCINNAMALDEHYDE à-methylcinnamaldehyde α-methyl-trans-cinnamaldehyde PARA-METHOXY-ALPHA-CINNAMALDEHYDE METHYLZIMTALDEHYD ALPHA-METHYLCINNAMYLALDHYDE Alph-methyl cinnamaldehyde ɑ-Methylcinnamaldehyde, predominantly (E), 97% ALPHA-METHYL-TRANS-CINNAMALDEHYDE AKOS BBS-00003193 alpha-Methylcinnamaldehyde,98% 3-Phenyl-2-methylacrylaldehyde α-Methylbenzeneacrylaldehyde α-Methylbenzenepropenal ^a-Methylcinnamaldehyde, predominantly (E), 97% 2-Methyl-3-phenylacrylaldehyde 2-methyl-3-phenyl-prop-2-enal 2-propenal,2-methyl-3-phenyl- alpha-methyl-cinnamaldehyd alpha-Methylcinnimal Cinnamaldehyde, alpha-methyl- Cinnamic aldehyde, .alpha.-methyl -Methylcinnamylaldhyde alpha-Methylcinnamaldehyde, predominantly (E), 97% -Methylcinnamaldehyde, FCC, 97+% α-Methyl-trans-ciamaldehyde α-MethylcinnaMalde 2-Methyl-3-phenylacrolein 3-Phenylmethacrolein 2-Methyl-3-phenyl-2-propenal A-METHYLCINNAMALDEHYDE FOR SYNTHESIS alpha-Methyl-trans-cinnaMaldehyde 98% (2E)-2-Methyl-3-phenyl-2-propenal 2-methyl-3-phenyl-1-propen-1-one Alph-methyl cinnamic aldehyde α-Methylcinnamaldehyde> alpha-Methylcinnamaldehyde USP/EP/BP 2-Propenal, 2-methyl-3-phenyl-,2-Methyl-3-phenyl-2-propenal,alpha-Methylcinnamaldehyde,α-Methyl-trans-cinnamaldehyde,3-Phenylmethacrolein,2- High Quality alpha-methylcinnamaldehyde CAS 101-39-3 TIANFU CHEM---alpha-Methylcinnamaldehyde FEMA 2697 2-methyl-3-phenyl-2-propenal alpha-Methylzimtaldehyd A-METHYLCINNAMALDEHYDE METHYL CINNAMIC ALDEHYDE a-Methyl-trans-cinnaMaldehyde α-Methylcinnamaldehyde