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Glycidyl phenyl ether

Glycidyl phenyl ether
Glycidyl phenyl ether structure
CAS No.
122-60-1
Chemical Name:
Glycidyl phenyl ether
Synonyms
PGE;ageflexpge;heloxywc-63;Ageflex pge;PHENYLGYCIDYLETHER;PHENYL GLYCID ETHER;PHENYLGLYCIDOLETHER;glycidolphenylether;Phenol-glycidaether;phenolglycidylether
CBNumber:
CB2429443
Molecular Formula:
C9H10O2
Formula Weight:
150.17
MOL File:
122-60-1.mol

Glycidyl phenyl ether Properties

Melting point:
3.5 °C(lit.)
Boiling point:
245-247 °C(lit.)
Density 
1.109 g/mL at 25 °C(lit.)
vapor density 
5.2 (vs air)
vapor pressure 
0.03 mm Hg ( 20 °C)
refractive index 
n20/D 1.531
Flash point:
>230 °F
storage temp. 
Store below +30°C.
solubility 
2.4g/l
form 
Liquid
color 
Clear colorless to yellow
Water Solubility 
2.4 g/L (20 ºC)
BRN 
2744
Exposure limits
TLV-TWA 6 mg/m3 (1 ppm) (ACGIH); 1 ppm (15 min) (NIOSH).
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
FQYUMYWMJTYZTK-UHFFFAOYSA-N
CAS DataBase Reference
122-60-1(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances
GLYCIDYL PHENYL ETHER
FDA 21 CFR
177.2280
EWG's Food Scores
5-6
FDA UNII
44KJQ1655I
IARC
2B (Vol. 47, 71) 1999
Proposition 65 List
Phenyl Glycidyl Ether
NIST Chemistry Reference
Oxirane, (phenoxymethyl)-(122-60-1)
EPA Substance Registry System
Phenyl glycidyl ether (122-60-1)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H332-H312+H332-H315-H317-H318-H335-H341-H350-H412
Precautionary statements  P304+P340-P405-P501a-P201-P261-P273-P280-P305+P351+P338-P308+P313
Hazard Codes  T
Risk Statements  45-20-37/38-43-52/53-68
Safety Statements  53-45-61
RIDADR  2810
WGK Germany  3
RTECS  TZ3675000
Autoignition Temperature 430 °C
TSCA  Yes
HazardClass  IRRITANT
HS Code  29109000
Toxicity LD50 orally in Rabbit: 2150 mg/kg LD50 dermal Rabbit 1500 mg/kg

Glycidyl phenyl ether price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.20553 2,3-Epoxypropyl phenyl ether for synthesis 122-60-1 250 mL $44.31 2021-03-22 Buy
Sigma-Aldrich 248487 1,2-Epoxy-3-phenoxypropane 99% 122-60-1 50g $45.1 2021-03-22 Buy
Sigma-Aldrich 248487 1,2-Epoxy-3-phenoxypropane 99% 122-60-1 250g $130 2021-03-22 Buy
Sigma-Aldrich 8.20553 2,3-Epoxypropyl phenyl ether for synthesis 122-60-1 20 kg $660.45 2021-03-22 Buy
TCI Chemical G0098 Glycidyl Phenyl Ether >99.0%(GC) 122-60-1 25g $21 2021-03-22 Buy

Glycidyl phenyl ether Chemical Properties,Uses,Production

Description

This monoglycidyl derivative is a reactive diluent in epoxy resins of the bisphenol A type. It is a component of epoxy paints, epoxy glues, and epoxy resins. Sensitization was observed in many professions, such as in construction workers, marble workers, ceramic workers, and in a shoemaker.

Chemical Properties

colourless liquid

Chemical Properties

Phenyl glycidyl ether is a colorless liquid with an unpleasant sweet odor

Uses

Chemical intermediate with high solvency for halogenated materials

Uses

Phenyl glycidyl ether (PGE) is used as anintermediate in organic syntheses.

Uses

2-Phenylglycidyl ether is an organic synthesis; chemical intermediate with high solvency for halogenated materials; reactive diluent of epoxy-resin systems; forms chemical bonds with the resin during cure and accelerates the curing process.

Production Methods

PGE is synthesized by condensation of phenol with epichlorohydrin, with subsequent dehydrochlorination with caustic to form the epoxy ring.

Synthesis Reference(s)

The Journal of Organic Chemistry, 50, p. 1784, 1985 DOI: 10.1021/jo00210a053

General Description

Colorless liquid.

Air & Water Reactions

Ethers tend to form unstable peroxides when exposed to oxygen. Ethyl, isobutyl, ethyl tert-butyl, and ethyl tert-pentyl ether are particularly hazardous in this respect. Ether peroxides can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid. Slightly soluble in water.

Reactivity Profile

Glycidyl phenyl ether, an ether, can act as a base. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

Health Hazard

PGE is a toxic compound exhibiting moderate irritant action and carcinogenicity inanimals. Application of 0.25 mg resulted insevere eye irritation in rabbits, while 500 mgcaused moderate skin irritation over a periodof 24 hours. Prolonged or repeated contactcan cause moderate irritation and skin sensitization in humans.
The symptoms of its toxicity in animalswere depression of the central nervous system and paralysis of the respiratory tract.Prolonged exposure caused changes in thekidney, liver, thymus, and testes, and lossof hair in rats. The toxicity of this compound in humans is low and the health hazardcan arise primarily from its skin-sensitizationaction.
LD50 value, oral (mice): 1400 mg/kg
DGE showed carcinogenicity in rats, causingnasal cancer.

Fire Hazard

Glycidyl phenyl ether is probably combustible.

Contact allergens

This monoglycidyl derivative is a reactive diluent in epoxy resins Bisphenol A type. It is a component of epoxy paints, epoxy glues, and epoxy resins. Sensitization has been observed in many professions, such as in construction workers, marble workers, ceramic workers, and shoemakers.

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by ingestion, skin contact, and subcutaneous routes. A severe eye and skin irritant. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. Used as a chemical intermediate. See also ETHERS

Potential Exposure

PGE is used to increase storage time and stability of halogenated compounds; as a reactive diluent in uncured epoxy resins to reduce the viscosity of the uncured system for ease in casting; adhesive, and laminating applications. NIOSH once estimated that 8000 workers are potentially exposed to PGE.

Carcinogenicity

Chronic exposure of rats to 1 or 12ppm 6 hours/day, 5 days/week for 2 years caused an increased incidence of rhinitis, squamous metaplasia, and epidermal carcinomas of the nasal cavity.4 The IARC has determined that there is sufficient evidence for the carcinogenicity of PGE in animals and that it is possibly carcinogenic to humans.

Shipping

UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, amines, and curing agents. PGE can presumably form explosive peroxides

Waste Disposal

Concentrated waste containing no peroxides-discharge liquid at a controlled rate near a pilot flame. Concentrated waste containing peroxidesperforation of a container of the waste from a safe distance followed by open burning.

Glycidyl phenyl ether Preparation Products And Raw materials

Raw materials

Preparation Products


Glycidyl phenyl ether Suppliers

Global( 172)Suppliers
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View Lastest Price from Glycidyl phenyl ether manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-07-02 1,2-Epoxy-3-phenoxypropane 99%
122-60-1
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2020-01-13 Glycidyl phenyl ether
122-60-1
US $1.00 / KG 1KG 98%-99.9% 100kg Career Henan Chemical Co

Glycidyl phenyl ether Spectrum


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