Azulene
- CAS No.
- 275-51-4
- Chemical Name:
- Azulene
- Synonyms
- AZULEN;AZULENE;Azunamic;Azulene,99%;AZULENE(RG);Azulene >AZULENE, FOR GC;Soluble azulene;275-51-4 AZULENE;AZULENE OEKANAL
- CBNumber:
- CB2440183
- Molecular Formula:
- C10H8
- Molecular Weight:
- 128.17
- MDL Number:
- MFCD00003810
- MOL File:
- 275-51-4.mol
- MSDS File:
- SDS
| Melting point | 98-100 °C(lit.) |
|---|---|
| Boiling point | 242 °C(lit.) |
| Density | 1.0530 |
| refractive index | 1.5736 (estimate) |
| Flash point | 241-243°C |
| storage temp. | Store at +2°C to +8°C. |
| solubility | Soluble in organic solvents. |
| form | Fine Crystalline Powder |
| color | Dark blue |
| Merck | 14,926 |
| BRN | 969517 |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents. |
| InChIKey | CUFNKYGDVFVPHO-UHFFFAOYSA-N |
| LogP | 3.200 |
| CAS DataBase Reference | 275-51-4(CAS DataBase Reference) |
| EWG's Food Scores | 1-3 |
| FDA UNII | 82R6M9MGLP |
| EPA Substance Registry System | Azulene (275-51-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H411 | |||||||||
| Precautionary statements | P273-P391-P501 | |||||||||
| Hazard Codes | N | |||||||||
| Risk Statements | 51/53 | |||||||||
| Safety Statements | 61 | |||||||||
| RIDADR | UN 3077 9/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | CO4570000 | |||||||||
| F | 8 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29029000 | |||||||||
| Toxicity | LD50 orl-rat: >4 g/kg DRUGAY 6,13,82 | |||||||||
| NFPA 704 |
|
Azulene price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | A97203 | Azulene 99% | 275-51-4 | 100mg | $82.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | A97203 | Azulene 99% | 275-51-4 | 1g | $225 | 2024-03-01 | Buy |
| TCI Chemical | A0634 | Azulene >99.0%(GC) | 275-51-4 | 1g | $378 | 2024-03-01 | Buy |
| TCI Chemical | A0634 | Azulene >99.0%(GC) | 275-51-4 | 5g | $1316 | 2024-03-01 | Buy |
| Alfa Aesar | L08271 | Azulene, 99% | 275-51-4 | 1g | $212 | 2024-03-01 | Buy |
Azulene Chemical Properties,Uses,Production
Chemical Properties
Azulene is a blue crystalline compound with the chemical formula C10H8 and a melting point of 99°C. It contains afive-membered ring fused to a seven-membered ring and has aromatic properties. When heated it is converted into naphthalene.
Uses
Azulene is used as an additive in ointments. It is an active ingredient in cosmetics, shaving creams and other topicals. It is used as antioxidant and in anti-inflammatory activities. It is involved in the colorimetric determination of furfural. It acts as ligand for low valent metals and forms pi complexes with both cyclopentadienyl and cylcloheptatrienyl ligands in organometallic chemistry. It is also used as precursor for the preparation of (azulene)Mo2 (CO)6 and (azulene)Fe2 (CO)5.
Uses
azulene is renowned as an anti-inflammatory, calming, and soothing agent. excellent for sensitive skin, azulene is a german chamomile derivative with a characteristic deep blue color. Careful, it stains!
Definition
ChEBI: Azulene is a mancude carbobicyclic parent consisting of a cycloheptatriene and cyclopentadiene rings. It has a role as a plant metabolite and a volatile oil component. It is an ortho-fused bicyclic arene, a member of azulenes and a mancude carbobicyclic parent.
Synthesis Reference(s)
Journal of the American Chemical Society, 75, p. 2386, 1953 DOI: 10.1021/ja01106a030
Tetrahedron Letters, 23, p. 495, 1982 DOI: 10.1016/S0040-4039(00)86871-9
Safety Profile
Poison by intraperitoneal,intravenous, and subcutaneous routes. When heated todecomposition it emits acrid smoke and irritating vapors.
Source
Azulene is a natural product and function as pigment in living organisms like plants, fungi etc. This compound was first isolated from the German Chamomile and later from yarrow, wormwood and other plants as oily liquid.
Purification Methods
Crystallise azulene from EtOH. It has UV max 270nm (log 4.72) in hexane. [Platner & Magyar Helv Chim Acta 25 581 1942, Beilstein 5 IV 1636.]
Azulene Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Mingrunda New Materials Technology Co., Ltd | +86 13482725029 13482725029 | sales@mrdchem.com | China | 1012 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Shanghai Zheyan Biotech Co., Ltd. | 18017610038 | zheyansh@163.com | CHINA | 3620 | 58 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5909 | 58 |
| BOC Sciences | +1-631-485-4226 | inquiry@bocsci.com | United States | 19553 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| Nanjing jinheyou Trading Co., Ltd. | 15705188088 | admin@jheyou.com | CHINA | 1268 | 58 |
View Lastest Price from Azulene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-11-28 | AZULENE
275-51-4
|
US $0.00-0.00 / kg | 1kg | 99% | 500000kg | Hebei Kingfiner Technology Development Co. , Ltd. | |
 |
2023-09-06 | Azulene
275-51-4
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Guanlang Biotechnology Co., Ltd. | |
 |
2019-11-08 | AZULENE
275-51-4
|
US $0.00 / g | 1g | 98%min | 20kg/month | Nanjing jinheyou Trading Co., Ltd. |