Methyl 4-bromobenzoate
- CAS No.
- 619-42-1
- Chemical Name:
- Methyl 4-bromobenzoate
- Synonyms
- METHYL P-BROMOBENZOATE;BRBSME;NSC 9392;RARECHEM AL BF 0075;Methyl 4-bromobenzoa;Methyl-4-brombenzoat;Methy14-bromobenzoate;METHYL 4-BROMOBENZOATE;Methyl 4-bromobenzoate,99%;Methyl 4-bromobenzoate 99%
- CBNumber:
- CB2139717
- Molecular Formula:
- C8H7BrO2
- Molecular Weight:
- 215.04
- MDL Number:
- MFCD00013531
- MOL File:
- 619-42-1.mol
- MSDS File:
- SDS
Melting point | 77-81 °C (lit.) |
---|---|
Boiling point | 252.95°C (rough estimate) |
Density | 1,689 g/cm3 |
refractive index | 1.5500 (estimate) |
storage temp. | Sealed in dry,Room Temperature |
solubility | Chloroform (Slightly), Methanol (Slightly) |
form | Crystals or Crystalline Powder |
color | White |
Water Solubility | Insoluble in water. |
Merck | 14,1408 |
BRN | 2045132 |
InChIKey | HANNIMAAZKBBRE-UHFFFAOYSA-N |
CAS DataBase Reference | 619-42-1(CAS DataBase Reference) |
FDA UNII | UB1YSJ5XAR |
NIST Chemistry Reference | 4-Bromobenzoic acid methyl ester(619-42-1) |
EPA Substance Registry System | Benzoic acid, 4-bromo-, methyl ester (619-42-1) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-24/25 | |||||||||
WGK Germany | 3 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29163990 | |||||||||
NFPA 704 |
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Methyl 4-bromobenzoate price More Price(31)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 407593 | Methyl 4-bromobenzoate 99% | 619-42-1 | 10g | $117 | 2024-03-01 | Buy |
TCI Chemical | B0556 | Methyl 4-Bromobenzoate >98.0%(GC) | 619-42-1 | 10g | $50 | 2024-03-01 | Buy |
TCI Chemical | B0556 | Methyl 4-Bromobenzoate >98.0%(GC) | 619-42-1 | 25g | $83 | 2024-03-01 | Buy |
Alfa Aesar | A15517 | Methyl 4-bromobenzoate, 98+% | 619-42-1 | 5g | $47.65 | 2024-03-01 | Buy |
Alfa Aesar | A15517 | Methyl 4-bromobenzoate, 98+% | 619-42-1 | 25g | $171 | 2024-03-01 | Buy |
Methyl 4-bromobenzoate Chemical Properties,Uses,Production
Chemical Properties
WHITE CRYSTALS OR CRYSTALLINE POWDER
Uses
Methyl 4-bromobenzoate is used as a starting material in the synthesis of three-carbon-bridged 5-substituted furo[2,3-d]pyrimidine and 6-substituted pyrrolo[2,3-d]pyrimidine and methyl 4-tri-n-butylstannylbenzoate. It is also used to stimulate microbial dechlorination of polychlorinated biphenyls. Further, it is used in the preparation of stable radioiodinating reagent to label monoclonal antibodies for radiotherapy of cancer.
Uses
Methyl 4-bromobenzoate is a halogenated benzoate used as a reagent in organic synthesis. It can be used to stimulate microbial dechlorination of PCBs. By condensing methyl 4-bromobenzoate with 3-buten-1-ol, 4-(4-methylphenyl)butanal can be obtained.
Application
Methyl 4-bromobenzoate may be used in the following syntheses:
- Methyl 4-(2-pyridyl)benzoate by cross coupling reaction with lithium 2-pyridyltriolborate.
- Methyl 4-imidazo[1,2-a]pyridin-3-ylbenzoate by ligand-free Pd(OAc)2 catalyzed reaction with Imidazo[1,2-a]pyridine.
- Methyl (E)-4-[3-(2-methoxycarbonylvinyl)-thiophen-2-yl]acrylate by reacting with methyl (E)-3-(thiophen-3-y)lacrylate.
General Description
Methyl 4-bromobenzoate is a para-substituted aryl bromide. Mol-ecules of methyl 4-bromobenzoate are almost planar. The compound is isostructural with methyl 4-iodo-benzoate. The Zeeman effect on the N.Q.R. (nuclear quadrupole resonance) of methyl 4-bromobenzoate on single crystals, has been investigated by the ′geometric method′.
Purification Methods
Crystallise the ester from MeOH. EtOH (m 81o, also 80.5o, 79.5o) or *C6H6/pet ether (m 78-79o). [Beilstein 9 H 352, 9 III 1405, 9 IV 1017.]
Methyl 4-bromobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20293 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18628 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21667 | 55 |
Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32836 | 60 |
Zjartschem | +86-571 87238903 | jocelynpan@zjarts.com | CHINA | 993 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2931 | 58 |
View Lastest Price from Methyl 4-bromobenzoate manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-04-09 | Methyl 4-bromobenzoate
619-42-1
|
US $5.00-0.10 / KG | 1KG | 98% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | ||
2023-09-06 | Methyl 4-bromobenzoate
619-42-1
|
US $0.00 / KG | 1KG | 99% | 500000kg | Hebei Guanlang Biotechnology Co., Ltd. | ||
2023-07-27 | Methyl 4-bromobenzoate
619-42-1
|
US $1.50 / g | 1g | 99.0% Min | 100 Tons | Shaanxi Didu New Materials Co. Ltd |
- Methyl 4-bromobenzoate
619-42-1
- US $5.00-0.10 / KG
- 98%
- Henan Fengda Chemical Co., Ltd
- Methyl 4-bromobenzoate
619-42-1
- US $0.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
- Methyl 4-bromobenzoate
619-42-1
- US $1.50 / g
- 99.0% Min
- Shaanxi Didu New Materials Co. Ltd