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4-Bromobiphenyl

CAS No.
92-66-0
Chemical Name:
4-Bromobiphenyl
Synonyms
92-66-0;4-BROMO-1,1'-BIPHENYL;pbb 3;P-BROMOBIPHENYL;PBB NO 3;4-Bromodipheny;4-Brom-biphenyl;4-BROMOBIPHENYL;4-BROMODIPHENYL;P-BROMODIPHENYL
CBNumber:
CB2489092
Molecular Formula:
C12H9Br
Molecular Weight:
233.1
MDL Number:
MFCD00000100
MOL File:
92-66-0.mol
Last updated:2024-04-24 17:21:45

4-Bromobiphenyl Properties

Melting point 82-86 °C(lit.)
Boiling point 310 °C(lit.)
Density 0.9327
refractive index 1.6565 (estimate)
Flash point 143 °C
storage temp. Sealed in dry,Room Temperature
solubility dioxane: soluble1g/10 mL, clear, colorless to very faintly yellow
form Crystalline Flakes
color Almost white to slightly yellow
Water Solubility Insoluble
BRN 1907453
Stability Stable. Incompatible with oxidizing agents.
InChIKey PKJBWOWQJHHAHG-UHFFFAOYSA-N
CAS DataBase Reference 92-66-0(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII OE77OKH5BL
NIST Chemistry Reference 1,1'-Biphenyl, 4-bromo-(92-66-0)
EPA Substance Registry System 4-Bromobiphenyl (92-66-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H302-H315-H318-H335-H400
Precautionary statements  P273-P280-P301+P312+P330-P305+P351+P338+P310-P391
Hazard Codes  Xi,N,Xn
Risk Statements  36/37/38-50/53-41-37/38-22
Safety Statements  22-24/25-37/39-26-61-60-39
RIDADR  UN 3152 9/PG 2
WGK Germany  3
RTECS  DV1750100
TSCA  T
HazardClass  IRRITANT
PackingGroup 
HS Code  29036990
NFPA 704
1
2 0

4-Bromobiphenyl price More Price(29)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 281999 4-Bromobiphenyl 98% 92-66-0 10g $29.8 2024-03-01 Buy
Sigma-Aldrich 281999 4-Bromobiphenyl 98% 92-66-0 50g $143 2024-03-01 Buy
Alfa Aesar A12638 4-Bromobiphenyl, 98+% 92-66-0 10g $32.8 2023-06-20 Buy
Alfa Aesar A12638 4-Bromobiphenyl, 98+% 92-66-0 50g $124 2023-06-20 Buy
Alfa Aesar A12638 4-Bromobiphenyl, 98+% 92-66-0 250g $493 2023-06-20 Buy
Product number Packaging Price Buy
281999 10g $29.8 Buy
281999 50g $143 Buy
A12638 10g $32.8 Buy
A12638 50g $124 Buy
A12638 250g $493 Buy

4-Bromobiphenyl Chemical Properties,Uses,Production

Chemical Properties

White powder

Uses

4-Bromobiphenyl is used as a reagent in the synthesis of spirooxindole derivatives for use as AMPK activators.  It is also used as a reagent in the preparation of indenoindole derivatives as organic electroluminescent device materials.

Uses

4-Bromobiphenyl is used as halogenated hydrocarbon and Intermediates of Liquid Crystals. It is also used in used in the synthesis of 4-biphenylthiolate.

General Description

Colorless crystals. Insoluble in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Bromobiphenyl may be sensitive to light, and it can react with oxidizing materials.

Fire Hazard

Combustible.

Synthesis

Into a 250 ml reactor equipped with magnetic agitation means, a condenser, a dropping funnel, and a thermometer, the following materials were introduced:
(i) 15.4 g biphenyl (0.1 M);
(ii) 100 ml solvent
at ambient temperature Then, over 10 min, the bromine was poured therein (39.2 g/0.22 M), whereupon the mixture was agitated for a varying period of time at ambient temperature. Upon completion of the reaction, the excess bromine was consumed by sodium or potassium sulfite or bisulfite. The organic phase was washed, dried and diluted to a given volume, and analyzed by CPG to give 4-Bromobiphenyl.

Purification Methods

Crystallise the biphenyl from abolute EtOH and dry it in vacuo.[Beilstein 5 IV 1819.]

5122-94-1
92-66-0
Synthesis of 4-Bromobiphenyl from 4-Biphenylboronic acid
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View Lastest Price from 4-Bromobiphenyl manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Bromobiphenyl pictures 2024-04-24 4-Bromobiphenyl
92-66-0
US $200.00-95.00 / kg 1kg 99% 20ton Hebei Zhuanglai Chemical Trading Co.,Ltd
4-Bromobiphenyl pictures 2024-04-24 4-Bromobiphenyl
92-66-0
US $0.00 / KG 10g/Bag 99.90% 20TONS Zhejiang Free Trade Zone Violet Trade Co., Ltd.
4-Bromobiphenyl pictures 2023-12-24 4-Bromobiphenyl
92-66-0
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
  • 4-Bromobiphenyl pictures
  • 4-Bromobiphenyl
    92-66-0
  • US $200.00-95.00 / kg
  • 99%
  • Hebei Zhuanglai Chemical Trading Co.,Ltd
  • 4-Bromobiphenyl pictures
  • 4-Bromobiphenyl
    92-66-0
  • US $0.00 / KG
  • 99.90%
  • Zhejiang Free Trade Zone Violet Trade Co., Ltd.
  • 4-Bromobiphenyl pictures
  • 4-Bromobiphenyl
    92-66-0
  • US $100.00-1.00 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd
(4-bromophenyl)benzene 1,1’-(biphenyl,-bromo- 1,1’-Biphenyl,4-bromo- 1,1’-biphenyl,-bromo-(4-bromobiphenyl) 1’-Biphenyl,4-bromo-1 4-Biphenyl bromide 4-biphenylylbromide 4-Brom-biphenyl 4-BROMOBIPHENYL PESTANAL, 250 MG 4-Bromobiphenyl, 98+% 4-BroMobiphenyl, 97+% 4-BroMobiphenyl, 99% 25GR 4-BROMOBIPHENYL Zone Refined Biphenyl-4-yl bromide 4-Bromobiphenyl,99% Of polybroMinated biphenyls 4-(4'-BROMOPHENYL)BENZENE 4-BROMOBIPHENYL 4-BROMODIPHENYL BROMOBIPHENYL(4-) P-BROMODIPHENYL PBB NO 3 4-bromo-1’-biphenyl 4-bromo-bipheny Biphenyl, 4-bromo- p-biphenylylbromide p-Phenylbromobenzene p-phenylphenylbromide 4-Bromobi pheny1 P-Bromobi phenyi p-Bromo Biphenyl 4-Bromo Biphenyl The broMine biphenyl Flurbiprofen impurity Ⅳ 4-Bromobiphenyl > Difenacoum Related Compound 1 4-Bromodipheny 4-Bromobiphenyl(PBB 3) pbb 3 4-BROMO-1,1'-BIPHENYL P-BROMOBIPHENYL 92-66-0 Benzoic Anhydride 98% 4-bromo-1,1'-biphenyl 92-66-0 103-78-7 202-176-6 C12H9Br BrC6H4C6H5 ARYL HALIDE Building Blocks Aryl C9 to C12 Halogenated Hydrocarbons Organic Building Blocks blocks Bromides Liquid Crystal intermediates Biphenyl derivatives