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(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene

CAS No.
174467-31-3
Chemical Name:
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
Synonyms
]-2,2'-bis(diphenyL;(SP,S'P)-1,1'-Bis[(R)-aL; (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phe;(SP,S′P)-1,1′-Bis[(R)-α-(dimethylamino)benzyl]-2,2′-bis(diphenylphosphino)ferrocene;(2R,2'R)-1,1'-BIS[(R)-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE;(SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene;(SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene;(1R,1'R)-1,1'-bis(diphenylphosphino)-2,2'-bis[(R)-(dimethylamino) phenylmethyl]ferrocene;(R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene;(Sp,Sp)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
CBNumber:
CB23357015
Molecular Formula:
C52H48FeN2P2
Molecular Weight:
818.76
MDL Number:
MFCD04117705
MOL File:
174467-31-3.mol
Last updated:2023-04-23 13:52:06

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Properties

alpha -320.0° (c 1.0, CHCl3)
form solid
color orange-red
Stability store cold

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
WGK Germany  3

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 26-0252 (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97% 174467-31-3 100mg $96 2024-03-01 Buy
Strem Chemicals 26-0252 (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97% 174467-31-3 500mg $355 2024-03-01 Buy
Strem Chemicals 26-0252 (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97% 174467-31-3 2g $1207 2024-03-01 Buy
Strem Chemicals 26-0252 (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97% 174467-31-3 10g $4824 2024-03-01 Buy
Ambeed A1158824 (R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene 98% 174467-31-3 250mg $158 2021-12-16 Buy
Product number Packaging Price Buy
26-0252 100mg $96 Buy
26-0252 500mg $355 Buy
26-0252 2g $1207 Buy
26-0252 10g $4824 Buy
A1158824 250mg $158 Buy

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Chemical Properties,Uses,Production

Uses

Chlorotricarbonyl(4,4'-di-t-butyl-2,2'-bipyridine)rhenium(I) is used for the reduction of carbon dioxide as a catalyst.

Reactions

  1. Ligand used for the palladium-catalyzed asymmetric coupling of potassium crotyltrifluoroborate with methyl 4-bromobenzoate.
  2. Ligand used for the gold-catalyzed phenol synthesis from furyldialkyne.
  3. Ligand for asymmetric palladium-catalyzed cross-coupling of aryl triflates with [( 6 -benzylamine)Cr(CO)3]
  4. Ligand used for the palladium-catalyzed asymmetric synthesis of α-allyl-α-aryl α-amino acids by tandem alkylation/π-allylation of α-iminoesters
Reactions of 174467-31-3_1 Reactions of 174467-31-3_2 Reactions of 174467-31-3_3 Reactions of 174467-31-3_4

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Preparation Products And Raw materials

Raw materials

Preparation Products

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Suppliers

Global( 22)Suppliers
Supplier Tel Email Country ProdList Advantage
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 12551 58
Career Henan Chemica Co
+86-0371-86658258 15093356674; laboratory@coreychem.com China 30255 58
Aladdin Scientific
+1-833-552-7181 sales@aladdinsci.com United States 52927 58
Shaanxi Rock New Materials Co., Ltd. 0917-3380777 18691786767 xuya@bjrock.com China 35 58
BeiJing Hwrk Chemicals Limted 0757-86329057 18501085097 sales3.gd@hwrkchemical.com China 7583 55
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41438 60
Shaanxi Rock New Materials Co., Ltd. 917-917-8888777 18691746767 zhaoting@bjrock.com China 302 62
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
Domole Scientific 13275595566 15001012717 domole.infsci@outlook.com China 585 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 021-88888888 420970979@qq.com China 2806 58
(S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE (SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene (2R,2'R)-1,1'-BIS[(R)-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE (SP,S'P)-1,1'-Bis[(R)-aL (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phe (R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene ]-2,2'-bis(diphenyL (S,S)Fc-1,1’- Bis(diphenylphosphino)-2,2'- bis[(R,R)C-(N,Ndimethylamino)phenylmethyl]fer rocene (SP,S′P)-1,1′-Bis[(R)-α-(dimethylamino)benzyl]-2,2′-bis(diphenylphosphino)ferrocene (1R,1'R)-1,1'-bis(diphenylphosphino)-2,2'-bis[(R)-(dimethylamino) phenylmethyl]ferrocene (SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene (S,S)-(-)-2,2''-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1''-bis(diphenylphosphino)ferrocene (Sp,Sp)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene 174467-31-3