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(2R)-(-)-GLYCIDYL 4-NITROBENZOATE

(2R)-(-)-GLYCIDYL 4-NITROBENZOATE
(2R)-(-)-GLYCIDYL 4-NITROBENZOATE structure
CAS No.
106268-95-5
Chemical Name:
(2R)-(-)-GLYCIDYL 4-NITROBENZOATE
Synonyms
GLYCIDYL4-NITROBENZOATE;(R)-(-)-GLYCIDYL-4-NITROBENZOATE;(2R)-(-)-GLYCIDYL 4-NITROBENZOATE;4-nitrobenzoate,(r)-oxiranemethano;(R)-(-)-Oxirane-2-methanol 4-nitrobenzoate;(2r)-(-)-(2,3-epoxypropylester)-4-nitrobenzoate;(R)-(-)-Glycidyl 4-nitrobenzoate, (R)-(-)-Oxirane-2-methanol 4-nitrobenzoate
CBNumber:
CB2440198
Molecular Formula:
C10H9NO5
Formula Weight:
223.18
MOL File:
106268-95-5.mol

(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Properties

Melting point:
60-62 °C
storage temp. 
2-8°C
optical activity
[α]19/D 37°, c = 1.08 in chloroform
BRN 
5278590
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
RTECS  RR0511000
10-21
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

(2R)-(-)-GLYCIDYL 4-NITROBENZOATE price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 300438 (2R)-(?)-Glycidyl 4-nitrobenzoate 98% 106268-95-5 1g $73.9 2018-11-20 Buy

(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Chemical Properties,Uses,Production

Purification Methods

Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.]

(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products


(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Suppliers

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