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Triphenylsulfonium Bromide

CAS No.
3353-89-7
Chemical Name:
Triphenylsulfonium Bromide
Synonyms
riphenylsulfanium,bromide;Triphenylsulfonium Bromid;TRIPHENYLSULFONIUM BROMIDE;Triphenyl sulphonium bromide
CBNumber:
CB1705979
Molecular Formula:
C18H15BrS
Molecular Weight:
343.28
MDL Number:
MFCD00428762
MOL File:
3353-89-7.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:34

Triphenylsulfonium Bromide Properties

Melting point 293 °C
form powder to crystal
color White to Almost white
CAS DataBase Reference 3353-89-7

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
HS Code  2930.90.2900

Triphenylsulfonium Bromide price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical T1609 Triphenylsulfonium Bromide >98.0%(T) 3353-89-7 1g $307 2024-03-01 Buy
TCI Chemical T1609 Triphenylsulfonium Bromide >98.0%(T) 3353-89-7 5g $1042 2024-03-01 Buy
TCI Chemical T1609 Triphenylsulfonium Bromide >98.0%(T) 3353-89-7 100mg $60 2024-03-01 Buy
TRC T809093 Triphenylsulfonium Bromide 3353-89-7 10mg $75 2021-12-16 Buy
AK Scientific 9346AL Triphenylsulfonium Bromide 3353-89-7 5g $1371 2021-12-16 Buy
Product number Packaging Price Buy
T1609 1g $307 Buy
T1609 5g $1042 Buy
T1609 100mg $60 Buy
T809093 10mg $75 Buy
9346AL 5g $1371 Buy

Triphenylsulfonium Bromide Chemical Properties,Uses,Production

Uses

Triphenylsulfonium Bromide is used in the preparation of sulfonium salt photoacid generator for deep-UV microlithography.

Preparation

Triphenylsulfonium bromide synthesis: A 3.0 M solution of phenylmagnesium bromide in diethyl ether (50 ml, 0.15 mole) was distilled under vacuum with slow heating from 20° to 80°C. Benzene (40 ml) was added, followed by n-heptane (300 ml). The resulting mixture was stirred and a solution of diphenylsulfoxide 10.1 g, (0.050 mol), in benzene (60 ml) was added during 1 hour at 80°C. The mixture was stirred for 3 hours and cooled to room temperature. An 25% aqueous hydrobromic acid solution (180 ml) was slowly added to the reaction mixture (exotherm-). The layers were separated and the organic layer was extracted twice with 5% aqueous hydrobromic acid (2 x 30 ml). The combined aqueous extracts were extracted three times with dichloromethane (3×250 ml). The dichloromethane extracts were dried over magnesium sulfate, filtered and the organic solvent evaporated to leave triphenylsulfonium bromide (10.2 g, 60%), which was crystallized from dichloromethane/diethyl ether. M.p. 285-7°C.

106-38-7
945-51-7
3353-89-7
4189-82-6
Synthesis of Triphenylsulfonium Bromide from 4-Bromotoluene and Phenyl sulfoxide

Triphenylsulfonium Bromide Preparation Products And Raw materials

Global( 56)Suppliers
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Sholon Chem-Tech Co.,Ltd
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Jilin Chinese Academy of Sciences-yanshen Technology
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View Lastest Price from Triphenylsulfonium Bromide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Triphenylsulfonium Bromide pictures 2023-05-12 Triphenylsulfonium Bromide
3353-89-7
US $0.00 / kg 1kg 99% according to customer's requirements Changzhou waston chemical technology Co.,Ltd
TRIPHENYLSULFONIUM BROMIDE Triphenyl sulphonium bromide Triphenylsulfonium Bromid riphenylsulfanium,bromide 3353-89-7 C18H15BrS Sulfonium Compounds Iodonium Sulfonium & Oxonium Compounds Iodonium Sulfonium & Oxonium Compounds Sulfonium Compounds