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D(+)-Raffinose pentahydrate

CAS No.
17629-30-0
Chemical Name:
D(+)-Raffinose pentahydrate
Synonyms
RAFFINOSE PENTAHYDRATE;D-RAFFINOSE PENTAHYDRATE;β-D-fructofuranoside;MELITOSE;D-(+)-RAFFINOSE;Raffinose, 99%+;RAFFINOSE, 5-HYDRATE;D-(+)-Raffinose Melitose, Melitriose;MELITOSE PENTAHYDRATE
CBNumber:
CB2230061
Molecular Formula:
C18H42O21
Molecular Weight:
594.51
MDL Number:
MFCD00071590
MOL File:
17629-30-0.mol
MSDS File:
SDS
Last updated:2023-08-11 15:49:39

D(+)-Raffinose pentahydrate Properties

Melting point 78-80 °C
alpha 105 º (c=10,water,dry basis)
Boiling point 78-82℃
Density 1.465
storage temp. Inert atmosphere,Room Temperature
solubility H2O: 50 mg/mL
form powder
color White
Odor Odorless
optical activity [α]20/D +105±2°, c = 10% in H2O
Water Solubility 143 g/L
Sensitive Hygroscopic
Merck 14,8096
BRN 4285763
Stability Hygroscopic
InChIKey BITMAWRCWSHCRW-PFQJHCPISA-N
CAS DataBase Reference 17629-30-0(CAS DataBase Reference)
EPA Substance Registry System .alpha.-D-Glucopyranoside, .beta.-D-fructofuranosyl O-.alpha.-D-galactopyranosyl-(1.fwdarw.6)-, pentahydrate (17629-30-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280-P271
Hazard Codes  Xi
Risk Statements  36/38
Safety Statements  24/25-37/39-26
WGK Germany  3
RTECS  LZ5851200
3
TSCA  Yes
HS Code  29400000
NFPA 704
1
1 0

D(+)-Raffinose pentahydrate price More Price(56)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 83400 D-(+)-Raffinose pentahydrate for microbiology, ≥99.0% 17629-30-0 25g $116 2024-03-01 Buy
Sigma-Aldrich 83400 D-(+)-Raffinose pentahydrate for microbiology, ≥99.0% 17629-30-0 100g $343 2024-03-01 Buy
TCI Chemical R0002 D-(+)-Raffinose Pentahydrate >98.0%(HPLC) 17629-30-0 25g $23 2024-03-01 Buy
Alfa Aesar A18313 D-(+)-Raffinose pentahydrate, 99% 17629-30-0 10g $41.7 2024-03-01 Buy
Alfa Aesar A18313 D-(+)-Raffinose pentahydrate, 99% 17629-30-0 50g $125 2024-03-01 Buy
Product number Packaging Price Buy
83400 25g $116 Buy
83400 100g $343 Buy
R0002 25g $23 Buy
A18313 10g $41.7 Buy
A18313 50g $125 Buy

D(+)-Raffinose pentahydrate Chemical Properties,Uses,Production

Description

D-(+)-Raffinose is a trisaccharide composed of galactose, glucose, and fructose that occurs naturally in a variety of vegetables and grains. It is hydrolyzed to galactose and sucrose by α-galactosidase.

Chemical Properties

Raffinose is a white crystalline powder. It is odorless and has a sweet taste approximately 10% that of sucrose.

Uses

D-(+)-Raffinose is a trisaccharide built from 1 mol each of D-galactose, D-glucose, and D-fructose which are obtained from it by acid hydrolysis. Invertase splits it into melibiose and saccharose. D-(+)-Raffinose occurs in Australian manna; in cottonseed meal.

Uses

moisturizes and smoothes skin, prevents skin ageing, promotes skin regeneration: non-digestible with lower efficiency than lactose or sucrose; prebiotic stimulates growth of lactobacilli and bifidobacteria; additive in low-cariogenic food or drinks

Uses

D-(+)-Raffinose is a trisaccharide built from 1 mol each of D-galactose, D-glucose, and D-fructose which are obtained from it by acid hydrolysis. Invertase splits it into melibiose and saccharose. D- (+)-Raffinose occurs in Australian manna; in cottonseed meal.

Production Methods

Raffinose occurs naturally in Australian manna, cottonseed meal, and seeds of various food legumes. It can be isolated from beet sugar molasses through sucrose separation, seed-crystallization, and filtration.

Pharmaceutical Applications

Raffinose is a trisaccharide carbohydrate that is used as a bulking agent, blood substitute, stabilizing agent, and water scavenger in freeze-drying where it acts as a stabilizer for freeze-dried formulations. It is also used as a crystallization inhibitor in sucrose solutions.

Biochem/physiol Actions

Raffinose is a trisaccharide composed of galactose, fructose, and glucose. Raffinose is hydrolysed to D-galactose and sucrose by D-galactosidase.

Safety

Raffinose is a naturally occurring trisaccharide investigated for use in freeze-dried pharmaceutical formulations. It occurs in a number of plants that are consumed widely.

storage

Raffinose is stable under ordinary conditions of use and storage. Excessive heat should be avoided to prevent degradation. Thermal decomposition products are carbon monoxide and carbon dioxide.

Purification Methods

fructo-furanose [17629-30-0 (5H2O), 512-69-6 (anhydrous)] M 594.5, m 8 0o, 80 -82o, +124o (c 10, H2O), [ ] D +105o (c 1 for pentahydrate, H2O), pK 1 12.40, pK 2 13.44, pK 3 13.52. D(+)-Raffinose crystallises from H2O, 90% aqueous EtOH or MeOH as the pentahydrate. The anhydrous sugar has m 132-135o. It has RF 0.8 on TLC (Silica Gel, and 1:3:3 CHCl3/butanone:/MeOH). The undecaacetate has been purified through an alumina column by elution with CHCl3, and recrystallised from EtOH/MeOH/H2O (3:2:5), with m 99-100o, [] D +92.8o (c 5.14, EtOH). [pK : Coccioli & Vicedomini Ann Chim (Rome) 66 269, 275 1976, 1H NMR: Suami et al. Carbohydr Research 26 234 1973, Beilstein 17 III/IV 3801, 17/8 V 403.]

Incompatibilities

Raffinose is incompatible with strong oxidizers.

Regulatory Status

Raffinose is a naturally occurring trisaccharide and is consumed as part of a normal diet.

D(+)-Raffinose pentahydrate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 468)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Zhanyao Biotechnology Co. Ltd
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Henan Bao Enluo International TradeCo.,LTD
+86-17331933971 +86-17331933971 deasea125996@gmail.com China 2503 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
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+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
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Shanghai Zheyan Biotech Co., Ltd.
18017610038 zheyansh@163.com CHINA 3620 58
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+86-0371-86658258 sales@coreychem.com China 29914 58
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View Lastest Price from D(+)-Raffinose pentahydrate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
D(+)-Raffinose pentahydrate; Cottonseed extract pictures 2024-04-23 D(+)-Raffinose pentahydrate; Cottonseed extract
17629-30-0
US $0.00 / KG 1KG 98% TLC 1000KG Changsha Staherb Natural Ingredients Co., Ltd.
D(+)-Raffinose pentahydrate pictures 2024-01-08 D(+)-Raffinose pentahydrate
17629-30-0
US $9.00 / KG 1KG 99% 50000tons Wuhan Boyuan Import & Export Co., LTD
D(+)-Raffinose pentahydrate pictures 2023-08-16 D(+)-Raffinose pentahydrate
17629-30-0
US $498.00 / KG 1KG >99% 50000kg/Month Weijer International Trade (Hebei) Co., Ltd
RAFFINOSE, 5-HYDRATE O-ALPHA-D-GALACTOPYRANOSYL-(1->6)-ALPHA-D-GLUCOPYRANOSYL BETA-D-FRUCTOFURANOSIDE PENTAHYDRATE 6-O-ALPHA-D-GALACTOPYRANOSYL-D-GLUCOPYRANOSYL-BETA-D-FRUCTOFURANOSIDE PENTAHYDRATE 1,6-ALPHA-D-RAFFINOSE PENTAHYDRATE 1,6-A-D-RAFFINOSE PENTAHYDRATE BETA-D-FRUCTOFURANOSYL-O-ALPHA-D-GLUCOPYRANOSIDE, PENTAHYDRATE D-(+)-RAFFINOSE D-(+)-RAFFINOSE PENTAHYDRATE MELITOSE MELITOSE PENTAHYDRATE MELITRIOSE PENTAHYDRATE GOSSYPOSE PENTAHYDRATE 1,6-α-D-Raffinose pentahydrate D-(+)-Raffinose pentahydrate,O-α-D-Galactopyranosyl-(1→6)-α-D-glucopyranosyl β-D-fructofuranoside, Melitose, Melitriose D(+)-Raffinose pentahydrate, for biology ALPHA-D-RAFFINOSE RESEARCH GRADE D-Raffinose pentahydrate ,98% (α-Galactosyl)sucrose 1,6-(α-Galactopyranosyl)-α-D-glucopyranosyl-β-D-fructofuranoside Nittenraffinose Pentahydrate NSC 170228 Pentahydrate β-D-Fructofuranosyl-O-a-D-galactopyranosyl-(1→6)-α-D-glucopyranoside D-(+)-Raffinose  O-α-D-Galactopyranosyl-(1→6)-α-D-glucopyranosyl Melitose, Melitriose 6-O-α-D-Galactopyranosyl-D-glucopyranosyl-β-D-fructofuranoside O-α-D-Galactopyranosyl-(1rightarrow6)-α-D-glucopyranosyl β-D-fructofuranoside D-(+)-Raffinose (hydrate) O-α-D-Galactopyranosyl-(1→6)-α-D-glucopyranosyl β-D-fructofuranoside beta-D-fructofuranosyl-6-O-alpha-D-galactopyranosyl-alpha-D-glucopyranoside D(+)-RAFFINOSE PENTAHYDRATE, FOR MICROBI OLOGY D(+)-RAFFINOSE PENTAHYDRATE SIGMAULTRA D(+)RAFFINOSE PENTAHYDRATE CELL CULTURE TESTED O-a-D-Galactopyranosyl-(1->6)-a-D-glucopyranosyl-D-fructofuranoside Melitose, Melitriose .alpha.-D-Glucopyranoside, .beta.-D-fructofuranosyl O-.alpha.-D-galactopyranosyl-(1?6)-, pentahydrate RAFFINOSE, D-(+)-(RG) D-(+)-RAFFINOSE PENTAHYDRATE, BIOTECH GRADE 99+% RaffinosePentahydrate(Melitose) RAFFINOSE GR (PENTAHYDRATE) D(+)-Raffinose pentahydrate, 99+% D-RAFFINOSE extrapure Melitose, Melitriose, O-α-D-Galactopyranosyl-(1-6)-α-D-glucopyranosyl β-D-fructofuranoside D-(+)-Raffinose pentahydrate, Melitose, Melitriose, 6-O-α-D-Galactopyranosyl-D-glucopyranosyl-β-D-fructofuranoside, O-α-D-Galactopyranosyl-(1rightarrow6)-α-D-glucopyranosyl β-D-fructofuranoside α-D-galactopyranosyl-(1->6)-O-α-D-glucopyranosyl-(1->2)-β-D-fructofuranoside pentahydrate O-a-D-Galactopyranosyl-(1-6)-a-D-glucopyranosyl b-D-fructofuranoside pentahydrate D-(+)-Raffinose Pentahydrate> α-D-Glucopyranoside, β-D-fructofuranosyl O-α-D-galactopyranosyl-(1→6)-, hydrate (1:5) D-(+)-Raffinose pentahydrate Solution, 100μg/mL D(+)-Raffinose pentahydrate USP/EP/BP Raffinose, 99%+ D-Raffinose Pentahydrate extrapure (3 S,4 S,5 R,6 R)-2-[[(2 R,3 S,4 S,5 S)-6-[(2 S,3 S,4 R,5 R)-3,4-dihydroxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxy-3,4,5-trihydroxyoxan-2-yl]methoxy]-6-(hydroxymethyl)oxane-3,4,5-triol D-RAFFINOSE PENTAHYDRATE For Biochemistry RAFFINOSE PENTAHYDRATE D-RAFFINOSE PENTAHYDRATE β-D-fructofuranoside O-α-D-Galactopyranosyl-(1→6)-α-D-glucopyranosyl β-D-fructofuranoside Raffinose, pentahydrate (8CI)