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ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE

CAS No.
20461-99-8
Chemical Name:
ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE
Synonyms
2-Carboethoxydithiolane;2-Carboethoxy-1,3-dithiolane;2-Ethoxycarbonyl-1,3-dithiolane;Ethyl 1,3-Ditholane-2-carboxylate;ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE;ETHYL GLYOXYLATE ETHYLENE THIOACETAL;Ethyl 1,3-dithiolane-2-carboxylate,99%;Ethyl 1,3-dithiolane-2-carboxylate, 98+%;Ethyl 1,3-dithiolane-2-carboxylate, GC 99%;Ethyl 1,3-dithiolane-2-carboxylate, 99% 5ML
CBNumber:
CB2105967
Molecular Formula:
C6H10O2S2
Molecular Weight:
178.27
MDL Number:
MFCD00005411
MOL File:
20461-99-8.mol
Last updated:2023-06-08 17:06:36

ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE Properties

Boiling point 85 °C/0.1 mmHg (lit.)
Density 1.249 g/mL at 25 °C (lit.)
refractive index n20/D 1.539(lit.)
Flash point >230 °F
storage temp. 2-8°C
form Liquid
color Clear light yellow
Specific Gravity 1.249
BRN 118157
CAS DataBase Reference 20461-99-8(CAS DataBase Reference)
FDA UNII ZP3BM93ES6

SAFETY

Risk and Safety Statements

Safety Statements  23-24/25
RIDADR  3334
WGK Germany  3
8-9
HS Code  29349990
NFPA 704
1
0 0

ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical D2105 Ethyl 1,3-Dithiolane-2-carboxylate >97.0%(GC) 20461-99-8 5g $67 2024-03-01 Buy
TRC E937118 Ethyl 1,3-Dithiolane-2-carboxylate 20461-99-8 50mg $45 2021-12-16 Buy
TRC E937118 Ethyl 1,3-Dithiolane-2-carboxylate 20461-99-8 100mg $60 2021-12-16 Buy
Matrix Scientific 098234 Ethyl 1,3-dithiolane-2-carboxylate 95+% 20461-99-8 1g $49 2021-12-16 Buy
American Custom Chemicals Corporation CHM0029461 ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE 95.00% 20461-99-8 5G $897.92 2021-12-16 Buy
Product number Packaging Price Buy
D2105 5g $67 Buy
E937118 50mg $45 Buy
E937118 100mg $60 Buy
098234 1g $49 Buy
CHM0029461 5G $897.92 Buy

ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE Chemical Properties,Uses,Production

Chemical Properties

clear light yellow liquid

General Description

Ethyl 1,3-dithiolane-2-carboxylate is an α-keto acid equivalent. It participates in the conjugate additions to enones. It is a bulky equivalent of acetate undergoing syn-selective aldol reactions. Anion derived from ethyl 1,3-dithiolane-2-carboxylate participates as nucleophile during the total synthesis of the corynanthe alkaloid dihydrocorynantheol and the formal syntheses of the indole alkaloids tacamonine, rhynchophylline and hirsutine. It also participates in the conjugate addition of enolates to phenylglycinol-derived α,β-unsaturated δ-lactams.

Purification Methods

Dissolve the ester in CHCl3, wash it with aqueous K2CO3, twice with H2O, dry it over MgSO4, filter, evaporate and distil the residue in vacuo. [Hermann et al Tetrahedron Lett 2599 1973, Corey & Erickson J Org Chem 36 3553 1971]. [Beilstein 19/7 V 225.]

ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE Preparation Products And Raw materials

Global( 69)Suppliers
Supplier Tel Email Country ProdList Advantage
career henan chemical co
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Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503259 +86-19930503259 cherry@crovellbio.com China 18458 58
PT CHEM GROUP LIMITED
+86-85511178 +86-85511178 peter68@ptchemgroup.com China 35453 58
GIHI CHEMICALS CO.,LIMITED
+8618058761490 info@gihichemicals.com China 49999 58
Aladdin Scientific
+1-833-552-7181 sales@aladdinsci.com United States 52927 58
Amadis Chemical Company Limited
571-89925085 sales@amadischem.com China 131981 58
Mainchem Co., Ltd. +86-0592-6210733 sale@mainchem.com China 32360 55
Chemwill Asia Co.,Ltd. 86-21-51086038 chemwill_asia@126.com CHINA 23931 58

View Lastest Price from ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
ethyl 1,3-dithiolane-2-carboxylate pictures 2020-02-01 ethyl 1,3-dithiolane-2-carboxylate
20461-99-8
US $1.00 / KG 1KG Min98% HPLC g/kg/ton Career Henan Chemical Co
ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE ETHYL GLYOXYLATE ETHYLENE THIOACETAL GLYOXYLIC ACID ETHYL ESTER ETHYLENE MERCAPTAL 2-Carboethoxy-1,3-dithiolane~1,3-Dithiolane-2-carboxylicacidethylester~2-Ethoxycarbonyl-1,3-dithiolane~Ethylglyoxyla 1,3-DITHIOLANE-2-CARBOXYLIC ACID ETHYL ESTER 2-Carboethoxy-1,3-dithiolane 2-Carboethoxydithiolane Ethyl 1,3-dithiolane-2-carboxylate, GC 99% 1,3-DITHIOLANE-2-CARBOXYLIC ACID ETHYL ESTER 95+% Ethyl 1,3-dithiolane-2-carboxylate, 98+% Ethyl 1,3-dithiolane-2-carboxylate,99% 2-Ethoxycarbonyl-1,3-dithiolane Ethyl Glyoxylate Dimethylene Dithioacetal Ethyl 1,3-dithiolane-2-carboxylate, 99% 5ML Ethyl 1,3-Ditholane-2-carboxylate 20461-99-8 C6H10O2S2 Sulfur Compounds (for Synthesis) Building Blocks Others S-Containing Heterocyclic Building Blocks Sulfur Compounds (for Synthesis) Synthetic Organic Chemistry Heterocyclic Compounds