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Ametryn

CAS No.
834-12-8
Chemical Name:
Ametryn
Synonyms
EVIK;a1093;AMESIP;G34162;A 1093;Amigan;X-SIPAX;EVIK(R);Cemerin;gestene
CBNumber:
CB2684343
Molecular Formula:
C9H17N5S
Molecular Weight:
227.33
MDL Number:
MFCD00055398
MOL File:
834-12-8.mol
MSDS File:
SDS
Last updated:2023-05-18 11:31:13

Ametryn Properties

Melting point 84-85°C
Boiling point 310.44°C (rough estimate)
Density 1.1232 (rough estimate)
vapor pressure 0Pa at 20℃
refractive index 1.5500 (estimate)
Flash point 11 °C
storage temp. Keep in dark place,Sealed in dry,2-8°C
solubility Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form Crystalline
pka 3.71±0.41(Predicted)
Water Solubility 209mg/L(25 ºC)
Merck 13,391
BRN 613099
InChIKey RQVYBGPQFYCBGX-UHFFFAOYSA-N
LogP 3 at 20℃
CAS DataBase Reference 834-12-8(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 1SPQ95183Y
Proposition 65 List Bromoxynil
NIST Chemistry Reference 1,3,5-Triazine-2,4-diamine, N-ethyl-N'-(1-methylethyl)-6-(methylthio)-(834-12-8)
EPA Substance Registry System Ametryn (834-12-8)
Pesticides Freedom of Information Act (FOIA) Bromoxynil

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H410
Precautionary statements  P273-P301+P312+P330
Hazard Codes  Xn;N,N,Xn,T,F
Risk Statements  22-50/53-39/23/24/25-23/24/25-11
Safety Statements  2-36-60-61-45-16-7
RIDADR  UN 1230 3/PG 2
WGK Germany  3
RTECS  XY9100000
HS Code  29336990
Toxicity LD50 in adult male, female rats (mg/kg): 508, 590 orally (Gaines, Linder)

Ametryn price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 45321 Ametryn PESTANAL 834-12-8 250mg $63.7 2024-03-01 Buy
TRC A576400 Ametryn 834-12-8 5g $460 2021-12-16 Buy
AK Scientific S263 Ametryn 834-12-8 100mg $23 2021-12-16 Buy
American Custom Chemicals Corporation PST0000055 AMETRYN 95.00% 834-12-8 1G $244.65 2021-12-16 Buy
AHH MT-47027 Ametryn 98% 834-12-8 500g $340 2021-12-16 Buy
Product number Packaging Price Buy
45321 250mg $63.7 Buy
A576400 5g $460 Buy
S263 100mg $23 Buy
PST0000055 1G $244.65 Buy
MT-47027 500g $340 Buy

Ametryn Chemical Properties,Uses,Production

Chemical Properties

White, crystalline powder. Slightly soluble in water; soluble in organic solvents.

Chemical Properties

Ametryn is a colorless powder

Uses

Herbicide used to control broad-leaved and grass weeds in corn, sugarcane, certain citrus subtropical fruits (bananas, pineapple) and in noncropland. Preharvest and postharvest desiccant used in potatoes to control both crop and weeds

Uses

Pre-emergence and post-emergence herbicides.

Uses

Ametryn is a methylthiotriazine based herbicide which inhibits photosynthesis and other enzymatic processes. Ametryn is used to control broadleaf weeds and annual grasses in pineapple, sugarcane and b ananas.

Production Methods

Ametryn is a colorless crystal synthesized by reacting atrazine with methyl mercaptan in the presence of an equivalent of NaOH or by reacting 2-mercapto-4-ethylamino-6-isopropylamino- 1,3,5-triazine with a methylating agent in the presence of NaOH. It is stable in slightly acidic or alkaline media, but is hydrolyzed to the inactive 6-hydroxy derivative in strong acidic or basic media.

Definition

ChEBI: A methylthio-1,3,5-triazine that is 2-(methylsulfanyl)-1,3,5-triazine substituted by an ethylamino and an isopropylamino group at positions 4 and 6 respectively.

General Description

Crystals. Melting point 190-192°F (88-89°C). Used as a herbicide.

Reactivity Profile

An amine, organosulfide. Organosulfides are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Hazard

Toxic by ingestion.

Health Hazard

Moderately toxic by ingestion; human toxic-ity data not available; a mild irritant to skinand eye.
LD50 oral (rat): 508 mg/kg
LD50 oral (mouse): 965 mg/kg
LD50 skin (rabbit): >5000 mg/kg.

Flammability and Explosibility

Non flammable

Agricultural Uses

Herbicide: Ametryn is a herbicide which inhibits photosynthesis and other enzymatic processes. It is used to control broadleaf weeds and annual grasses in pineapple, sugarcane and bananas. Uses are being supported in the U.S. only for the following agricultural crops: field corn, popcorn, sugarcane, and pineapple (EPA, 2005). Used in premixes with atrazine, diuron, simazine, and terbutryn. Not approved for use in the EU.

Trade name

AMESIP®; AMERTREX®; AMETREX; AMETRON SC®; AMETRYNE TECHNICAL®; AMIGAN®; AMULEX; CRISATRINE®; CRISATRINA®; DORUPLANT®; EVIK®; G-34162®; GESAPAX®; HERBIPAK®; KRISMAT®; OXON PRIMATOL Z 80®; SANCOPAX®; TRINATOX-D®

Potential Exposure

Ametryn, a triazine and an organosulfide, amine compound A potential danger to those involved in the manufacture, formulation and application of this selective herbicide.

Carcinogenicity

No carcinogenic response was observed at the highest dose tested in lifetime studies, 2000 ppm, for both rats and mice.

Environmental Fate

Biological. Cook and Hütter (1982) reported that bacterial cultures were capable of degrading ametryne forming the corresponding hydroxy derivative (hydroxyametryne)
Soil. Although no products were reported, the half-life in soil is 70–120 days (Worthing and Hance, 1991)
Groundwater. According to the U.S. EPA (1986) ametryn has a high potential to leach to groundwater
Chemical/Physical. Hydrolyzes to the 6-hydroxy analog, especially in the presence of
Photolytic. The dye-sensitized photodecomposition of ametryn was studied in aqueous, aerated solutions (Rejto et al., 1983). When an aqueous ametryn solution was irradiated in sunlight for several hours, 2-(methylthio)-4-(isopropylamino)-6-amino-

Shipping

UN2763 Triazine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials

Incompatibilities

Triazines are incompatible with nitric acid. Amines are chemical bases, they neutralize acids to form salts plus water with an exothermic reaction. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents such as hydrides, nitrides, alkali metals, and sulfides.

Waste Disposal

In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

Ametryn Preparation Products And Raw materials

Global( 192)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49390 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17367 58
TargetMol Chemicals Inc.
+1-781-999-5354 +1-00000000000 marketing@targetmol.com United States 19892 58
Longyan Tianhua Biological Technology Co., Ltd
0086 18039857276 18039857276 CHINA 2783 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
Shanghai Biolang Biotechnology Co., Ltd.
+86-15970428662 +86-13397199602 Niky@biolang.cn China 518 58

View Lastest Price from Ametryn manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ametryn pictures 2022-02-23 Ametryn
834-12-8
US $9.90-7.70 / g 10g 99.99%HPLC.USP42——Powder、Oil、Pills、Capsules、Tablets,Customiz 1000kgs Shanghai Biolang Biotechnology Co., Ltd.
Ametryn pictures 2021-07-02 Ametryn
834-12-8
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
Ametryn pictures 2020-11-16 Ametryn
834-12-8
US $9.00 / Kg/Bag 1Kg/Bag 99% 20 Tons Longyan Tianhua Biological Technology Co., Ltd
  • Ametryn pictures
  • Ametryn
    834-12-8
  • US $9.90-7.70 / g
  • 99.99%HPLC.USP42——Powder、Oil、Pills、Capsules、Tablets,Customiz
  • Shanghai Biolang Biotechnology Co., Ltd.
  • Ametryn pictures
  • Ametryn
    834-12-8
  • US $15.00-10.00 / KG
  • 99%+ HPLC
  • Zhuozhou Wenxi import and Export Co., Ltd
  • Ametryn pictures
  • Ametryn
    834-12-8
  • US $9.00 / Kg/Bag
  • 99%
  • Longyan Tianhua Biological Technology Co., Ltd
n-ethyl-n’-isopropyl-6-methylthio-1,3,5-triazine-2,4-diyldiamine N-Ethyl-N'-isopropyl-6-methylthio-1,3,5-triazine-2,4-diamine N-ethyl-N'-(1-methylethyl)-6-methylthio-1,3,5-triazine-2,4-diamine ametryn (ISO) 2-ethylamino-4-isopropylamino-6-methylthio-1,3,5-triazine Ametryn W.P. EVIK(R) N'-ETHYL-6-METHYLSULFANYL-N-PROPAN-2-YL-1,3,5-TRIAZINE-2,4-DIAMINE X-SIPAX 1,3,5-Triazine,2-(ethylamino)-4-(isopropylamino)-6-(methylthio) 2-(Methylmercapto)-4-(ethylamino)-6-(isopropylamino)-s-triazine 2-(Methylmercapto)-4-(isopropylamino)-6-(ethylamino)-s-triazine 2-(Methylthio)-4-(ethylamino)-6-(isopropylamino)-s-triazine 2-ethylamino-4-isopropylamino-6-methylthio-s-triazin caswellnumber:431 Cemerin Crisatrine Doruplant epapesticidecode080801 Evik 80W gardopax gestene Ametryn suspension [4-(ethylamino)-6-(methylthio)-s-triazin-2-yl]-isopropyl-amine 4-N-ethyl-6-methylsulfanyl-2-N-propan-2-yl-1,3,5-triazine-2,4-diamine N4-ethyl-6-methylsulfanyl-N2-propan-2-yl-1,3,5-triazine-2,4-diamine Ametryne 500mg [834-12-8] N2-ethyl-N4-isopropyl-6-(Methylthio)-1,3,5-triazine-2,4-diaMine Ametryn Standard 2-methylmercapto-4-ethylamino-6-isopropylamino-s-triazine 2-methylmercapto-4-isopropylamino-6-ethylamino-s-triazine 2-methylthio-4-ethylamino-6-isopropylamino-s-triazine 5-triazine-2,4-diamine,n-ethyl-n’-(1-methylethyl)-6-(methylthio)-3 2-ETHYLAMINO-4-ISOPROPYLAMINO-6-METHYLMERCAPTO-S-TRIAZINE 2-ETHYLAMINO-4-ISOPROPYLAMINO-6-METHYLTHIO-1,3,5-TRIAZINE 2-ETHYLAMINO-4-ISOPROPYLAMINO-6-METHYLTHIO-S-TRIAZINE ALMULEX AMETREX AMETRYN AMETRYNE AMESIP MEBATRYNE GESAPAX GESAPAX(R) G34162 EVIK A 1093 a1093 Amephyt Ametrine Ametryn-terbutryn Amigan n-ethyl-n-isopropyl-6-methylthio-1,3,5-triazine-2,4-diamine primatolz80 s-Triazine, 2-(ethylamino)-4-(isopropylamino)-6-(methylthio)- s-triazine,2-(ethylamino)-4-(isopropylamino)-6-(methylthio)- topazol Trinatox D trinatoxd