FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID

CAS No.
93372-25-9
Chemical Name:
FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID
Synonyms
FMOC-TOAC;FMOC-TOAC-OH 500 MG;FMOC-TOAC-OH 100 MG;FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID;Fmoc-2,2,6,6-tetramethylpiperidine-N-oxyl-4-amino-4-carboxylic acid≥ 98% (HPLC);4-(9H-fluoren-9-ylmethoxycarbonylamino)-2,2,6,6-tetramethyl-1-oxidopiperidin-1-ium-4-carboxylic acid
CBNumber:
CB2166593
Molecular Formula:
C25H29N2O5*
Molecular Weight:
437.51
MDL Number:
MFCD03425569
MOL File:
Mol file
MSDS File:
SDS
Last updated:2023-05-24 08:28:53

FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID Properties

Melting point 162-164°C
storage temp. Store at +2°C to +8°C.
solubility Acetonitrile (Slightly), Chloroform (Slightly), Methanol (Slightly)
form Solid
color Pale Yellow to Yellow

SAFETY

Risk and Safety Statements

WGK Germany  WGK 2 water endangering
HS Code  2933 39 99

FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.52342 Fmoc-TOAC-OH Novabiochem? 93372-25-9 100MG $224 2023-06-20 Buy
Sigma-Aldrich 8.52342 Fmoc-TOAC-OH Novabiochem? 93372-25-9 500MG $890 2023-06-20 Buy
TRC F675000 Fmoc-2,2,6,6-tetramethylpiperidine-N-oxyl-4-amino-4-carboxylicAcid 93372-25-9 50mg $155 2021-12-16 Buy
Usbiological 276452 Fmoc-2,2,6,6-tetramethylpiperidine-N-oxyl-4-amino-4-carboxylic acid 93372-25-9 2mg $403 2021-12-16 Buy
Iris Biotech GmbH FAA1771 Fmoc-TOAC-OH 93372-25-9 500mg $486 2021-12-16 Buy
Product number Packaging Price Buy
8.52342 100MG $224 Buy
8.52342 500MG $890 Buy
F675000 50mg $155 Buy
276452 2mg $403 Buy
FAA1771 500mg $486 Buy

FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID Chemical Properties,Uses,Production

Chemical Properties

Yellow Solid

Uses

A protected spin-labelled, cyclic, chiral ?amino acid resolved in an enantiomerically pure state

Uses

Fmoc-2,2,6,6-tetramethylpiperidine-N-oxyl-4-amino-4-carboxylic Acid is a stable, free radical spin label.

Uses

A stable free radical spin label.

General Description

Fmoc-TOAC-OH is a useful tool for the incorporation of the ESR spin-label TOAC into peptide sequences [1]. Incorporation of this derivative and the following residue is best achieved using HATU activation. TFA/water/TIS should be used for cleavage of TOAC-containing peptides. The use of EDT should be avoided as it can cause permanent reduction of the nitroxide radical [2]. Following cleavage, the TOAC peptide should be treated with aqueous ammonia in air to regenerate the nitroxide from the hydroxylamine that is generated by the TFA treatment.

82911-69-1
15871-57-5
93372-25-9
Synthesis of FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID from N-(9-Fluorenylmethoxycarbonyloxy)succinimide and 2,2,6,6-TETRAMETHYLPIPERIDINE-1-OXYL-4-AMINO-4-CARBOXYLIC ACID

FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID Preparation Products And Raw materials

FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID Suppliers

Global( 16)Suppliers
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Fmoc-2,2,6,6-tetramethylpiperidine-N-oxyl-4-amino-4-carboxylic acid≥ 98% (HPLC) FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID FMOC-TOAC FMOC-TOAC-OH 100 MG FMOC-TOAC-OH 500 MG 4-(9H-fluoren-9-ylmethoxycarbonylamino)-2,2,6,6-tetramethyl-1-oxidopiperidin-1-ium-4-carboxylic acid 93372-25-9 Chiral Reagents Spin Labeling Compounds