ChemicalBook >> CAS DataBase List >>4-Biphenylcarboxylic acid

4-Biphenylcarboxylic acid

CAS No.
92-92-2
Chemical Name:
4-Biphenylcarboxylic acid
Synonyms
BIPHENYL-4-CARBOXYLIC ACID;4-PHENYLBENZOIC ACID;4-phenylbenzoate;4-Biphenylcarboxylic;NSC 23040;4-United acid;4-diphenic acid;4-CARBOXYDIPHENYL;4-Carboxybiphenyl;PHENYLBENZOICACID
CBNumber:
CB2359014
Molecular Formula:
C13H10O2
Molecular Weight:
198.22
MDL Number:
MFCD00002553
MOL File:
92-92-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-01 19:06:17
Product description Number Pack Size Price
Biphenyl-4-carboxylic acid 95% B34729 25g $58.9
Biphenyl-4-carboxylic acid 95% B34729 100g $119
Biphenyl-4-carboxylic Acid >98.0%(GC)(T) P0961 25g $29
Biphenyl-4-carboxylic Acid >98.0%(GC)(T) P0961 100g $87
4-BIPHENYLCARBOXYLIC ACID 95% AR3938 1G $4
More product size

4-Biphenylcarboxylic acid Properties

Melting point 220-225 °C(lit.)
Boiling point 295.53°C (rough estimate)
Density 1.1184 (rough estimate)
refractive index 1.5954 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility 0.03g/l
pka 4.19±0.10(Predicted)
form Crystalline Powder
color White to beige
Water Solubility Insoluble in water.
BRN 973519
InChI 1S/C13H10O2/c14-13(15)12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9H,(H,14,15)
InChIKey NNJMFJSKMRYHSR-UHFFFAOYSA-N
SMILES OC(=O)c1ccc(cc1)-c2ccccc2
CAS DataBase Reference 92-92-2(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 36J7VPO67K
NIST Chemistry Reference [1,1'-Biphenyl]-4-carboxylic acid(92-92-2)
EPA Substance Registry System [1,1'-Biphenyl]-4-carboxylic acid (92-92-2)
UNSPSC Code 12352106
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P305+P351+P338
PPE Eyeshields, Gloves, type N95 (US)
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-20/21/22-51-36-22
Safety Statements  37/39-26-36
WGK Germany  1
RTECS  DV1925100
Hazard Note  Irritant
TSCA  TSCA listed
HS Code  29163900
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
NFPA 704
0
1 0

4-Biphenylcarboxylic acid price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B34729 Biphenyl-4-carboxylic acid 95% 92-92-2 25g $58.9 2026-04-30 Buy
Sigma-Aldrich B34729 Biphenyl-4-carboxylic acid 95% 92-92-2 100g $119 2026-04-30 Buy
TCI Chemical P0961 Biphenyl-4-carboxylic Acid >98.0%(GC)(T) 92-92-2 25g $29 2026-04-30 Buy
TCI Chemical P0961 Biphenyl-4-carboxylic Acid >98.0%(GC)(T) 92-92-2 100g $87 2026-04-30 Buy
AstaTech AR3938 4-BIPHENYLCARBOXYLIC ACID 95% 92-92-2 1G $4 2026-04-30 Buy
Product number Packaging Price Buy
B34729 25g $58.9 Buy
B34729 100g $119 Buy
P0961 25g $29 Buy
P0961 100g $87 Buy
AR3938 1G $4 Buy

4-Biphenylcarboxylic acid Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powder

Uses

Biphenyl-4-carboxylic acid is employed in the synthesis, characterization of europium, terbium complexes.

Synthesis Reference(s)

Synthetic Communications, 25, p. 3695, 1995 DOI: 10.1080/00397919508015507

Safety Profile

Experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating vapors.

Synthesis

Under argon protection, 2.75 g (13.8 mmol) of 4-bromobenzoic acid, 2 g (16.4 mmol) of phenylboronic acid, 32.71 g (27.3 mmol) of K2CO, and 0.2 g of palladium tetrakis(triphenylphosphine) were added to 40 mL of dioxyhexahydroxane solvent/water (10:1), and heated up to 75 C, and the reaction was completely monitored by TLC after 5h. The reaction solution was cooled, filtered, adjusted PH to 2-3, a large amount of white solid was generated, filtered to obtain a white solid 4-biphenylcarboxylic acid 2.30 g, yield 84.9%.

Purification Methods

Crystallise the acid from *C6H6/pet ether or aqueous EtOH. [Beilstein 9 IV 2479.]

619-58-9
98-80-6
92-92-2
Synthesis of 4-Biphenylcarboxylic acid from 4-Iodobenzoic acid and Phenylboronic acid
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View Lastest Price from 4-Biphenylcarboxylic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Biphenylcarboxylic acid pictures 2026-04-30 4-Biphenylcarboxylic acid
92-92-2
US $29.00 / g 99.58% 10g TargetMol Chemicals Inc.
4-Biphenylcarboxylic acid pictures 2026-03-20 4-Biphenylcarboxylic acid
92-92-2
US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Chuanghai Biotechnology Co., Ltd
4-Biphenylcarboxylic acid pictures 2025-12-24 4-Biphenylcarboxylic acid
92-92-2
US $0.00-0.00 / KG 1KG 99.0% 1000KG Shaanxi Dideu Medichem Co. Ltd
4-CARBOXYDIPHENYL 4-BIPHENYLCARBOXYLIC ACID LABOTEST-BB LT02084792 DIPHENYL-4-CARBOXYLIC ACID RARECHEM AL BO 0062 TIMTEC-BB SBB008141 P-PHENYLBENZOIC ACID (1,1’-biphenyl)-4-carboxylicacid [1,1’-biphenyl]-4-carboxylicacid 4-Carboxy-1,1'-biphenyl 4-Carboxybiphenyl 4-Diphenylcarboxylic acid 4-diphenylcarboxylicacid Biphenylcarboxylic acid-(4) Para phenyl benzoic acid paraphenylbenzoicacid 4-Phenylbenzoic acid/4-Biphenylcarboxylic acid 4 - carboxylic acid diphenyl - 4-Phenylbenzic acid 4-BiphenylbenzoicAcid 4-phenylbenzoic acide or [1,1-biphenyl]-4-carboxylic acid 4-Biphenylcarboxylicacid,98% 4-Biphenylcarboxylic acid 98% PHENYLBENZOICACID Biphenyl-4-carbonsure dlphenyl-4-carboxylic acid 4-phenylbenzoic acide 4-Biphenylylcarboxylic acid -Carboxy-1,1'-biphenyl phenyl(4)benzoic acid 4-Biphenylcarboxylic acid,99% Biphenyl-4-carboxylic acid,4-Phenylbenzoic acid Biphenyl-4-carboxylic acid 98% 4-United acid 4-Biphenylcarboxylic Acid:4-Phenylbenzoic Acid:4-Carboxydiphenyl 4-Biphenylcarboxylic acid, 99% 25GR NSC 23040 p-Biphenylcarboxylic acid 4-diphenic acid 4-Biphenylcarboxylic Acid, 97+% (3aR,4R,5R,6aS)-Hexahydro-2-oxo-4-[(1E)-3-oxo-1-octen-1-yl]-2H-cyclopenta[b]furan-5-yl Ester [1,1&rsquo 4-Biphenylcarboxylic acid in stock Factory Biphenyl-4-carboxylicAcid> 4-PHENYLBENZOIC ACID BIPHENYL-4-CARBOXYLIC ACID 4-Biphenylcarboxylic 4-phenylbenzoate 4 Biphenylcarboxylic acid,4Biphenylcarboxylic acid 1,1'-biphenyl]-4-carboxylic acid 4-Biphenylcarboxylicaci 92-92-2 C13H9O2 C13 to C42+ Carboxylic Acids Carbonyl Compounds Building Blocks Organic Building Blocks Exciton Chirality CD Method (for Hydroxyl Groups)