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NICKEL BROMATE

Description References
NICKEL BROMATE
NICKEL BROMATE structure
CAS No.
13462-88-9
Chemical Name:
NICKEL BROMATE
Synonyms
NiBr2;Nickel-bromid;NICKEL BROMATE;Nickel dibromide;Nickel(II)-bromid;Nickel(Ⅱ) bromide;Dibromonickel(II);Nickeleus bromide;nickelbromide(nibr2);Nickel(II) dibromide
CBNumber:
CB2669337
Molecular Formula:
Br2Ni
Formula Weight:
218.5
MOL File:
13462-88-9.mol

NICKEL BROMATE Properties

Melting point:
963 °C(lit.)
Density 
5.098 g/mL at 25 °C(lit.)
solubility 
H2O: slightly soluble(lit.)
form 
powder
color 
Brown
Specific Gravity
5.098
Water Solubility 
Soluble in water, alcohol and ether.
Sensitive 
Hygroscopic
Merck 
14,6502
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
IPLJNQFXJUCRNH-UHFFFAOYSA-L
CAS DataBase Reference
13462-88-9(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,N,Xi
Risk Statements  45-22-43-50/53-68-48/23-42/43-61-49
Safety Statements  53-36/37-45-60-61
RIDADR  UN 3077 9/PG 3
WGK Germany  3
TSCA  Yes
HazardClass  6.1(b)
PackingGroup  III
HS Code  28275900
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Sensitisation, respiratory Category 1 Danger P261, P285, P304+P341, P342+P311,P501
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger
H360 May damage fertility or the unborn child Reproductive toxicity Category 1A, 1B Danger
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P201 Obtain special instructions before use.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER or doctor/physician.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P308+P313 IF exposed or concerned: Get medical advice/attention.

NICKEL BROMATE price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 217891 Nickel(II) bromide 98% 13462-88-9 10g $29.7 2018-11-13 Buy
Sigma-Aldrich 217891 Nickel(II) bromide 98% 13462-88-9 50g $98.9 2018-11-13 Buy
Alfa Aesar 053115 Nickel(II) bromide, anhydrous, 99% 13462-88-9 250g $356 2018-11-16 Buy
Alfa Aesar 053115 Nickel(II) bromide, anhydrous, 99% 13462-88-9 50g $80.4 2018-11-16 Buy
Strem Chemicals 28-1140 Nickel(II) bromide, anhydrous (99+%-Ni) 13462-88-9 50g $95 2018-11-13 Buy

NICKEL BROMATE Chemical Properties,Uses,Production

Description

Nickel bromide (chemical formula: NiBr2) is the nickel salt of hydrobromic acid. It is a weak reducing agent made by the reaction of nickel, nickel oxide, nickel carbonate or nickel hydroxide with hydrobromic acid, or the reaction between nickel and bromine. Nickel bromide has many kinds of applications. It is mostly an electron acceptor, being capable of catalyze organic structure such as carbonamides, and convert aryl bromides into aryl phosphines. It can also be used as a catalyst in cross-coupling reactions. It is also applied for bonding to other ligands. For example, graphene supported NrBr2 is used in a condensation reaction consisting of aromatic aldehyde, acetoacetate and urea for manufacturing 3, 4- dihydropyrimidiones.

References

https://en.wikipedia.org/wiki/Nickel(II)_bromide

Chemical Properties

Brownish powder

General Description

Yellowish-green odorless solid. Sinks in and mixes with water.

Air & Water Reactions

Deliquescent. Soluble in water.

Reactivity Profile

NICKEL BROMATE is a yellow, crystalline material, mildly toxic, carcinogenic. On contact with strong acids or acid fumes NICKEL BROMATE produces highly toxic and corrosive hydrogen bromide gas. When heated to decomposition NICKEL BROMATE emits toxic bromide fumes. [M. K.]

Health Hazard

Inhalation of dust causes irritation of nose and throat. Ingestion causes vomiting; if large amount is swallowed and not thrown up, it can cause drowsiness and other symptoms of bromide poisoning. Dust irritates eyes and may cause dermatitis in contact with skin.

Fire Hazard

Special Hazards of Combustion Products: Irritating hydrogen bromide vapors may form in fire.

Purification Methods

Crystallise it from dilute HBr (0.5mL/g) by partial evaporation in a desiccator. The anhydrous salt is yellow, but the trihydrate is green.

NICKEL BROMATE Preparation Products And Raw materials

Raw materials

Preparation Products


NICKEL BROMATE Suppliers

Global( 94)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32452 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 25796 58
Hubei xin bonus chemical co. LTD
13657299721
zhangyuzhu@xhlchem.com CHINA 17424 58
Shanghai Macklin Biochemical Co.,Ltd. 15221275939
021-51821727 shenlinxing@macklin.cn China 15724 55
Suzhou Xiaoli Material Technology Co., Ltd. 0512-87815088/18015562287
0512-69233866 xmwang@xiaolitech.com China 10 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
3B Pharmachem (Wuhan) International Co.,Ltd. 86-21-50328103 * 801、802、803、804 Mobile:18930552037
86-21-50328109 3bsc@sina.com China 15882 69
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30168 84
BeiJing Hwrk Chemicals Limted 4006990298;010-57411839;0757-86311057;021-51691807
010-87653215;0757-86311057;021-55236763 sales@hwrkchemical.com China 14686 55
Beijing Ouhe Technology Co., Ltd +86-10-4006331231;+86-10-51280831;+86-10-82967028
+86-10-82967029 sales@ouhechem.com China 12499 60

View Lastest Price from NICKEL BROMATE manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-07-10 NICKEL BROMATE
13462-88-9
US $1.00 / KG 1KG 99% 25kg career henan chemical co

NICKEL BROMATE Spectrum


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