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6-Bromoquinoline

Bromoquinoline Application and synthetic method
6-Bromoquinoline
6-Bromoquinoline
CAS No.
5332-25-2
Chemical Name:
6-Bromoquinoline
Synonyms
NSC 3996;6-Br-quinoline;6-bromo-quinolin;6-BROMOQUINOLINE;6-BROMOOQUINOLINE;Quinoline, 6-bromo-;TIMTEC-BB SBB001559;6-Bromoquinoline,97%;6-BROMOQUINOLINE 95+%;6-Bromoquinoline ,98%
CBNumber:
CB2314673
Molecular Formula:
C9H6BrN
Formula Weight:
208.05
MOL File:
5332-25-2.mol

6-Bromoquinoline Properties

Melting point:
19°C
Boiling point:
116 °C / 6mmHg
Density 
1.55
refractive index 
n20/D 1.663
Flash point:
19 °C
storage temp. 
Refrigerator
solubility 
Soluble in acetone, acetonitrile, dichloromethane, ethyl acetate and THF.
InChIKey
IFIHYLCUKYCKRH-UHFFFAOYSA-N
CAS DataBase Reference
5332-25-2(CAS DataBase Reference)
NIST Chemistry Reference
6-Bromo quinoline(5332-25-2)
EPA Substance Registry System
Quinoline, 6-bromo-(5332-25-2)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-41-37/38-22-20/21/22
Safety Statements  26-37/39-39-36
WGK Germany  3
Hazard Note  Irritant
TSCA  Yes
HazardClass  IRRITANT
HS Code  29334900
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

6-Bromoquinoline price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 697893 6-Bromoquinoline 97% 5332-25-2 1g $41.9 2018-11-13 Buy
Sigma-Aldrich 697893 6-Bromoquinoline 97% 5332-25-2 5g $138 2018-11-13 Buy
TCI Chemical B2015 6-Bromoquinoline >95.0%(GC) 5332-25-2 1g $17 2018-11-22 Buy
TCI Chemical B2015 6-Bromoquinoline >95.0%(GC) 5332-25-2 5g $53 2018-11-22 Buy
Alfa Aesar H55111 6-Bromoquinoline, 97% 5332-25-2 5g $120 2018-11-13 Buy

6-Bromoquinoline Chemical Properties,Uses,Production

Bromoquinoline

There are seven positional isomers of bromoquinoline and their main properties are listed below: There are seven positional isomers of bromoquinoline and their main properties are listed

Application and synthetic method

3-bromo-quinoline is reacted with mixed acid for generating 3-bromo-5-nitro-quinoline, which heats together with potassium permanganate for being oxidation into 5-bromo-2, 3-pyridine dicarboxylic acid.
6-bromo-quinoline is heated together with nitric acid to generate 6-bromo-8-nitro quinolone with further reaction with potassium permanganate for being oxidized to 2, 3-pyridinedicarboxylic acid.
2-bromo-quinolien can be synthesized through the reaction between 2-hydroxy quinoline and phosphorus pentabromide.
Quinoline perbromide is heated at 180 °C for generating 3-bromo-quinoline.
From the heating between 4-hydroxy quinoline and phosphorus pentabromide, or from the diazotization reaction via 4-aminoquinoline to generate 4-bromo-quinoline;
5-bromo-quinoline is synthesize by the heating reaction between m-bromo-aniline, glycerol, m-bromo nitrobenzene and concentrated sulfuric acid, or from the diazotization reaction of 5-aminoquinoline.
6-bromo-quinoline can be synthesized from the heating of bromoaniline, glycerol, concentrated sulfuric acid, and p-bromo-nitrobenzene. 7-bromo-quinoline can be synthesized from the diazotization reaction of 7-aminoquinoline.
8-bromo-quinoline can be synthesized from the heating reaction of o-bromo-aniline, glycerol, concentrated sulfuric acid and o-bromo nitrobenzene.
application: as organic synthesis reagents.
The above information is edited by the Chemicalbook of Dai Xiongfeng.

Chemical Properties

Thick Oil

6-Bromoquinoline Preparation Products And Raw materials

Raw materials

Preparation Products


6-Bromoquinoline Suppliers

Global( 271)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
China Synchem Technology Co.,Ltd.
0552-4929304
0552-4928800 sales@cnsynchem.com CHINA 45 55
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22049 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20786 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32651 55
ATK CHEMICAL COMPANY LIMITED
+86 21 5161 9050/ 5187 7795
+86 21 5161 9052/ 5187 7796 ivan@atkchemical.com CHINA 14293 60
Accela ChemBio Inc.
(+1)-858-699-3322
(+1)-858-876-1948 info@accelachem.com United States 12156 58
HaBo Hong Kong Co., Limited.
+86-25-18512596065
info@habotech.com CHINA 509 58
Shenzhen Nexconn Pharmatechs Ltd
15013857715
admin@nexconn.com CHINA 2515 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19990 58
Shanghai Harvest Chemical Industrial Co., Ltd. +86-21-31038972, 31038973
+86-21-51385350 ammyzuo@harvest-chem.com China 2445 64

View Lastest Price from 6-Bromoquinoline manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-14 6-Bromoquinoline
5332-25-2
US $1.00 / kg 1kg as customer's need 1000kg career henan chemical co

6-Bromoquinoline Spectrum


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