DIETHYLALUMINUM CYANIDE SOLUTION
- CAS No.
- 5804-85-3
- Chemical Name:
- DIETHYLALUMINUM CYANIDE SOLUTION
- Synonyms
- Einecs 227-359-8;(Cyano-C)diethyL;Cyanodiethylalane;Diethylcyanoaluminum;Cyanodiethylaluminum;(cyano-C)diethylaluminium;Aluminum, (cyano-kC)diethyl-;DIETHYLALUMINUM CYANIDE SOLUTION;Aluminum, (cyano-.kappa.C)diethyl-;Diethyl Aluminium Cyanide (1.0 M in Toluene)
- CBNumber:
- CB2502593
- Molecular Formula:
- C5H10AlN
- Molecular Weight:
- 111.121138
- MDL Number:
- MFCD00001764
- MOL File:
- 5804-85-3.mol
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS02,GHS06,GHS08,GHS09 |
|---|---|
| Signal word | Danger |
| Hazard statements | H225-H300+H330-H304-H311-H315-H336-H361d-H373-H400 |
| Precautionary statements | P210-P260-P264-P273-P280-P284 |
| Hazard Codes | F,T+,N |
| Risk Statements | 11-26/27/28-32-38-48/20-50/53-63-65-67 |
| Safety Statements | 36/37-45-60-61-62-28-16 |
| RIDADR | UN 3123 6.1/PG 1 |
| WGK Germany | 2 |
| F | 10 |
DIETHYLALUMINUM CYANIDE SOLUTION price More Price(3)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 276863 | Diethylaluminum cyanide solution 1.0M in toluene | 5804-85-3 | 100ml | $296 | 2024-03-01 | Buy |
| Sigma-Aldrich | 276863 | Diethylaluminum cyanide solution 1.0M in toluene | 5804-85-3 | 800ml | $1570 | 2024-03-01 | Buy |
| Sigma-Aldrich | 276863 | Diethylaluminum cyanide solution 1.0 M in toluene | 5804-85-3 | 4x25ml | $111.6 | 2024-03-01 | Buy |
DIETHYLALUMINUM CYANIDE SOLUTION Chemical Properties,Uses,Production
Uses
DIETHYLALUMINUM CYANIDE SOLUTION Reagents used to hydrocyanate side chain ketones directed by aryl sulfinyl groups.1
Application
Diethylaluminum Cyanide is used for hydrocyanation of α,β-unsaturated ketones;[1] preparation of α-cyanohydrins from carbonyl compounds.[2]
Preparation
Diethylaluminum Cyanide is prepared by reaction of Triethylaluminum with a slight excess of Hydrogen Cyanide below rt[3].
storage
Diethylaluminum Cyanide is highly toxic. It can be stored as 1-2 M solutions in benzene, toluene, or diisopropyl ether. Use in a fume hood.
References
1. Nagata, W.; Yoshioka, M.; Hirai, S. JACS 1972, 94, 4635.
2. Agosta, W. C.; Lowrance, W. W., Jr. JOC 1970, 35, 3851.
3. Nagata, W.; Yoshioka, M. OR 1977, 25, 255.
DIETHYLALUMINUM CYANIDE SOLUTION Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49732 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-87569266 15319487004 | 1015@dideu.com | China | 3939 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615531151365 | mina@chuanghaibio.com | China | 18138 | 58 |
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43340 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +86-18621343501; +undefined18621343501 | product@acmec-e.com | China | 33338 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| Shanghai Likang New Materials Co., Limited | +86-16631818819 +86-17736933208 | 3684455296@qq.com | China | 9300 | 58 |
| SHANGHAI KEAN TECHNOLOGY CO., LTD. | +8613817748580 | cooperation@kean-chem.com | China | 40066 | 58 |
| Beijing HwrkChemical Technology Co., Ltd | 010-89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9371 | 55 |