(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03

CAS No.
72952-73-9
Chemical Name:
(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03
Synonyms
Pentadienyltrimethylsilane;5-(Trimethylsilyl)-1,3-pentadiene;trimethyl(penta-2,4-dienyl)silane;Silane, trimethyl(2E)-2,4-pentadien-1-yl-;(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03
CBNumber:
CB2502210
Molecular Formula:
C8H16Si
Molecular Weight:
140.3
MDL Number:
MFCD00054805
MOL File:
72952-73-9.mol
MSDS File:
SDS
Last updated:2023-06-26 08:28:19

(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 Properties

Boiling point 127°C
Density 0.758±0.06 g/cm3(Predicted)
Flash point 18°C
solubility sol hexane, benzene, CH2Cl2, ether, THF.

SAFETY

Risk and Safety Statements

Risk Statements  11-36/37/38
Safety Statements  16-26-36
RIDADR  1993

(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 Chemical Properties,Uses,Production

Physical properties

bp 41 °C/36 mmHg or 105 °C/760 mmHg; n20/ D 1.4570.

Uses

5-Trimethylsilyl-1,3-pentadiene is a useful pentadienylation reagent; an allyl silane; a precursor for 1-trimethylsilyldienes and intramolecular Diels–Alder substrates).

Preparation

5-Trimethylsilyl-1,3-pentadiene may be prepared in 85% yield by the reaction of pentadienyllithium with chlorotrimethylsilane in THF at room temperature.1–3 Generally the product is ≈95% (E) isomer as judged by IR (strong band at 1000 cm?1) or NMR(trans coupling constant of 15.2 Hz for proton at C-3, 5.92 ppm).

75-77-4
54962-98-0
72952-73-9
Synthesis of (2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 from Chlorotrimethylsilane and Lithium, 2,4-pentadien-1-yl-

(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 Preparation Products And Raw materials

Raw materials

Preparation Products

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72952-73-9((2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03)Related Search:

(2,4-PENTADIENYL)TRIMETHYLSILANEDISC 06/13/03 Pentadienyltrimethylsilane 5-(Trimethylsilyl)-1,3-pentadiene Silane, trimethyl(2E)-2,4-pentadien-1-yl- trimethyl(penta-2,4-dienyl)silane 72952-73-9