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4-tert-Butylphenol

4-tert-Butylphenol
4-tert-Butylphenol
CAS No.
98-54-4
Chemical Name:
4-tert-Butylphenol
Synonyms
PTBP;FEMA 3918;BUTYLPHEN;Lowinox 070;Lowinox PTBT;t-Butylphenol;4-tert.-Butylp;4-t-Butylphenol;P-T-BUTYLPHENOL;p-terc.Butylfenol
CBNumber:
CB1854749
Molecular Formula:
C10H14O
Formula Weight:
150.22
MOL File:
98-54-4.mol

4-tert-Butylphenol Properties

Melting point:
96-101 °C(lit.)
Boiling point:
236-238 °C(lit.)
Density 
0.908 g/mL at 25 °C(lit.)
vapor pressure 
1 mm Hg ( 70 °C)
refractive index 
1.4787
FEMA 
3918 | P-TERT-BUTYLPHENOL
Flash point:
113 °C
storage temp. 
room temp
solubility 
ethanol: soluble50mg/mL, clear, colorless
form 
Flakes or Pastilles
pka
10.23(at 25℃)
color 
White to light beige
PH
7 (10g/l, H2O, 20℃)
explosive limit
0.8-5.3%(V)
Water Solubility 
8.7 g/L (20 ºC)
Merck 
14,1585
BRN 
1817334
Stability:
Stable. Incompatible with copper, steel, bases, acid chlorides, acid anhydrides, oxidizing agents.
InChIKey
QHPQWRBYOIRBIT-UHFFFAOYSA-N
CAS DataBase Reference
98-54-4(CAS DataBase Reference)
NIST Chemistry Reference
Phenol, p-tert-butyl-(98-54-4)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi,N
Risk Statements  37/38-41-51/53-62-38-37-34
Safety Statements  26-39-61-36/37/39-45
RIDADR  UN 3077 9/PG 3
WGK Germany  2
RTECS  SJ8925000
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29071900
Toxicity LD50 orally in rats: 3.25 ml/kg (Smyth)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H303 May be harmfulif swallowed Acute toxicity,oral Category 5 P312
H313 May be harmful in contact with skin Acute toxicity,dermal Category 5 P312
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P391 Collect spillage. Hazardous to the aquatic environment
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P337+P313 IF eye irritation persists: Get medical advice/attention.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

4-tert-Butylphenol price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B99901 4-tert-Butylphenol 99% 98-54-4 1kg $55.1 2018-11-13 Buy
Sigma-Aldrich 425761 4-tert-Butylphenol purified by sublimation, 99% 98-54-4 5g $57.9 2018-11-13 Buy
TCI Chemical B0230 4-tert-Butylphenol >98.0%(GC) 98-54-4 25g $14 2018-11-22 Buy
TCI Chemical B0230 4-tert-Butylphenol >98.0%(GC) 98-54-4 500g $25 2018-11-22 Buy
Alfa Aesar A15871 4-tert-Butylphenol, 99% 98-54-4 2500g $117 2018-11-13 Buy

4-tert-Butylphenol Chemical Properties,Uses,Production

Chemical Properties

white crystalline powder

Chemical Properties

The butylphenols include several isomers. Solid butylphenols (28805-86-9) generally have properties similar to the above:

Uses

Plasticizer for cellulose acetate; intermediate for antioxidants, special starches, oil-soluble phe- nolic resins; pour-point depressors and emulsion breakers for petroleum oils and some plastics; syn- thetic lubricants; insecticides; industrial odorants; motor-oil additives.

Definition

ChEBI: A member of the class of phenols that is phenol substituted with a tert-butyl group at position 4..

General Description

Crystals or practically white flakes. Has a disinfectant-like odor. May float or sink in water. Insoluble in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Phenols, such as 4-tert-Butylphenol, do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has Ka = 1.3 x 10^[-10]). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases. Such heating may initiate polymerization of the organic compound. Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature). The reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid.

Hazard

Irritant to eyes and skin.

Fire Hazard

Combustible.

Contact allergens

Para-tert-butylphenol is used with formaldehyde to produce the polycondensate p-tert-butylphenol-formaldehyde resins (PTBPFR). Major occupational sources are neoprene glues and adhesives in industry, in the shoemaking and leather industries or in car production. It is also used as a box preservative in box and furniture manufacture and in the production of casting molds, car brake linings, insulated electrical cables, adhesives, printing inks, and paper laminates. Para-tertbutylphenol seems to be the sensitizer

Safety Profile

Poison by intraperitoneal route. Moderately toxic by skin contact and ingestion. A skin and severe eye irritant. Questionable carcinogen with experimental neoplastigenic data. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid and irritating fumes. See also PHENOL and other butyl phenols.

Potential Exposure

Butylphenols may be used as intermediates in manufacturing varnish and lacquer resins; as a germicidal agent in detergent disinfectants; as a pour point depressant, in motor-oil additives; de-emulsifier for oil; soap-antioxidant, plasticizer, fumigant, and insecticide

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit

Shipping

UN2430 Alkylphenols, solid, n.o.s. (including C2-C12 homologues), Hazard class: 8; Labels: 8— Corrosive material

Purification Methods

Crystallise the phenol to constant melting point from pet ether (b 60-80o). It sublimes in vacuo. Also purify it via the benzoate, as for phenol. The salicylate ester [87-18-30] has m 63-64o (from aqueous EtOH, or EtOH). [Beilstein 6 IV 3296.]

Incompatibilities

Vapors may form explosive mixture with air. These phenol/cresol materials can react with oxidizers; reaction may be violent. Incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may cause the gas to ignite and explode. Heat is also generated by the acid-base reaction with bases; such heating may initiate polymerization of the organic compound. React with boranes, alkalies, aliphatic amines, amides, nitric acid, sulfuric acid. Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature). These reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid and can explode when heated. Many phenols form metal salts that may be detonated by mild shock

4-tert-Butylphenol Preparation Products And Raw materials

Raw materials

Preparation Products


4-tert-Butylphenol Suppliers

Global( 214)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22058 58
Dalian Richfortune Chemicals Co., Ltd
86-411-84820922, 84821539
86-411-84821380 sales@richfortunechem.com China 362 57
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20795 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32764 55
ATK CHEMICAL COMPANY LIMITED
+86 21 5161 9050/ 5187 7795
+86 21 5161 9052/ 5187 7796 ivan@atkchemical.com CHINA 14297 60
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 20001 58
NINGBO INNO PHARMCHEM CO., LTD.
13867897135
sales@nbinno.com CHINA 931 58
Shanghai Excellent Chemical Co., Ltd. 0086-21-33559231; 018964673308 qq48685515;Skype: excellentchem
0086-21-33559231 sales@excellentchem.com China 2110 59
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40399 62

View Lastest Price from 4-tert-Butylphenol manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-15 4-tert-Butylphenol
98-54-4
US $8.00 / kg 1kg 99% 100MT career henan chemical co

4-tert-Butylphenol Spectrum


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