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3-Ethyl-3-oxetanemethanol

CAS No.
3047-32-3
Chemical Name:
3-Ethyl-3-oxetanemethanol
Synonyms
(3-Ethyloxetan-3-yl)Methanol;3-ethyl;3-ETHYL-3-HYDROXYMETHYLOXETANE;EOX;EOXA;EHMO;OXA (oxet;YF-FM EHMO;Monomer-EHMO;Eternacoll EHO
CBNumber:
CB2354190
Molecular Formula:
C6H12O2
Molecular Weight:
116.16
MDL Number:
MFCD00190143
MOL File:
3047-32-3.mol
MSDS File:
SDS
Last updated:2023-12-01 09:32:45

3-Ethyl-3-oxetanemethanol Properties

Boiling point 96 °C/4 mmHg (lit.)
Density 1.019 g/mL at 25 °C (lit.)
vapor pressure 3.1Pa at 25℃
refractive index n20/D 1.453(lit.)
Flash point 227 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Liquid
pka 14.58±0.10(Predicted)
color Clear colorless
Water Solubility Miscible in water.
InChI InChI=1S/C6H12O2/c1-2-6(3-7)4-8-5-6/h7H,2-5H2,1H3
InChIKey UNMJLQGKEDTEKJ-UHFFFAOYSA-N
SMILES O1CC(CC)(CO)C1
LogP 0.6 at 25℃
CAS DataBase Reference 3047-32-3(CAS DataBase Reference)
FDA UNII 622325VBYO
EPA Substance Registry System 3-Oxetanemethanol, 3-ethyl- (3047-32-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P271-P261-P280
Hazard Codes  Xn
Risk Statements  36/37/38-22
Safety Statements  37/39-26-24/25
WGK Germany  3
TSCA  Yes
HS Code  29329990
NFPA 704
1
2 0

3-Ethyl-3-oxetanemethanol price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 444197 3-Ethyl-3-oxetanemethanol 96% 3047-32-3 10g $79.3 2024-03-01 Buy
TCI Chemical E0546 3-Ethyl-3-oxetanemethanol >96.0%(GC) 3047-32-3 25g $36 2024-03-01 Buy
TCI Chemical E0546 3-Ethyl-3-oxetanemethanol >96.0%(GC) 3047-32-3 100g $106 2024-03-01 Buy
Alfa Aesar H53497 3-Ethyl-3-oxetanemethanol, 97% 3047-32-3 5g $56.4 2023-06-20 Buy
Alfa Aesar H53497 3-Ethyl-3-oxetanemethanol, 97% 3047-32-3 25g $216 2023-06-20 Buy
Product number Packaging Price Buy
444197 10g $79.3 Buy
E0546 25g $36 Buy
E0546 100g $106 Buy
H53497 5g $56.4 Buy
H53497 25g $216 Buy

3-Ethyl-3-oxetanemethanol Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

Uses

3-Ethyl-3-oxetanemethanol is used as pharmaceutical intermediate.

Application

Poly(3-ethyl-3-oxetanemethanol) could be used as a core to synthesize amphiphilic hyperbranched polyethers (AHPs), which have multiple linear poly-(ethylene glycol) arms. The AHPs owned good dispersion performance for coating pigment particles. Among AHP's products, AHP47 with 0.47 DB had good potential in coating applications. can also be used to synthesize azobenzene-focused hyperbranched poly(3- ethyl-3-oxetanemethanol)[1-2].

Synthesis Reference(s)

Journal of the American Chemical Society, 79, p. 3455, 1957 DOI: 10.1021/ja01570a038

Synthesis

3-Ethyl-3-oxetanemethanol was prepared by a modified procedure described in the literature. A mixture of trimethylopropane (1, 26.8 g, 0.2 mol), diethyl carbonate (23.6 g, 0.2 mol) and potassium hydroxide (0.1 g, 1.8 mmol) in 2 ml absolute ethyl alcohol was refluxed in oil bath at 110?C for 1 h. Then, the mixture was distilled at 110?C for 1 h. Distillation was continued until the temperature of oil bath reached 140?C. After the distillation, the vacuum was supplied for 1 h to remove the excess solvent. On heating above 185?C, the distilled materials were collected in a cold trap under vacuum and obtained >85% of the theoretical yield. 1H-NMR (CDCl3, δ, ppm): 0.80–0.83 (t, 3H, –CH2CH3), 1.61–1.66 (q, 2H, –CH2CH3), 3.62 (s, 2H, –CH2OH), 3.66 (s, 1H, –CH2OH), 4.31–4.32 and 4.38–4.39 (d, 4H, –CH2O).

References

[1] Q. Xu. “Synthesis and properties of amphiphilic hyperbranched polyethers as pigment dispersant.” IOP Conference Series: Materials Science and Engineering 216 1 (2018).
[2] Xu, Youqian et al. “Hierarchical self-assembly of protoporphyrin IX-bridged Janus particles into photoresponsive vesicles?.” RSC Advances 37 (2016): 31053–31058.

77-99-6
3047-32-3
Synthesis of 3-Ethyl-3-oxetanemethanol from Trimethylolpropane

3-Ethyl-3-oxetanemethanol Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 259)Suppliers
Supplier Tel Email Country ProdList Advantage
Qingdao Scienoc Chemical CO Ltd
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Shanghai Z&T Chemical Co., Ltd
+86-21-33561011 13818804961 Sales@ztchemical.com.cn China 402 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
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+86-371-66670886 info@dakenam.com China 14764 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21700 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Accela ChemBio Inc.
(+1)-858-699-3322 info@accelachem.com United States 19965 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845 sales@amoychem.com China 6387 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58

View Lastest Price from 3-Ethyl-3-oxetanemethanol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
 3-ETHYL-3-OXETANEMETHANOL pictures 2023-03-06 3-ETHYL-3-OXETANEMETHANOL
3047-32-3
US $5.60 / KG 1KG 99% 5000kg Hebei Guanlang Biotechnology Co,.LTD
3-ETHYL-3-OXETANEMETHANOL pictures 2023-02-25 3-ETHYL-3-OXETANEMETHANOL
3047-32-3
US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Guanlang Biotechnology Co., Ltd.
3-ETHYL-3-OXETANEMETHANOL pictures 2023-01-31 3-ETHYL-3-OXETANEMETHANOL
3047-32-3
US $0.00 / Kg/Drum 1Kg/Drum 99% 5000KG Hebei Mojin Biotechnology Co., Ltd

3-Ethyl-3-oxetanemethanol Spectrum

Cyracure UVR 6000 EOXA Eternacoll EHO OXA (oxet 3-Ethyl-3-oxetanemethanol,96% 2-Hydroxymethyl-2-ethyl-1,3-epoxypropane 3-Hydroxymethyl-3-ethyloxetane 2-HYDROXYMETHYL-2-ETHYL-1,3-EPOXYPROPANE 3-ETHYL-3-OXETANEMETHANOL 3-HYDROXYMETHYL-3-ETHYLOXETANE Trimethylolpropaneoxetane,TMPO 3-Ethyl-(hydroxymethyl)oxetane Trimethylolpropane oxetane 3-ethyl-3-oxetanemethano (3-Ethyloxetane-3-yl)methanol 3-Ethyloxacyclobutane-3-methanol 3-Ethyl-3-oxethanemethanol 3-ethyloxetane-3-methanol 3-Ethyl-3-(hydroxymethyl)oxacyclobutane 3-Ethyl-3-methyloloxetane 3-Oxetanemethanol,3-ethyl- Aron Oxetane OXT 101 3-Ethyl-3-oxetanemethanol> (3-Ethyl-3-oxetanyl)methanol 3047-32-3 3-ETHYL-3-OXETANEMETHANOL EHMO Monomer-EHMO YF-FM EHMO (3-Ethyloxetan-3-yl)Methanol 3-ETHYL-3-HYDROXYMETHYLOXETANE EOX 3-ethyl 3047-32-3 3072-32-4 Oxetanes Simple 4-Membered Ring Compounds ALCOHOL Organic Building Blocks Oxygen Compounds Building Blocks Alcohols C2 to C6 Asymmetric Synthesis Building Blocks C2 to C6 Chemical Synthesis Chiral Building Blocks Heterocyclic Building Blocks Organic Building Blocks Oxygen Compounds Oxetanes Simple 4-Membered Ring Compounds Alcohols C2 to C6 Oxygen Compounds