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1,4-Bis(diphenylphosphino)butane

1,4-Bis(diphenylphosphino)butane structure

CAS No.: 7688-25-7

Chemical Name:: 1,4-Bis(diphenylphosphino)butane

Synonyms: DPPB;1,4-di(diphenylphosphino)-butane;[4-(Diphenylphosphino)butyl](diphenyl)phosphine;1,4-Bis(diphenylphosphanyl)butane;TETRAMETHYLENEBIS(DIPHENYLPHOSPHINE);1,4-B;98% DPPB;1,4-Bis(diphenylphos;1,4-BIS(DIPHENYPHOSPHINO);Bis(1,4-diphenylphosphino

CBNumber:: CB1774195

Molecular Formula:: C28H28P2

Molecular Weight:: 426.47

MDL Number:: MFCD00003051

MOL File:: 7688-25-7.mol

MSDS File:: SDS

Last updated:2023-08-17 18:11:45

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1,4-Bis(diphenylphosphino)butane Properties

Melting point	132-136 °C (lit.)
Boiling point	542.0±33.0 °C(Predicted)
storage temp.	Inert atmosphere,Room Temperature
form	Crystalline Powder
color	White to almost white
Water Solubility	Soluble in chloroform. Slightly soluble in water
BRN	706446
InChIKey	BCJVBDBJSMFBRW-UHFFFAOYSA-N
CAS DataBase Reference	7688-25-7(CAS DataBase Reference)
FDA UNII	35HP6LTD2D
NIST Chemistry Reference	1,4-Bis(diphenylphosphino)butane(7688-25-7)
EPA Substance Registry System	Phosphine, 1,4-butanediylbis[diphenyl- (7688-25-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Xi,F

Risk Statements

36/38-36/37/38-11

Safety Statements

26-36-37/39-33-16-7/9

WGK Germany

10-23

TSCA

Yes

HS Code

29319090

NFPA 704

	0
2		0

1,4-Bis(diphenylphosphino)butane price More Price(45)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	261947	1,4-Bis(diphenylphosphino)butane 98%	7688-25-7	5g	$55.4	2024-03-01	Buy
Sigma-Aldrich	261947	1,4-Bis(diphenylphosphino)butane 98%	7688-25-7	25g	$90.8	2024-03-01	Buy
TCI Chemical	B1246	1,4-Bis(diphenylphosphino)butane >98.0%(GC)	7688-25-7	5g	$40	2024-03-01	Buy
TCI Chemical	B1246	1,4-Bis(diphenylphosphino)butane >98.0%(GC)	7688-25-7	25g	$120	2024-03-01	Buy
Alfa Aesar	B21122	1,4-Bis(diphenylphosphino)butane, 98%	7688-25-7	1g	$18.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
261947	5g	$55.4	Buy
261947	25g	$90.8	Buy
B1246	5g	$40	Buy
B1246	25g	$120	Buy
B21122	1g	$18.65	Buy

1,4-Bis(diphenylphosphino)butane Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

1,4-Bis(diphenylphosphino)butane is used in Suzuki reaction. It plays an essential role as a ligand in palladium(0)-catalyzed acylcyanation of arylacetylenes and deprotection of allyloxycarbamates. It acts as a ligand for alkylations, isomerization reactions and in organometallic chemistry. Further, it is used in Heck reaction, Negishi coupling and Sonogashira coupling. In addition to this, it is useful in organometallic chemistry.

Purification Methods

Recrystallise it from EtOH [Trippett J Chem Soc 4263 1961]. [King J Coord Chem 1 62 1971, Tolman Chem Rev 77 313 1977.]

1,4-Bis(diphenylphosphino)butane synthesis

Synthesis of 1,4-Bis(diphenylphosphino)butane from 1,4-Dibromobutane and Diphenylphosphine

1,4-Bis(diphenylphosphino)butane Preparation Products And Raw materials

Raw materials

Diphenylphosphine Ethanol Acetone 1,4-Dichlorobutane Sodium

Tetrahydrofuran Ethyl acetate Hydrochloric acid 1,4-Dibromobutane Dichloromethane

Sodium hydroxide Triphenylphosphine Magnesium sulfate Lithium n-Butyllithium

Diphenyl[4-(diphenylphosphinyl)butyl]phosphine oxide

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Preparation Products

(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE (S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE (R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE (R)-7,7'-BIS(DIPHENYLPHOSPHINO)-1,1'-SPIROBIINDANE

(4-chlorobutyl)diphenylphosphane TETRAPHENYLBIPHOSPHINE

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1,4-Bis(diphenylphosphino)butane Suppliers

Global( 418)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Puyang Huicheng Electronic Materials Co., Ltd.	+86-0393-+86-0393-8910800 +8615839383373	info@huichengchem.com	China	516	58
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12456	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15928	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9348	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
AB PharmaTech,LLC	323-480-4688		United States	989	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Jinan Carbotang Biotech Co.,Ltd.	+8615866703830	figo.gao@foxmail.com	China	6992	58

Supplier	Advantage
Puyang Huicheng Electronic Materials Co., Ltd.	58
Hebei Mojin Biotechnology Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
AB PharmaTech,LLC	55
career henan chemical co	58
Jinan Carbotang Biotech Co.,Ltd.	58

View Lastest Price from 1,4-Bis(diphenylphosphino)butane manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-26	1,4-Bis(diphenylphosphino)butane 7688-25-7	US $5.00 / kg	1kg	≥98%	500mt/year	Jinan Finer Chemical Co., Ltd
2023-08-18	1,4-Bis(diphenylphosphino)butane 7688-25-7	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd
2023-05-17	1,4-Bis(diphenylphosphino)butane 7688-25-7	US $9.00 / KG	1KG	99.9	1 ton	Hebei Guanlang Biotechnology Co,.LTD

1,4-Bis(diphenylphosphino)butane
7688-25-7
US $5.00 / kg
≥98%
Jinan Finer Chemical Co., Ltd

1,4-Bis(diphenylphosphino)butane
7688-25-7
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

1,4-Bis(diphenylphosphino)butane
7688-25-7
US $9.00 / KG
99.9
Hebei Guanlang Biotechnology Co,.LTD

1,4-Bis(diphenylphosphino)butane Spectrum

1,4-Bis(diphenylphosphino)butane(7688-25-7)MS 1,4-Bis(diphenylphosphino)butane(7688-25-7)¹HNMR 1,4-Bis(diphenylphosphino)butane(7688-25-7)¹³CNMR 1,4-Bis(diphenylphosphino)butane(7688-25-7)³¹PNMR 1,4-Bis(diphenylphosphino)butane(7688-25-7)IR1 1,4-Bis(diphenylphosphino)butane(7688-25-7)IR2 1,4-Bis(diphenylphosphino)butane(7688-25-7)Raman

7688-25-7(1,4-Bis(diphenylphosphino)butane)Related Search:

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1,3-Bis(diphenylphosphino)propane (2S,4S)-(-)-N-BOC-4-Diphenylphosphino-2-diphenylphosphinomethyl-pyrrolidine (2S,4S)-4-Diphenylphosphino 2-diphenylphosphinomethyl pyrrolidine TETRAMETHYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE) (-)-DIOP

(+)-DIOP 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE,(2R,3R)-(+)-Bis(diphenylphosphino)butane, (R,R)-CHIRAPHOS (2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE Phenyl phosphine

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98% DPPB Tetramethylenebis(diphenylphosphine) DPPB 1,4-Bis(diphenylphosphino)butane, 98% 5GR 1,4-Bis(diphenylphosphiNA)butane 1,4-Bis(diphenylphosphino)buta 1,4-Bis(diphenylphosphino)butane Butane-1,4-diylbis[diphenylphosphine] 1,4-Butylenebis(diphenylphosphine) 1,4-diphenyl phosphinobutane 1,4-Bis(diphenylphosphino)butane SynonyM Butane-1,4-diylbis[diphenylphosphine] 1,4-Bis(diphenylphosphino)butane 98% 4-Bis(diphenylphosphino)butane, 98% 1,5-dimethyl-4-[methyl(nitroso)amino]-2-phenyl-1,2-dihydro-3h-pyrazol-3-one 1,4-butanediylbis[diphenyl-phosphin Bis(1,4-diphenylphosphino)butane Phosphine, 1,4-butanediylbis[diphenyl- 1,4-bis(diphenylphosphino)butane(dppb) 1,4-Bis(diphenyphosphino)Butane 1,4-Bis(diphenylphosphino)butane,98%DPPB DPPB/1,4-BIS(DIPHENYLPHOSPHINO)BUTANE bis-(diphenylphosphino)butane (dppb) 1,4-BIS(DIPHENYPHOSPHINO) 1,4-Bis(diphenylphosphino)butane(98%) 4-Di(phenyl)phosphanylbutyl-di(phenyl)phosphane 1,4-Butanediylbis(diphenylphosphine) Bis-(Diphenylphosphino)Butane Bis(1,4-diphenylphosphino 1,4-Bis(diphenylphos Butane-1,4-diylbis[diphenylphosphine] 1,4-BIS(DIPHENYLPHOSPHINE)BUTANE 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE 1,4-B 1,4-Bis(diphenylphosphino)butane, 98%, for synthesis 1,4-Bis(diphenylphosphino)butane > Phosphine, 1,1'-(1,4-butanediyl)bis[1,1-diphenyl- 1,4-bis(diphenylphosphaneyI)butane (DPPB) DPPB (1,4-Bis(Diphenylphosphino)Butane) extrapure, 98% [4-(Diphenylphosphino)butyl](diphenyl)phosphine TETRAMETHYLENEBIS(DIPHENYLPHOSPHINE) 1,4-di(diphenylphosphino)-butane DPPB 1,4-Bis(diphenylphosphanyl)butane 7688-25-7 C28H28P C6H52PCH24PC6H52 C6H52PCH2CH2CH2CH2PC6H52 Catalysis and Inorganic Chemistry Phosphine Ligands Phosphorus Compounds Polydentate Phosphine Ligands Phosphines Phosphine Ligands Synthetic Organic Chemistry Ligand Achiral Phosphine Aryl Phosphine organophosphine ligand