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THALLIUM(I) BROMIDE

CAS No.
7789-40-4
Chemical Name:
THALLIUM(I) BROMIDE
Synonyms
TlBr;KRS 5;THALLOUS BROMIDE;Thalliam bromide;THALLIUM BROMIDE;Thallium(Ⅰ)bromide;THALLIUM(+1)BROMIDE;THALLIUM(I) BROMIDE;Thallium monobromide;thalliumbromide(tlbr)
CBNumber:
CB2483025
Molecular Formula:
BrTl
Molecular Weight:
284.29
MDL Number:
MFCD00011273
MOL File:
7789-40-4.mol
MSDS File:
SDS
Last updated:2023-11-21 14:02:06

THALLIUM(I) BROMIDE Properties

Melting point >300 °C(lit.)
Boiling point 815 °C
Density 7.5 g/mL at 25 °C(lit.)
form Powder
Specific Gravity 7.557
color yellow
Water Solubility Practically insoluble in water
Sensitive Hygroscopic
Merck 14,9258
Solubility Product Constant (Ksp) pKsp: 5.43
Exposure limits ACGIH: TWA 0.02 mg/m3 (Skin)
CAS DataBase Reference 7789-40-4(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII W18FF0756H
EPA Substance Registry System Thallium bromide (TlBr) (7789-40-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H300+H330-H373-H411
Precautionary statements  P260-P264-P270-P273-P304+P340+P310-P314
Hazard Codes  T+,N
Risk Statements  26/28-33-51/53
Safety Statements  13-28-45-61
RIDADR  UN 1707 6.1/PG 2
WGK Germany  3
RTECS  XG3850000
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  28275900
NFPA 704
0
3 0

THALLIUM(I) BROMIDE price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 336270 Thallium(I) bromide anhydrous, beads, 10 mesh, 99.999% trace metals basis 7789-40-4 10g $116 2023-06-20 Buy
Sigma-Aldrich 177644 Thallium(I) bromide 99.999% trace metals basis 7789-40-4 100g $392 2023-06-20 Buy
Alfa Aesar 011841 Thallium(I) bromide 99.999% (metals basis) 7789-40-4 25g $165.65 2024-03-01 Buy
Alfa Aesar 011841 Thallium(I) bromide 99.999% (metals basis) 7789-40-4 100g $590.65 2024-03-01 Buy
Strem Chemicals 93-8103 Thallium(I) bromide (99.999%-Tl) PURATREM 7789-40-4 10g $74 2024-03-01 Buy
Product number Packaging Price Buy
336270 10g $116 Buy
177644 100g $392 Buy
011841 25g $165.65 Buy
011841 100g $590.65 Buy
93-8103 10g $74 Buy

THALLIUM(I) BROMIDE Chemical Properties,Uses,Production

Crystal System

The space lattice of TlBr belongs to the cubic system, and its cesium chloride-type structure has a lattice constant of a=0.397 nm.

Description

Thallium bromide is a yellow-white solid and hygroscopic. It is similar to silver bromide. It gets darker when light shines on it. It is very toxic, like all thallium compounds. It does not dissolve in water. Thallium bromide is used in gamma ray and x-ray detectors and also in semiconductors. Prolonged period of exposure to thallium compounds has been reported to cause adverse health effects such as joint pain, severe pain in legs, loss of appetite, fatigue, and albuminuria.

Chemical Properties

THALLIUM(I) BROMIDE is yellow crystalline powder

Uses

THALLIUM(I) BROMIDE is used for mixed crystals with thallium iodide for infrared radiation transmitters used in military detection devices.

Uses

Thallium(I) bromide is used as Chemical reagents and pharmaceutical intermediates.

Production Methods

Single crystals are synthesized by the Stockbarger method after putting high grade sources into a well dried alumina crucible. The crystal is easy to process according to its nonfragile character.

Safety Profile

Poison by ingestion and subcutaneous routes. Reacts violently with Na, K. When heated to decomposition it emits very toxic fumes of Brand T1. See also BROMIDES and THALLIUM COMPOUNDS.

Purification Methods

Thallous bromide (20g) is purified by refluxing for 2-3hours with water (200mL) containing 3mL of 47% HBr. It is then washed until acid-free, heated to 300o for 2-3hours and stored in brown bottles. It solubility in H2O (w/w) is 0.034% at 0o, 0.048% at 20o, and 0.204% at 100o. [D.nges in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 870 1963]. POISONOUS.

THALLIUM(I) BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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THALLIUM(I) BROMIDE, 99,9% (METAL BASIS) THALLIUM(I)BROMIDE, 99.999% Thallium Bromide, 9.999% Thallium Bromide, 99.999% Thallium(I) bromide, ultra dry, 99.998% (metals basis) ThalliuM(I) broMide, (Metal basis) ThalliuM(I) broMide anhydrous, beads, -10 Mesh, 99.999% trace Metals basis Thallium monobromide Thallium(I) bromide 99.999% trace metals basis THALLOUS BROMIDE THALLIUM (OUS) BROMIDE Thalliam bromide THALLIUM BROMIDE THALLIUM(+1)BROMIDE THALLIUM(I) BROMIDE KRS 5 Thallium bromide (Tl2Br2) Thallium bromide (TlBr) Thallium bromide (TlBr), dimer Thallium bromide iodide (TlBrI) thalliumbromide(tlbr) TlBr Thallium(I) bromide (99.999%-Tl) PURATREM ThalliumbromidePURATREMyellowpowder Thallium(Ⅰ)bromide Thallium(I) bromide, anhydrous, beads, #10 mesh, 99.999% metals basis Thallium(I) bromide, 99.995% Thallium(I) bromide, 99+% Thallium(I)bromide,99.999%(metalsbasis) Thallium(I)bromide,ultradry,99.999%(metalsbasis) THALLOUS BROMIDE, 99.9% Thallium bromide (as thallium) thallium(i) bromide, ultra dry THALLOUS BROMIDE, 99.9%THALLOUS BROMIDE, 99.9%THALLOUS BROMIDE, 99.9%THALLOUS BROMIDE, 99.9% THALLIUM(I) BROMIDE ISO 9001:2015 REACH 7789-40-4 7789-40-0 BrTl Thallium Catalysis and Inorganic Chemistry Salts Thallium Salts ThalliumMetal and Ceramic Science metal halide Catalysis and Inorganic Chemistry Chemical Synthesis Crystal Grade Inorganics