ChemicalBook
Chinese Japanese Germany

N-Bromosuccinimide

N-Bromosuccinimide
N-Bromosuccinimide
CAS No.
128-08-5
Chemical Name:
N-Bromosuccinimide
Synonyms
NBS;NSC 16;NIBRIN;SUCCINBROMIDE;SUCCINBROMIMIDE;bromosuccinimide;N-Bromsuccinimid;Succinibromimide;N-BROMOSUCINIMIDE;AKOS BBS-00004413
CBNumber:
CB2234049
Molecular Formula:
C4H4BrNO2
Formula Weight:
177.98
MOL File:
128-08-5.mol

N-Bromosuccinimide Properties

Melting point:
175-180 °C (dec.)(lit.)
Boiling point:
221.4°C (rough estimate)
Density 
2.098
refractive index 
1.6060 (estimate)
storage temp. 
0-6°C
solubility 
14.8g/l (decomposition)
form 
Crystalline Powder
color 
White to light yellow
Water Solubility 
Soluble in acetone, tetrahydrofuran, dimethyl formamide, dimethyl sulfoxide and acetonitrile. Slightly soluble in water and acetic acid. Insoluble in ether, hexane and carbon tetrachloride.
Sensitive 
Moisture Sensitive
Merck 
14,1438
BRN 
113916
Stability:
Stable. Incompatible with strong oxidizing agents, halogenated hydrocarbons.
InChIKey
PCLIMKBDDGJMGD-UHFFFAOYSA-N
CAS DataBase Reference
128-08-5(CAS DataBase Reference)
NIST Chemistry Reference
2,5-Pyrrolidinedione, 1-bromo-(128-08-5)
EPA Substance Registry System
2,5-Pyrrolidinedione, 1-bromo-(128-08-5)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  C,Xn
Risk Statements  22-34-36/37/38
Safety Statements  26-36/37/39-45-37/39
RIDADR  UN 3261 8/PG 2
WGK Germany  3
Hazard Note  Harmful
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29251995
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H290 May be corrosive to metals Corrosive to Metals Category 1 Warning P234, P390, P404
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
Precautionary statements:
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P390 Absorb spillage to prevent material damage.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P406 Store in corrosive resistant/… container with a resistant inner liner.
P501 Dispose of contents/container to..…

N-Bromosuccinimide price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B81255 N-Bromosuccinimide 99% 128-08-5 5g $27 2018-11-20 Buy
Sigma-Aldrich B81255 N-Bromosuccinimide 99% 128-08-5 1kg $119 2018-11-20 Buy
TCI Chemical B0656 N-Bromosuccinimide >98.0%(T) 128-08-5 25g $15 2018-11-22 Buy
TCI Chemical B0656 N-Bromosuccinimide >98.0%(T) 128-08-5 100g $25 2018-11-22 Buy
Alfa Aesar A15922 N-Bromosuccinimide, 99% 128-08-5 250g $37.8 2018-11-13 Buy

N-Bromosuccinimide Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystalline powder

Uses

N-Bromosuccinimide is a brominated succinimide used as a chemical reagent in radical substitution and electrophilic addition reactions in organic synthesis.

Uses

NBS, is a chemical reagent used in organic chemistry in electrophilic addition reactions and radical substitution

Uses

In bromination of olefins; in oxidation of alcohols to aldehydes and ketones and of aldehydes to acid bromides.

Definition

ChEBI: A five-membered cyclic dicarboximide compound having a bromo substituent on the nitrogen atom.

Safety Profile

Poison by intraperitoneal route. An irritating poison to skin, eyes, and mucous membranes. Reacts explosively with adme, dtallyl sulfide, and hydrazine hydrate. Explosive reaction with propiononitrile after heating to 105℃ for 24 hours. Violent reaction with dtbenzoyl peroxide + 4-tok acid. When heated to decomposition it emits toxic fumes of Brand NOx. See also BROMIDES and NITROGEN MONOXIDE.

Purification Methods

N-Bromosuccinimide (30g) is purified by dissolving rapidly in 300mL of boiling water and filtering through a fluted filter paper into a flask immersed in an ice bath, and left for 2hours. The crystals are filtered off, washed thoroughly with ca 100mL of ice-cold water and drained on a Büchner funnel before drying under vacuun over P2O5 or CaCl2 [Dauben & McCoy J Am Chem Soc 81 4863 1959]. This brominating agent has also been crystallised from acetic acid or water (10 parts), washed in water and dried in vacuo [Wilcox et al. J Am Chem Soc 108 7693 1986, Shell et al. J Am Chem Soc 108 121 1986, Phillips & Cohen J Am Chem Soc 108 2013 1986, Beilstein 21/9 V 543.]

N-Bromosuccinimide Preparation Products And Raw materials

Raw materials

Preparation Products


N-Bromosuccinimide Suppliers

Global( 443)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Hebei Guanlang Biotechnology Co., Ltd.
+86-0311-66562153 whatsapp +8615203118427
+86-0311-66562153 sales@crovellbio.com CHINA 417 50
Shenzhen Sendi Biotechnology Co.Ltd.
0755-23311925 18102838259
0755-23311925 Abel@chembj.com CHINA 3218 55
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22080 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20795 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555
+86-021-57951555 jack.li@time-chemicals.com CHINA 1374 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32764 55
Hangzhou FandaChem Co.,Ltd.
0086 158 5814 5714 (Mobile; WhatsApp; Telegram)
+86-571-56059825 fandachem@gmail.com CHINA 1915 55
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070;product@chemlin.com.cn
product@chemlin.com.cn CHINA 3015 60
Nanjing Finetech Chemical Co., Ltd.
025-85710122 17714198479
025-85710122 sales@fine-chemtech.com CHINA 894 55
Zjartschem
+86-571-8723 8903 jocelynpan@zjarts.com
+86-571-87063838 jocelynpan@zjarts.com CHINA 660 58

View Lastest Price from N-Bromosuccinimide manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-07-23 N-Bromosuccinimide
128-08-5
US $100.00 / KG 5KG 99% 100tons

128-08-5(N-Bromosuccinimide)Related Search:


Copyright 2017 © ChemicalBook. All rights reserved