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3-Nitrobenzoic acid

3-Nitrobenzoic acid structure

CAS No.: 121-92-6

Chemical Name:: 3-Nitrobenzoic acid

Synonyms: M-NITROBENZOIC ACID;3-nitrobenzoic;NITROBENZOIC(3-) ACID;Metanitrobenzoic acid;3-NITROPHENYL METHANOIC ACID;N-204;Nitrobenzene acid;Arylex Impurity 6;3-nitro-benzoicaci;m-nitro-benzoicaci

CBNumber:: CB1709821

Molecular Formula:: C7H5NO4

Molecular Weight:: 167.12

MDL Number:: MFCD00007251

MOL File:: 121-92-6.mol

MSDS File:: SDS

Last updated:2023-12-28 11:36:52

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3-Nitrobenzoic acid Properties

Melting point	139-141 °C(lit.)
Boiling point	295.67°C (rough estimate)
Density	1,494 g/cm³
vapor density	5.76 (vs air)
vapor pressure	0.005Pa at 25℃
refractive index	1.6280 (estimate)
Flash point	190 °C
storage temp.	no restrictions.
solubility	water: soluble3g/L at 25°C
form	Crystals or Powder
pka	3.47(at 25℃)
color	Slightly green to light yellow
PH Range	3
PH	3 (5g/l, H2O, 20℃)(aqueous suspension)
Water Solubility	<0.01 g/100 mL at 18 ºC
Merck	14,6588
BRN	908644
Stability	Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey	AFPHTEQTJZKQAQ-UHFFFAOYSA-N
LogP	1.1 at 25℃
CAS DataBase Reference	121-92-6(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	H318ZW7612
NIST Chemistry Reference	Benzoic acid, 3-nitro-(121-92-6)
EPA Substance Registry System	m-Nitrobenzoic acid (121-92-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H319

Precautionary statements

P264-P280-P305+P351+P338-P337+P313

Hazard Codes

Xn,Xi

Risk Statements

22-36/37-33-36/37/38

Safety Statements

26-24/25

WGK Germany

RTECS

DH5000000

Autoignition Temperature

490 °C

Hazard Note

Irritant

TSCA

Yes

HS Code

29163900

NFPA 704

	1
2		0

3-Nitrobenzoic acid price More Price(31)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	185329	3-Nitrobenzoic acid ReagentPlus , 99%	121-92-6	5g	$38.5	2024-03-01	Buy
Sigma-Aldrich	185329	3-Nitrobenzoic acid ReagentPlus , 99%	121-92-6	100g	$46.4	2024-03-01	Buy
Sigma-Aldrich	8.00645	3-Nitrobenzoic acid for synthesis	121-92-6	250g	$33.1	2024-03-01	Buy
TCI Chemical	N0154	3-Nitrobenzoic Acid >99.0%(GC)(T)	121-92-6	25g	$18	2024-03-01	Buy
TCI Chemical	N0154	3-Nitrobenzoic Acid >99.0%(GC)(T)	121-92-6	500g	$66	2024-03-01	Buy

Product number	Packaging	Price	Buy
185329	5g	$38.5	Buy
185329	100g	$46.4	Buy
8.00645	250g	$33.1	Buy
N0154	25g	$18	Buy
N0154	500g	$66	Buy

3-Nitrobenzoic acid Chemical Properties,Uses,Production

Chemical Properties

White or light yellow monoclinic leaf-like crystal. Soluble in acetone, chloroform, ethanol and ether, slightly soluble in benzene, water, carbon disulfide and petroleum ether, more soluble in hot water. It smells like almonds. 3-nitrobenzoic acid is quite a strong acid, it is soluble in a relatively weak base. It is about ten times more acidic than benzoic acid.The conjugate base of benzoic acid is stabilised by the presence of the electron withdrawing nitro group which explains its increased acidity in comparison to unsubstituted benzoic acid.

Uses

3-Nitrobenzoic acid was used to investigated the role of ozone as additional decomposition or finishing reagent in the degradation of o-, m- and p-nitobenzoic acids

Application

3-Nitrobenzoic acid is an intermediate of photosensitive materials, functional pigments and drugs. In the pharmaceutical industry, it is used to produce bile acid, acetic acid and so on.
m-nitrobenzoic acid is a reagent used in the coupling of allyl acetate to allylic, aliphatic and benzylic alcohols. It is also used as a chemoattractant against Pseudomonas strains.

Preparation

3-Nitrobenzoic acid is prepared by nitrating benzoic acid at low temperature. Approximately 20% of the 2-nitro isomer and 1.5% of the 4-nitro isomer are co-produced. The 3-nitrobenzoic acid can be purified by recrystallization of the sodium salt. The oxidation of 3-nitrobenzaldehyde, prepared by the controlled oxidation of benzaldehyde, gives a higher yield.

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 1, p. 391, 1941
The Journal of Organic Chemistry, 46, p. 3056, 1981 DOI: 10.1021/jo00328a013

General Description

Off white to yellowish-white crystals. Bitter taste. Melts in hot water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

3-Nitrobenzoic acid is incompatible with strong oxidizers. 3-Nitrobenzoic acid is also incompatible with strong bases. 3-Nitrobenzoic acid may react with cyanides.

Fire Hazard

Flash point data for 3-Nitrobenzoic acid are not available but 3-Nitrobenzoic acid is probably combustible.

Flammability and Explosibility

Non flammable

Purification Methods

Crystallise the acid from *benzene, H2O, EtOH (charcoal), glacial acetic acid or MeOH/H2O. Dry and store it in a vacuum desiccator. The amide has m 143o (from H2O or *C6H6). [Beilstein 9 III 1489, 9 IV 1055.]

3-Nitrobenzoic acid Preparation Products And Raw materials

Raw materials

3-Nitrotoluene Methyl benzoate Benzoic acid

Preparation Products

3-(Dimethylamino)benzoic acid 2,5-BIS(3-NITROPHENYL)-1,3,4-OXADIAZOLE m-Nitrobenzoyl chloride 3-Aminobenzoic acid 2,3-Dihydro-3-(MethoxyphenylMethylene)-2-oxo-1H-indole-6-carboxylic acid Methyl ester

4,4'-Dinitrodiphenic acid 3-AMINOBENZOYLMETHYLAMIDE 3-NITROBENZHYDRAZIDE 3-Nitropropiophenone 3-AMINO-5-BROMOBENZOATE

4-Iodo-3-nitrobenzoic acid 3-Nitrobenzyl alcohol N-(2-methylphenyl)-3-nitrobenzamide

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3-Nitrobenzoic acid Suppliers

Global( 614)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12453	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7377	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21695	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9352	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Shenzhen Nexconn Pharmatechs Ltd	+86-755-89396905 +86-15013857715	admin@nexconn.com	China	7838	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Hebei Guanlang Biotechnology Co., Ltd.	+86-19930503282	alice@crovellbio.com	China	8822	58
Xiamen AmoyChem Co., Ltd	+86-592-6051114 +8618959220845	sales@amoychem.com	China	6387	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22968	58

Supplier	Advantage
Hebei Mojin Biotechnology Co., Ltd	58
Henan Fengda Chemical Co., Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
career henan chemical co	58
Shenzhen Nexconn Pharmatechs Ltd	58
Hubei Jusheng Technology Co.,Ltd.	58
Hebei Guanlang Biotechnology Co., Ltd.	58
Xiamen AmoyChem Co., Ltd	58
Hubei xin bonus chemical co. LTD	58

Reactivity and Polarity of 3-Nitrobenzoic acid
3-Nitrobenzoic acid is an off-white solid, it is used to prepare some dyes.
Dec 28，2023

View Lastest Price from 3-Nitrobenzoic acid manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-19	3-Nitrobenzoic acid 121-92-6	US $15.35 / Kg/Drum	25Kg/Drum	99.50%HPLC	10tons/month	Asia Chem I and E (Jiangsu) Co Ltd
2023-12-24	3-Nitrobenzoic acid 121-92-6	US $100.00-1.00 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2023-09-05	3-Nitrobenzoic acid 121-92-6	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd

3-Nitrobenzoic acid
121-92-6
US $15.35 / Kg/Drum
99.50%HPLC
Asia Chem I and E (Jiangsu) Co Ltd

3-Nitrobenzoic acid
121-92-6
US $100.00-1.00 / KG
99%
Henan Fengda Chemical Co., Ltd

3-Nitrobenzoic acid
121-92-6
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

3-Nitrobenzoic acid Spectrum

3-Nitrobenzoic acid(121-92-6)MS 3-Nitrobenzoic acid(121-92-6)¹HNMR 3-Nitrobenzoic acid(121-92-6)¹³CNMR 3-Nitrobenzoic acid(121-92-6)IR1 3-Nitrobenzoic acid(121-92-6)IR2 3-Nitrobenzoic acid(121-92-6)Raman

121-92-6(3-Nitrobenzoic acid)Related Search:

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DL-α-Tocopherol 4-Nitrobenzoic acid Hyaluronic acid Diphenolic acid 4-(Diethylamino)salicylaldehyde

Ethyl 2-(Chlorosulfonyl)acetate Pralmorelin 2-Chloro-5-nitrobenzoic acid

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RARECHEM AL BO 0229 3-NITRODRACYLIC ACID 3-NITROBENZOIC ACID LABOTEST-BB LT00795102 3-nitro-benzoicaci Benzoic acid, m-nitro- Benzoicacid,3-nitro- m-NITROBENZOIC ACID extrapure AR m-NITROBENZOIC ACID pure 3-Nitrobenzoic acid,98% 1-CARBOXY-3-NITROBENZENE 3-Carboxynitrobenzene 3-Nitrobenzoic acid ReagentPlus(R), 99% Between the nitro benzoic acid 3-Nitrobenzoic acid Vetec(TM) reagent grade, 98% m-Nitrobenzoic Acid 3-Nitrobenzoic Acid 3-NitrobenzoicAcid,>99% m-carboxynitrobenzene metanitrobenzoicacid meta-nitrobenzoicacid m-Nitrobenzenecarboxylic acid m-nitrobenzenecarboxylicacid m-nitro-benzoicaci 3-Nitrobenzoic acid/m-Nitrobenzoic acid N-204 META-NITROBENZOATE 3-NITROBENZOIC ACID 96+% Nitrobenzene acid m-carboxynitrobenzen 3-NitrobenzoicAcid> 3-Nitrobenzoic acid ISO 9001：2015 REACH m-Nitrobenzoic acid, GR 99%+ 3-Nitrobenzoes?ure M-NITROBENZOIC ACID NITROBENZOIC(3-) ACID 3-nitrobenzoic Metanitrobenzoic acid 3-NITROPHENYL METHANOIC ACID Arylex Impurity 6 3-Nitrobenzoic Acid, ≥ 99.0% 121-92-6 CARBOXYLIC ACID Building Blocks C7 Carboxylic Acids Carbonyl Compounds Organic Building Blocks Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts Organics Organic acids Dyestuff Intermediates C7 Carbonyl Compounds Carboxylic Acids