ChemicalBook >> CAS DataBase List >>Carbonyltris(triphenylphosphine)rhodium(I) hydride
Carbonyltris(triphenylphosphine)rhodium(I) hydride
- CAS No.
- 17185-29-4
- Chemical Name:
- Carbonyltris(triphenylphosphine)rhodium(I) hydride
- Synonyms
- HRh(CO)(PPh3)3;(betab-5-23)-rhodiu;Carbonyltris(triphen;HRh(CO)(PPh3)3 - RODRIDO;Carbonyltris(triphenylphosphine)rhodium;Carbonylhydridotris(triphenylphosphine);TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) &;Carbonyltris(triphenylphosphine)rhodiuM(I);Carbonylhydrotris(triphenylphosphin)rhodium;Carbonyl triphenylphosphine rhodiuM hydride
- CBNumber:
- CB2322445
- Molecular Formula:
- 3C18H15P.CO.HRh
- Molecular Weight:
- 918.8
- MDL Number:
- MFCD00151644
- MOL File:
- 17185-29-4.mol
Last updated:2023-10-21 14:20:03
| Melting point | 150 °C (dec.) (lit.) |
|---|---|
| Density | 1.33 |
| vapor pressure | 0Pa at 25℃ |
| storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
| solubility | Soluble in hydrocarbons (e.g. benzene and toluene) with dissociation of phosphine ligands |
| form | crystal |
| color | light yellow |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| Merck | 14,9758 |
| Exposure limits |
ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3 NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 |
| InChIKey | CEKFIOLKXHVOKA-UHFFFAOYSA-N |
| CAS DataBase Reference | 17185-29-4(CAS DataBase Reference) |
| FDA UNII | 720P7594ZM |
| NIST Chemistry Reference | carbonyl(hydrido)tris(triphenylphosphine)rhodium(17185-29-4) |
| EPA Substance Registry System | Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)- (17185-29-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H413-H301+H311+H331 | |||||||||
| Precautionary statements | P261-P264-P270-P271-P280-P301+P310+P330-P302+P352+P312+P361+P364-P304+P340+P311-P403+P233-P405-P501 | |||||||||
| Hazard Codes | T | |||||||||
| Risk Statements | 23/24/25 | |||||||||
| Safety Statements | 36/37/39-45-36/37 | |||||||||
| RIDADR | UN 2811 6.1/PG 2 | |||||||||
| WGK Germany | 1 | |||||||||
| F | 10-23 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 4.3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28439000 | |||||||||
| NFPA 704 |
|
Carbonyltris(triphenylphosphine)rhodium(I) hydride price More Price(35)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 225665 | Tris(triphenylphosphine)rhodium(I) carbonyl hydride 97% | 17185-29-4 | 500mg | $251 | 2024-03-01 | Buy |
| Sigma-Aldrich | 225665 | Tris(triphenylphosphine)rhodium(I) carbonyl hydride 97% | 17185-29-4 | 5g | $1760 | 2024-03-01 | Buy |
| TCI Chemical | C1383 | Carbonylhydridotris(triphenylphosphine)rhodium(I) | 17185-29-4 | 1g | $396 | 2024-03-01 | Buy |
| TCI Chemical | C1383 | Carbonylhydridotris(triphenylphosphine)rhodium(I) | 17185-29-4 | 5g | $1189 | 2024-03-01 | Buy |
| Alfa Aesar | 010016 | Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 10.0% min | 17185-29-4 | 0.1g | $47.2 | 2023-06-20 | Buy |
Carbonyltris(triphenylphosphine)rhodium(I) hydride Chemical Properties,Uses,Production
Chemical Properties
Carbonylhydrido-tris(triphenylphosphine)rhodium(I), carbonyl-tris(triphenylphosphine)rhodium(I) hydride, forms yellow crystals that are stable in air, mp 172 – 174℃ in a closed nitrogen-filled capillary. It is readily soluble in benzene, chloroform, and dichloromethane. In solution, one phosphine ligand is readily lost by dissociation to give a 16-electron complex that is an active catalyst for the hydrogenation of alkenes and for hydroformylation.
Uses
Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation
Uses
Carbonylhydrido-tris(triphenylphosphine)rhodium(I) is used in industry for the hydroformylation of alkenes by the low pressure oxo (LPO) process developed by Union Carbide, Davy Power Gas, and Johnson Matthey. The reaction takes place rapidly at 25℃ giving a product in which the ratio of n- to iso-aldehydes is very favorable (ca. 20 : 1), a much higher ratio than can be obtained with cobalt catalysts.
Production Methods
Carbonyltris(triphenylphosphine)rhodium(I) hydride is obtained by the reaction of a solution of RhCl3.3 H2O in alcoholic alkali with aqueous formaldehyde (the carbon monoxide source) and an excess of triphenyl phosphine. The commercial product is a microcrystalline powder with a purity of 97 % (Degussa).
Carbonyltris(triphenylphosphine)rhodium(I) hydride Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 223)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| AB PharmaTech,LLC | 323-480-4688 | United States | 989 | 55 | |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
| SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | contact@trustwe.com | China | 5738 | 58 |
| SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17367 | 58 |
| Shanghai Daeyeon Chemicals Co., Ltd | 021-64478606 +8615900664856 | daeyeon001@vip.163.com | China | 2062 | 58 |
| Shanghai Bosheng Metal Materials Co. LTD | 18601346310 | CHINA | 153 | 58 |
View Lastest Price from Carbonyltris(triphenylphosphine)rhodium(I) hydride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-11-19 | Carbonyltris(triphenylphosphine)rhodium(I) hydride
17185-29-4
|
US $30.00 / KG | 1KG | 99% | 10000KG | Longyan Tianhua Biological Technology Co., Ltd | |
 |
2020-02-14 | Carbonyltris(triphenylphosphine)rhodium(I) hydride
17185-29-4
|
US $7.00 / KG | 1KG | 99% | 100KG | Career Henan Chemical Co |
-
- Carbonyltris(triphenylphosphine)rhodium(I) hydride
17185-29-4
- US $30.00 / KG
- 99%
- Longyan Tianhua Biological Technology Co., Ltd
-
- Carbonyltris(triphenylphosphine)rhodium(I) hydride
17185-29-4
- US $7.00 / KG
- 99%
- Career Henan Chemical Co
17185-29-4(Carbonyltris(triphenylphosphine)rhodium(I) hydride)Related Search:
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CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
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Carbonyltris(triphenylphosphine)rhodium(I) hydride, Hydridocarbonyl-tris(triphenylphosphine)-rhodium(I), Rhodium(I) tris(triphenylphosphine) carbonyl hydride
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Carbonyltris(triphen
Tris(triphenylphosphine)rhodium(I) carbonyl hydride ,98%
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Carbonyltris(triphenylphosphine)rhodium(I) Hydride
Tris(triphenylphosphine)rhodium(I) Carbonyl Hydride
Tris(triphenylphosphine)rhodium(Ⅰ) carbonyl hydride
CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRI
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Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 11.2% min
Carbonylhydridotris(triphenylphosphane)rhodium(I) “RODRIDO”
Carbonyltris(triphenylphosphine)rhodium(I) hydride ISO 9001：2015 REACH
HRh(CO)(PPh3)3 - RODRIDO
Carbonylhydridotris(triphenylphosphine)rhodium(I)[RhH(CO)(PPh3)3
HRh(CO)(PPh3)3
17185-29-4
C6H53P3RhCOH
C55H46O1P3Rh1
RhHCOPPh33
RhHCOPC6H533
C55H46OP3Rh
C54H46P3Rh
3C18H15PCOHRh
Transition Metal Compounds
Catalysts for Organic Synthesis
Rh (Rhodium) Compounds
Classes of Metal Compounds
Homogeneous Catalysts
Metal Complexes