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LITHIUM METHOXIDE

LITHIUM METHOXIDE
LITHIUM METHOXIDE
CAS No.
865-34-9
Chemical Name:
LITHIUM METHOXIDE
Synonyms
Methoxylithium;LITHIUMMETHOXID;LITHIUM METHYLATE;LITHIUM METHOXIDE;lithium methanolate;methanol,lithiumsalt;Lithiummethoxide;96.8%;;Lithium methoxide, 98+%;Lithiummethoxide,min.95%;lithium methoxide solution
CBNumber:
CB2315281
Molecular Formula:
CH3LiO
Formula Weight:
37.97
MOL File:
865-34-9.mol

LITHIUM METHOXIDE Properties

Melting point:
500°C
Boiling point:
64.6 °C
Density 
0.85 g/mL at 20 °C
Flash point:
52 °F
storage temp. 
Flammables area
solubility 
Soluble in methanol.
form 
powder
color 
White
Sensitive 
Moisture Sensitive
Stability:
Stable, but reacts violently with water. Highly flammable. Store under dry inert gas.
CAS DataBase Reference
865-34-9(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  F,T,C
Risk Statements  14-17-34-39/23/24/25-36/38-23/24/25-11
Safety Statements  8-16-26-43-45-36/37/39-36/37
RIDADR  UN 3274 3/PG 2
WGK Germany  3
3-10-23
TSCA  Yes
HazardClass  4.2
PackingGroup  II
HS Code  29051990
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H251 Self-heating; may catch fire Self-heating substances and mixtures Category 1 Danger
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P235+P410 Keep cool. Protect from sunlight.
P310 Immediately call a POISON CENTER or doctor/physician.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

LITHIUM METHOXIDE price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 344370 Lithium methoxide 98% 865-34-9 25g $65.7 2018-11-20 Buy
Sigma-Aldrich 344370 Lithium methoxide 98% 865-34-9 100g $184 2018-11-20 Buy
Alfa Aesar 044129 Lithium methoxide, 98+% 865-34-9 25g $53.8 2018-11-16 Buy
Alfa Aesar 044129 Lithium methoxide, 98+% 865-34-9 100g $157 2018-11-16 Buy
Strem Chemicals 93-0335 Lithium methoxide, 10% in methanol 865-34-9 500g $128 2018-11-13 Buy

LITHIUM METHOXIDE Chemical Properties,Uses,Production

Chemical Properties

white powder

Purification Methods

The most probable impurity is LiOH due to hydrolysis by moisture. It is important to keep the sample dry. It can be dried by keeping in a vacuum at 60-80o under dry N2 using an oil pump for a few hours. Store it under N2 in the cold. It should not have bands above 3000cm-1, IR has 1078, 2790, 2840 and 2930cm-1 in KBr. [Suebold J Org Chem 21 1561956, Beilstein 1 IV 1220, 1241.]

LITHIUM METHOXIDE Preparation Products And Raw materials

Raw materials

Preparation Products


LITHIUM METHOXIDE Suppliers

Global( 140)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
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Mainchem Co., Ltd.
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Shandong Yinglang Chemical Co.,Ltd. 18888295188;18888295177
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