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(S)-VANOL

CAS No.
147702-13-4
Chemical Name:
(S)-VANOL
Synonyms
(R)-VANOL;(S)-VANOL;(R)-VANOL 97%;(R)-VANOL,99%e.e.;(R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL;(S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL);3,3'-diphenyl-<2,2'-binaphthalene>-1,1'-diol;(2R)-3,3’-Diphenyl[2,2’-binaphthalene]-1,1’-diol;(2R)-3,3'- diphenyl [2,2'- binaphthyl ]-1,1'- diol;2,2'-Binaphthalene]-1,1'-diol, 3,3'-diphenyl-, (2R)-
CBNumber:
CB2188801
Molecular Formula:
C32H22O2
Molecular Weight:
438.52
MDL Number:
MFCD08459338
MOL File:
147702-13-4.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

(S)-VANOL Properties

Melting point 200-204 °C
Boiling point 580.1±50.0 °C(Predicted)
alpha +362° (c 1.0, THF)
Density 1.251±0.06 g/cm3(Predicted)
storage temp. 2-8°C
pka 7.71±0.50(Predicted)
form Powder
color white to pale yellow
optical activity [α]20/D +310°, c = 1 in chloroform
CAS DataBase Reference 147702-13-4

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07
Signal word  Danger
Hazard statements  H315-H318-H335-H413
Precautionary statements  P273-P280-P302+P352-P305+P351+P338+P310
Hazard Codes  Xi
Risk Statements  37/38-41
Safety Statements  26-39
WGK Germany  3

(S)-VANOL price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 675156 (R)-VANOL 97% 147702-13-4 250mg $178 2024-03-01 Buy
Strem Chemicals 08-1700 (2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol, min. 98% (R)-VANOL 147702-13-4 100mg $212 2024-03-01 Buy
Strem Chemicals 08-1700 (2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol, min. 98% (R)-VANOL 147702-13-4 500mg $838 2024-03-01 Buy
Ambeed A466556 (2R)-3,3'-Diphenyl[2,2'-binaphthalene]-1,1'-diol 98%99%ee 147702-13-4 100mg $68 2021-12-16 Buy
Ambeed A466556 (2R)-3,3'-Diphenyl[2,2'-binaphthalene]-1,1'-diol 98%99%ee 147702-13-4 1g $458 2021-12-16 Buy
Product number Packaging Price Buy
675156 250mg $178 Buy
08-1700 100mg $212 Buy
08-1700 500mg $838 Buy
A466556 100mg $68 Buy
A466556 1g $458 Buy

(S)-VANOL Chemical Properties,Uses,Production

Reaction

  1. Chiral ligand used in catalytic asymmetric aziridination.
  2. Chiral ligand used in catalytic asymmetric aminoallylation of aldehydes. 
Reactions of 147702-13-4

Uses

VANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

(S)-VANOL Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-VANOL Suppliers

Global( 31)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Acmec Biochemical Technology Co., Ltd.
+undefined18621343501 product@acmec-e.com China 33349 58
Aladdin Scientific
+1-833-552-7181 sales@aladdinsci.com United States 52927 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94838 76
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 6818 65
Shanghai Topbiochem Technology Co., Ltd +86-21-60341587 sales@topbiochem.com China 6181 58
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41438 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Shanghai Chiral bio-compound co., Ltd. 021-5068 3667/17749785980/1029026415; 17749785980 1029026415@qq.com China 2790 58
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
(2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol,min.98%(R)-VANOL (2R)-(+)-3,3''-DIPHENYL-[2,2''-BINAPHTHALENE]-1,1''-DIOL (R)-VANOL (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthalol, (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthol (S)-VANOL (R)-VANOL (S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL) (R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL (2S)-(-)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL (2R)-(+)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL (R)-VANOL 97% (R)-VANOL,99%e.e. 3,3'-diphenyl-<2,2'-binaphthalene>-1,1'-diol 2,2'-Binaphthalene]-1,1'-diol, 3,3'-diphenyl-, (2R)- (2R)-3,3'- diphenyl [2,2'- binaphthyl ]-1,1'- diol (2R)-(+)-3,3''-Diphenyl-[2,2''-binaphthalene]-1,1''-diol (2R)-3,3’-Diphenyl[2,2’-binaphthalene]-1,1’-diol 147702-13-4 BINOL Series Chiral Oxygen