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Acetoacetamide

CAS No.
5977-14-0
Chemical Name:
Acetoacetamide
Synonyms
3-oxobutanamide;Nsc632231;Aids134414;Aids-134414;Acetoacetamid;ACETIACETAMIDE;ACETOACETAMIDE;β-Oxobutanamide;3-Oxobutyramide;Acetylacetamide
CBNumber:
CB1743902
Molecular Formula:
C4H7NO2
Molecular Weight:
101.1
MDL Number:
MFCD00025528
MOL File:
5977-14-0.mol
MSDS File:
SDS
Last updated:2023-05-04 17:34:40

Acetoacetamide Properties

Melting point 53-56 °C(lit.)
Boiling point 271.0±23.0 °C(Predicted)
Density 1.093±0.06 g/cm3(Predicted)
vapor pressure 0.93Pa at 20℃
Flash point >230 °F
storage temp. Refrigerator
solubility water: soluble1g/10 mL, clear, colorless
pka 12.38±0.46(Predicted)
form Crystalline Powder
color white to yellowish
Water Solubility 1000g/L at 20℃
BRN 1560550
InChIKey GCPWJFKTWGFEHH-UHFFFAOYSA-N
LogP -1.4 at 23℃
CAS DataBase Reference 5977-14-0(CAS DataBase Reference)
FDA UNII 6O9U7CFY0T
EPA Substance Registry System Butanamide, 3-oxo- (5977-14-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
WGK Germany  1
RTECS  EJ3667188

Acetoacetamide price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 328812 Acetoacetamide 97% 5977-14-0 100g $61.4 2023-06-20 Buy
Sigma-Aldrich 328812 Acetoacetamide 97% 5977-14-0 500g $132 2023-06-20 Buy
Sigma-Aldrich 688789 Acetoacetamide Lonza quality, 98.5-100.3% (w/w) (T) 5977-14-0 1kg $270 2023-06-20 Buy
Sigma-Aldrich 688789 Acetoacetamide Lonza quality, 98.5-100.3% (w/w) (T) 5977-14-0 25kg $1400 2023-06-20 Buy
TRC A161805 Acetoacetamide 5977-14-0 500g $415 2021-12-16 Buy
Product number Packaging Price Buy
328812 100g $61.4 Buy
328812 500g $132 Buy
688789 1kg $270 Buy
688789 25kg $1400 Buy
A161805 500g $415 Buy

Acetoacetamide Chemical Properties,Uses,Production

Chemical Properties

White to yellowish crystals

Uses

Acetoacetamide is used as intermediate for different organic syntheses, mainly organic dyestuffs. Product Data Sheet

Uses

Acetoacetamide is a β-keto amide commonly used in building heterocyclic systems. It can be used in synthesizing various N-substituted acetoacetamides, that are primary precursors for several organic dyes and pigments.

Uses

Acetoacetamide was used in a study to assess the stability of artificial sweeteners- aspartame, acesulfame-K and binary sweetener blend of aspartame x acesulfame-K during storage. Acetoacetamide was also used in analysis of multiple sweeteners and their degradation products in lassi by HPLC.

Definition

ChEBI: Acetoacetamide is a monocarboxylic acid amide of acetoacetic acid. It is functionally related to an acetoacetic acid.

General Description

Acetoacetamide is a degradation product of acesulfame-K, sweetener. Acetoacetamide undergoes alkaline hydrolysis to form salt of acetoacetic acid.

Flammability and Explosibility

Not classified

Purification Methods

Recrystallise the amide from CHCl3, or Me2CO/pet ether. It also crystallises from pyridine with 4mols of solvent. It is slightly soluble in H2O, EtOH and AcOH but is insoluble in Et2O. The phenylhydrazone has m 128o. [Kato Chem Pharm Bull Jpn 15 921 923 1967, Claisen & Meyer Chem Ber 35 583 1902, Beilstein 3 H 659, 3 I 231, 3 III 1204, 3 IV 1545.]

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View Lastest Price from Acetoacetamide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Acetoacetamide pictures 2020-01-08 Acetoacetamide
5977-14-0
US $1.00 / KG 1KG 99.0% 100kg Career Henan Chemical Co
Acetyl acetomide ACETOACETAMIDE PURUM ACETIACETAMIDE acetessigsaureamid alpha-acetylacetamide 3-Oxobutyramide β-Oxobutanamide Aids134414 Aids-134414 Nsc632231 Acetoacetamide Lonza quality, 98.5-100.3% (w/w) (T) Acetoacetamid ACETOACETAMIDE acetoaceticacidamide Acetylacetamide 3-oxo-butanamid 3-oxo-Butanamide Butanamide, 3-oxo- Acesulfame EP Impurity A 3-Oxobutanamide (Acetylacetamide) Acesulfame potassium EP Impurity A Acesulfame Potassium Impurity A Acesulfame Potassium Impurity A/ Acetoacetamide Acetoacetamide,cas:5977-14-0 3-oxobutanamide Acetoacetamide CAS NO.5977-14-0 Acesulfame Potassium EP Impurity A (Acetoacetamide) 5977-14-0 CH3COCH2CONH2 Organic Building Blocks Amides Building Blocks Carbonyl Compounds Amides Carbonyl Compounds Organic Building Blocks Building Blocks Carbonyl Compounds Chemical Synthesis Organic Building Blocks Pharmaceutical Intermediates