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Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)

CAS No.
27057-09-6
Chemical Name:
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
Synonyms
Bis(triphenylphosphino)(2-methylphenyl)chloronickel;Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II);BIS(TRIPHENYLPHOSPHINO)(2-METHYLPHENYL)CHLORONICKEL(II),99%;Bis(triphenylphosphine) (2-methylphenyl) Nickel(II) chloride;Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99%;2-[(7R,10S,13R,16R,19R,22S,25R)-25-amino-13-(4-aminobutyl)-7,22-dibenzyl-10-[(1R)-1-hydroxyethyl]-16,19-bis(1H-indol-3-ylmethyl)-6,9,12,15,18,21,24-heptaoxo-1,2-dithia-5,8,11,14,17,20,23-heptazacyclohexacos-5-yl]acetamide
CBNumber:
CB23151060
Molecular Formula:
C43H39ClNiP2
Molecular Weight:
711.88
MDL Number:
MFCD28144558
MOL File:
27057-09-6.mol
Last updated:2023-04-23 13:52:06

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Properties

Melting point 195-200°C
storage temp. 2-8°C
form Powder
color yellow
CAS DataBase Reference 27057-09-6

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08
Signal word  Danger
Hazard statements  H317-H350
Precautionary statements  P201-P280-P302+P352-P308+P313
WGK Germany  3

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 794279 Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) 27057-09-6 250mg $81.6 2024-03-01 Buy
Sigma-Aldrich 794279 Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) 27057-09-6 1g $358 2024-03-01 Buy
Strem Chemicals 28-0096 Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99% 27057-09-6 250mg $117 2024-03-01 Buy
Strem Chemicals 28-0096 Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99% 27057-09-6 1g $352 2024-03-01 Buy
Arctom AS591439 Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II) 98% 27057-09-6 1g $160 2021-12-16 Buy
Product number Packaging Price Buy
794279 250mg $81.6 Buy
794279 1g $358 Buy
28-0096 250mg $117 Buy
28-0096 1g $352 Buy
AS591439 1g $160 Buy

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Chemical Properties,Uses,Production

Reaction

  1. This complex is used as an air-stable nickel precatalyst for the amination of aryl chlorides, sulfamates, mesylates, and triflates.
  2. This nickel precatalyst is used for the polymerization of halothiophenes. 
Reactions of 27057-09-6

Uses

Product is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers.

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) Suppliers

Global( 34)Suppliers
Supplier Tel Email Country ProdList Advantage
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 12722 58
Career Henan Chemica Co
+86-0371-86658258 15093356674; laboratory@coreychem.com China 30255 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
Hunan russell chemicals technology co ltd
731-88557738 +8613739093081 sales01@russellchem.com CHINA 291 58
Shandong Dexiang International Trade Co., Ltd
15662695772;+8615662691337 sales006@dexiangchemical.com China 998 58
Aladdin Scientific
+1-833-552-7181 sales@aladdinsci.com United States 52927 58
BeiJing Hwrk Chemicals Limted 0757-86329057 18501085097 sales3.gd@hwrkchemical.com China 7639 55
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41438 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Alfa Chemistry 1-516-6625404 support@alfa-chemistry.com United States 9171 60
Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) BIS(TRIPHENYLPHOSPHINO)(2-METHYLPHENYL)CHLORONICKEL(II),99% Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II), 99% 2-[(7R,10S,13R,16R,19R,22S,25R)-25-amino-13-(4-aminobutyl)-7,22-dibenzyl-10-[(1R)-1-hydroxyethyl]-16,19-bis(1H-indol-3-ylmethyl)-6,9,12,15,18,21,24-heptaoxo-1,2-dithia-5,8,11,14,17,20,23-heptazacyclohexacos-5-yl]acetamide Bis(triphenylphosphino)(2-methylphenyl)chloronickel Bis(triphenylphosphine) (2-methylphenyl) Nickel(II) chloride 27057-09-6 C43H37ClNiP2