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PMK ethyl glycidate

CAS No.
28578-16-7
Chemical Name:
PMK ethyl glycidate
Synonyms
GLYCIDATE;ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate;Pmk Glycidate Oil;3,4-MDP-2-P intermediate;ethyl 3-(benzo[d][1,3]dioxol-5-yl)-2-methyloxirane-2-carboxylate;2-Oxiranecarboxylicacid, 3-(1,3-benzodioxol-5-yl)-2-Methyl-, ethyl ester;cheap 3,4-MDP-2P ethyl ester;3-(1,3-benzodioxol-5-yl)-2-Methyl-;PMK BMK;New PMK
CBNumber:
CB22731285
Molecular Formula:
C13H14O5
Molecular Weight:
250.25
MDL Number:
MFCD30478653
MOL File:
28578-16-7.mol
Last updated:2023-06-02 14:42:00

PMK ethyl glycidate Properties

Boiling point 327.8±42.0 °C(Predicted)
Density 1.302±0.06 g/cm3(Predicted)
solubility DMF: 15 mg/ml; DMSO: 30 mg/ml; Ethanol: 10 mg/ml; PBS (pH 7.2): 1 mg/ml

PMK ethyl glycidate price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Cayman Chemical 21990 PMK ethyl glycidate ≥98% 28578-16-7 1mg $64 2023-01-06 Buy
Cayman Chemical 21990 PMK ethyl glycidate ≥98% 28578-16-7 5mg $168 2023-01-06 Buy
TRC N900275 NSC195099 28578-16-7 10mg $140 2021-12-16 Buy
AK Scientific 9011CB Ethyl3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate 28578-16-7 1mg $179 2021-12-16 Buy
AK Scientific 9011CB Ethyl3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate 28578-16-7 5mg $309 2021-12-16 Buy
Product number Packaging Price Buy
21990 1mg $64 Buy
21990 5mg $168 Buy
N900275 10mg $140 Buy
9011CB 1mg $179 Buy
9011CB 5mg $309 Buy

PMK ethyl glycidate Chemical Properties,Uses,Production

Description

PMK ethyl glycidate is an analytical reference standard categorized as a precursor in the synthesis of methylenedioxy phenethylamines and amphetamines, including 3,4-MDMA. This product is intended for research and forensic applications.

Uses

NSC 195099 can be used as an analytical reference standard.

Application

PMK methyl glycidate is applied as immediate precursors of 3,4-methylenedioxymethamphetamine. 

Synthesis

To a solution of piperonal (1, 3.00 g, 19.9 mmol) in CH2Cl2 (100 mL) was added (carbethoxyethylidene)triphenylphosphorane (2,14.5 g, 40.0 mmol), and the reaction mixture was stirred for 24 h at room temperature. The mixture was then concentrated at reduced pressure, and the residue was purified by flash column chromatography on silica gel (hexanes/EtOAc,10:1) to afford olefin 3 (4.45 g, 95%) as a colorless oil: 1H NMR (400 MHz, CDCl3) d 7.58 (s, 1H), 6.92 (d, J = 1.7 Hz, 1H), 6.90 (dd, J = 7.9, 1.7 Hz, 1H), 6.82 (d, J = 8.0 Hz, 1H), 5.97 (s, 2H), 4.24 (q, J = 7.1 Hz, 2H), 2.10 (d, J = 1.6 Hz, 3H),1.33 (t, J = 7.1 Hz, 3H); 13C NMR (100 MHz, CDCl3) d 168.7,147.6, 138.3, 129.9, 126.9, 124.6, 109.5, 108.2, 101.2,  60.7, 14.3,1 4.0; IR (ATR, cm-1): 2981, 2902,1698, 1628, 1502, 1489,1442, 1258, 1224; HRMS (EI) m/z calcd for C13H14O4 (M+) 234.0892, found 234.0895.
synthetic step of PMK ethyl glycidateFig The synthetic step of PMK ethyl glycidate

PMK ethyl glycidate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 159)Suppliers
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Wuhan Aoliqisi New Material Technology Co., Ltd.
+8613545906766 sales@whaop.com China 294 58
Zibo Dorne Chemical Technology co. LTD
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Hebei Minshang Biotechnology Co.,Ltd
+8613582176207 cathy@hbminshang.cn China 300 58
HEBEI YINGONG NEW MATERIAL TECHNOLOGY CO.,LTD
+86-19933070948 +86-19930599843 claire@hbyingong.com China 963 58
Shanxi Lianxu New Material Co., LTD
+86-18903404542 vevi@lianxuchemical.com China 611 58

Related articles

View Lastest Price from PMK ethyl glycidate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Oxiranecarboxylicacid pictures 2023-06-03 2-Oxiranecarboxylicacid
28578-16-7
US $0.00 / kg 1kg 99% 500t /month Shanxi Boaoke New Material Co., Ltd
PMK ethyl glycidate pictures 2023-06-03 PMK ethyl glycidate
28578-16-7
US $0.00-0.00 / kg 1kg 99% 1000kg Suzhou Sanyi Polymer Chemical Technology Co., Ltd.
ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate pictures 2023-06-03 ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate
28578-16-7
US $0.00-0.00 / g 10g 98%+ 10000kgs per Month Shanghai Qyubiotech Co., Ltd.
  • PMK ethyl glycidate pictures
  • PMK ethyl glycidate
    28578-16-7
  • US $0.00-0.00 / kg
  • 99%
  • Suzhou Sanyi Polymer Chemical Technology Co., Ltd.
3,4-MDP-2P ethyl ester Pharmaceutical intermediates 2-Oxiranecarboxylicacid 2-Oxiranecarboxylicacid, 3-(1,3-benzod.../3,4-MDP-2-P intermediate new p 28578-16-7 3-(1,3-benzod.../3,4-MDP-2-P intermediate BMK CAS 28578-16-7 Ethyl 3-(1,3-benzodioxol-5-yl)-2-methyl-2-oxiranecarboxylate Ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate Liquid PMK BMK new pmk oil OXIRANECARBOXYLICACID, 3-(1,3-BENZODIOXOL-5-YL)-2-METHYL-, ETHYL ESTER /PMK / BMK / PMK ethyl glycidate BMK PMK Oil Ethyl Glycidate Oil 99% Purity White crystilline powder ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate GLYCIDATE oil PMK ethyl glycidate (PMK powder&oil) pmk, 3-(1,3-benzodioxol-5-yl)-2-Methyl- NEW PMK,Pmk,Pmk Glycidate Oil PMK ethyl glycidate 3,4-MDP-2-P intermediate 2-Oxiranecarboxylicacid, 3-(1,3-benzodioxol-5-yl)-2-Methyl-, ethyl ester ethyl 3-(benzo[d][1,3]dioxol-5-yl)-2-methyloxirane-2-carboxylate 3-(1,3-benzodioxol-5-yl)-2-Methyl- cheap 3,4-MDP-2P ethyl ester Pmk Glycidate Oil GLYCIDATE ethyl 3-(1,3-benzodioxol-5-yl)-2-methyloxirane-2-carboxylate New PMK PMK liquid PMK Oil/ Powder PMK ethyl glycidate oil ethyl3-(1,3-benzodioxol-5-yl)-2-methyChemicalbookloxirane-2-carboxylate pmk oil 28578-16-7 2-Oxiranecarboxylicacid, 3-(1,3-benzodioxol-5-yl)-2-Methyl-, ethyl ester (Related Reference) benzodioxol Methyl piperonyl epoxy propionate ethyl ester 28578-16-7 28578-16-1 28578-16-6 28578-17-6 28578-15-7 28587-16-7 28578-16-7 1 28578 PMK Pharm