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Hexahydro-4-methylphthalic anhydride

CAS No.
19438-60-9
Chemical Name:
Hexahydro-4-methylphthalic anhydride
Synonyms
MHHPA;4-MHHPA;Rikacid MH;Hexahydro-4-methyL;HEXAHYDRO-4-METHYLPHTH;Methylaexahydrophthalic Anhydride;5-Methylhexahydrophthalicanhydride;4-Methylhexahydrohthalic anhydride;4-Methylhexahydrophthalsureanhydrid;HEXAHYDRO-3-METHYLPHTHALIC ANHYDRIDE
CBNumber:
CB2125569
Molecular Formula:
C9H12O3
Molecular Weight:
168.19
MDL Number:
MFCD00005927
MOL File:
19438-60-9.mol
MSDS File:
SDS
Last updated:2023-11-20 10:55:26

Hexahydro-4-methylphthalic anhydride Properties

Melting point -29°C
Boiling point 120°C (1 mmHg)
Density 1.162 g/mL at 25 °C(lit.)
vapor pressure 0.23Pa at 25℃
refractive index n20/D 1.477(lit.)
Flash point >230 °F
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
pka 4.24[at 20 ℃]
form Liquid
color Clear
Water Solubility REACTS
Sensitive Moisture Sensitive
Stability Hygroscopic, Moisture Sensitive
InChIKey FKBMTBAXDISZGN-UHFFFAOYSA-N
LogP -3.95 at 20℃
CAS DataBase Reference 19438-60-9(CAS DataBase Reference)
FDA UNII 0A6XX8MUNL
EPA Substance Registry System 1,3-Isobenzofurandione, hexahydro-5-methyl- (19438-60-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS08
Signal word  Danger
Hazard statements  H317-H318-H334
Precautionary statements  P261-P272-P280-P284-P302+P352-P305+P351+P338
Hazard Codes  Xn
Risk Statements  41-42/43
Safety Statements  22-24-26-37/39
WGK Germany  1
Hazard Note  Irritant
TSCA  Yes
HS Code  29172090
NFPA 704
1
2 0

Hexahydro-4-methylphthalic anhydride price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 149934 Hexahydro-4-methylphthalic anhydride, mixture of cis and trans 96% 19438-60-9 3kg $853 2024-03-01 Buy
TCI Chemical M0567 4-Methylcyclohexane-1,2-dicarboxylic Anhydride >98.0%(GC) 19438-60-9 25g $21 2024-03-01 Buy
TCI Chemical M0567 4-Methylcyclohexane-1,2-dicarboxylic Anhydride >98.0%(GC) 19438-60-9 500g $79 2024-03-01 Buy
Sigma-Aldrich 149934 Hexahydro-4-methylphthalic anhydride, mixture of cis and trans 96% 19438-60-9 25g $58.6 2024-03-01 Buy
Sigma-Aldrich 149934 Hexahydro-4-methylphthalic anhydride, mixture of cis and trans 96% 19438-60-9 500g $188 2024-03-01 Buy
Product number Packaging Price Buy
149934 3kg $853 Buy
M0567 25g $21 Buy
M0567 500g $79 Buy
149934 25g $58.6 Buy
149934 500g $188 Buy

Hexahydro-4-methylphthalic anhydride Chemical Properties,Uses,Production

Description

Methylhexahydrophthalic anhydride (MHHP A) is an epoxy hardener, irritant to skin and mucus membranes. It is included in non-diglycidyl-ether-of-bisphenol- A epoxy resins. It can induce both allergic contact dermatitis and immunologic contact urticaria. MHHP A is structurally close to methyltetrahydrophthalic anhydride (MTHP A), which can also cause sensitization.

Chemical Properties

Hexahydro-4-methylphthalic anhydride has a melting point of 29 °C, so it is a liquid at room temperature. It has a boiling point of 120 °C and at 25 °C its density is 1.162 g/mL.

Uses

Hexahydro-4-methylphthalic anhydride, mixture of?cis?and?trans may be used as an analytical standard for the determination of the analyte in human biological samples by gas chromatography-mass spectrometry (GC-MS).

General Description

Methylhexahydrophthalic anhydride, a congener of phthalic anhydride, is utilized in the production of plastics, paints, and electronic components. It can potentially result in allergenic effects on humans upon exposure and cause immunological reactions.

Flammability and Explosibility

Non flammable

Contact allergens

Methylhexahydrophthalic anhydride is an epoxy hardener, irritant to skin and mucous membranes. It is included in nondiglycidyl-ether-of-bisphenol-A epoxy resins. It can induce both allergic contact dermatitis and immunologic contact urticaria. It is structurally close to methyltetrahydrophthalic anhydride, which can also cause sensitization.

Synthesis

5-methyl-3a,4,7,7a-tetrahydroisobenzofuran-1,3-dione could used as a starting material to synthesize Hexahydro-4-methylphthalic anhydride. The byproducts include 5-methylisobenzofuran-1,3-dione, 5-methyl-4,5,6,7-tetrahydroisobenzofuran-1,3-dione, and 6-methyl-3a,4,5,7a-tetrahydroisobenzofuran-1,3-dione.
Hexahydro-4-methylphthalic anhydride

Hexahydro-4-methylphthalic anhydride Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 231)Suppliers
Supplier Tel Email Country ProdList Advantage
Puyang Huicheng Electronic Materials Co., Ltd.
+86-0393-+86-0393-8910800 +8615839383373 info@huichengchem.com China 516 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15371 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Accela ChemBio Inc.
(+1)-858-699-3322 info@accelachem.com United States 19965 58
Shandong chuangyingchemical Co., Ltd.
18853181302 sale@chuangyingchem.com CHINA 5909 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17367 58

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View Lastest Price from Hexahydro-4-methylphthalic anhydride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl Hexahydrophthalic Anhydride pictures 2023-11-13 Methyl Hexahydrophthalic Anhydride
19438-60-9
US $0.00-0.00 / KG 1KG ≥98.0 71000 Puyang Huicheng Electronic Materials Co., Ltd.
Methylhexahydrophthalic anhydride pictures 2022-10-25 Methylhexahydrophthalic anhydride
19438-60-9
US $30.00-28.00 / Kg 1Kg 99.0% up 50 tons per month Xinxiang Hongqi District Houyuan Trading Co.,Ltd
Hexahydro-4-methylphthalic anhydride pictures 2022-10-18 Hexahydro-4-methylphthalic anhydride
19438-60-9
US $30.00-28.00 / Kg 1Kg 99.0% up 50 tons per month Xinxiang Hongqi District Houyuan Trading Co.,Ltd
HEXAHYDRO-4-METHYLPHTHALIC ANHYDRIDE HEXAHYDRO-3-METHYLPHTHALIC ANHYDRIDE 3-METHYL-1,2-CYCLOHEXANEDICARBOXYLIC ANHYDRIDE 4-METHYL-1,2-CYCLOHEXANEDICARBOXYLIC ANHYDRIDE 4-METHYLCYCLOHEXANE-1,2-DICARBOXYLIC ANHYDRIDE 3-Isobenzofurandione,hexahydro-5-methyl-1 4-methylcyclohexyl-1,6-dicarboxylicacidanhydride 5-Methylhexahydro-1,3-isobenzofurandione 5-Methylhexahydrophthalicanhydride hexahydro-4-methylphthalicanhydride,mixtureofcisandtrans hexahydro-5-methyl-3-isobenzofurandione Methylaexahydrophthalic Anhydride (+/-)-HEXAHYDRO-4-METHYLPHTHALIC ANHYDRI DE, 97%, MIXTURE OF CIS & TR Hexahydro-4-methylphthalic anhydride, mixture of isomers 1,3-Isobenzofurandione, hexahydro-5-methyl- 4-METHYLCYCLOHEXANE-1,2-DICARBOXYLICACIDANHYDRIDE 4-Methylhexahydrophthalsureanhydrid 4-Methyl-1,2-cyclohexanedicarboxylic anhydride, mixture of isomers, 98% 5-Methyl-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Hexahydro-4-methylphthalic anhydride, 98%, mixture of cis and trans 4-Methylhexahydrophthalic acid anhydride 4-Methylhexahydrophthalic anhydride(4-MHHPA) Hexahydro-4-Methylphthalic anhydride, Mixture of cis and trans 96% 5-Methylhexahydroisobenzofuran-1,3-dione Hexahydro-4-methylphthalic anhdride, mixture of isomers 4-Methylcyclohexane-1,2-dicarboxylicAnhydride> Hexahydro-4-methyL HEXAHYDRO-4-METHYLPHTH Hexahydro-4-methylphthalic anhydride, mixture of cis and tra... 4-Methylhexahydrohthalic anhydride 4-Methylcyclohexane-1,2-dicarboxylic Anhydride (cis- and trans- mixture) MHHPA 4-MHHPA Rikacid MH 19438-60-9 ANHYDRIDE Organics