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(R)-MONOPHOS

(R)-MONOPHOS Structure
(R)-MONOPHOS structure
CAS No.
157488-65-8
Chemical Name:
(R)-MONOPHOS
Synonyms
(R)-MONOPHOS;(S)-MONOPHOS;97% (R)-MONOPHOS;3,4-a']dinaphthalen;3,4-a']dinaphthalen-4-yl)piperidine;3,4-a']dinaphthalen-4-yl)Morpholine;3,4-a']dinaphthalen-4-yl)dipropylaMine;3,4-a']dinaphthalen-4-yl)dimethylamine;(R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine, R-MonoPhos
CBNumber:
CB2704984
Molecular Formula:
C22H18NO2P
Molecular Weight:
359.36
MDL Number:
MFCD03426988
MOL File:
157488-65-8.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:34
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(R)-MONOPHOS Properties

Melting point 190 °C (dec.)
Boiling point 548.7±33.0 °C(Predicted)
alpha -583° (c 0.06, CHCl3)
storage temp. Inert atmosphere,Room Temperature
pka 1.22±0.20(Predicted)
form crystal
color white
Sensitive air sensitive
InChIKey QCHAVHXSBZARBO-UHFFFAOYSA-N

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280-P305+P351+P338-P304+P340-P405-P501A
Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3
TSCA  No
HS Code  2934.99.4400

(R)-MONOPHOS price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 668206 (R)-(?)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)dimethylamine 97% 157488-65-8 1g $55.4 2023-06-20 Buy
TCI Chemical D4992 (R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine >98.0%(HPLC)(N) 157488-65-8 1g $56 2024-03-01 Buy
TCI Chemical D4992 (R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine >98.0%(HPLC)(N) 157488-65-8 5g $180 2024-03-01 Buy
Strem Chemicals 15-1232 (R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (R)-MONOPHOS 157488-65-8 250mg $29 2024-03-01 Buy
Strem Chemicals 15-1232 (R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (R)-MONOPHOS 157488-65-8 1g $85 2024-03-01 Buy
Product number Packaging Price Buy
668206 1g $55.4 Buy
D4992 1g $56 Buy
D4992 5g $180 Buy
15-1232 250mg $29 Buy
15-1232 1g $85 Buy

(R)-MONOPHOS Chemical Properties,Uses,Production

Reaction

  1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids.
  2. Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position.
  3. Ligand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction.
  4. Ligand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes.
  5. Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition.
Reactions of 157488-65-8

Uses

DSM MonoPhos Family of Highly Efficient Privileged Ligands

(R)-MONOPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-MONOPHOS Suppliers

Global( 116)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15928 58
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32480 60
AB PharmaTech,LLC 		323-480-4688 United States 989 55
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Changzhou Ansciep Chemical Co., Ltd. 		+86 519 86305871 sales@ansciepchem.com CHINA 4242 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc. 		8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 47465 58
Richest Group Ltd 		18017061086 oled@richest-group.com CHINA 5601 58
Antai Fine Chemical Technology Co.,Limited 		18503026267 info@antaichem.com CHINA 9641 58
Supplier Advantage
Shanghai Daken Advanced Materials Co.,Ltd 		58
ATK CHEMICAL COMPANY LIMITED 		60
AB PharmaTech,LLC 		55
career henan chemical co 		58
Changzhou Ansciep Chemical Co., Ltd. 		58
Chongqing Chemdad Co., Ltd 		58
Alchem Pharmtech,Inc. 		58
CONIER CHEM AND PHARMA LIMITED 		58
Richest Group Ltd 		58
Antai Fine Chemical Technology Co.,Limited 		58

View Lastest Price from (R)-MONOPHOS manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(r)-(-)-(3,5-dioxa-4-phosphacyclohepta(2,1-a pictures 2022-10-01 (r)-(-)-(3,5-dioxa-4-phosphacyclohepta(2,1-a
157488-65-8
 US $0.00-0.00 / KG 1KG 98% 1ton Henan Aochuang Chemical Co.,Ltd.
(R)-()-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)dimethylamine pictures 2021-07-02 (R)-()-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)dimethylamine
157488-65-8
 US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
(R)-MONOPHOS pictures 2019-07-31 (R)-MONOPHOS
157488-65-8
 US $1.00 / KG 1KG 98% 10KG Career Henan Chemical Co
  • (R)-MONOPHOS pictures
  • (R)-MONOPHOS
    157488-65-8
  • US $1.00 / KG
  • 98%
  • Career Henan Chemical Co

(R)-MONOPHOS Spectrum

(R)-MONOPHOS(157488-65-8)1HNMR(R)-MONOPHOS(157488-65-8)31PNMR

157488-65-8((R)-MONOPHOS)Related Search:

3,4-a']dinaphthalen-4-yl)dimethylamine (R)-MONOPHOS (S)-(+)-(2,6-DIMETHYL-3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)DIMETHYLAMINE (11BR)-2,6-BIS(DIPHENYLPHOSPHINO)-N,N-DIMETHYLDINAPHTHO(2,1-D:1',2'-F)-1,3,2-DIOXAPHOSPHEPIN-4-AMINE, KANATA PURITY (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (R)-MONOPHOS
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

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(R)-(-)-[4-N,N-Dimethylamino]dinaphtho[2.1-d:1'.2'-f][1.3.2]dioxaphosphepine(R)-monophos] (R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a 3,4-a']dinaphthalen-4-yl)dimethylamine,min.97%(R)-MONOPHOS (R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (R)-MONOPHOS 3,4-a']dinaphthalen-4-yl)dimethylamine (R)-()-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a′]di-naphthalen-4-yl)dimethylamine,(R)-Monophos 3,4-a']dinaphthalen 3,4-a']dinaphthalen-4-yl)[(1S)-1-phenylethyl]-aMine 3,4-a']dinaphthalen-4-yl)dipropylaMine 3,4-a']dinaphthalen-4-yl)Morpholine 3,4-a']dinaphthalen-4-yl)piperidine R-8,9,10,11,12,13,14,15,Octahydro-3,5-dioxa-4-phosphacyclohepta[2,1-a (R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)diMethylaMine 97% (R)-N,N-DiMethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine 3,4-a']dinaphthalen-4-yl)dimethylamine,97% (R)-MONOPHOS (11bR)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 97% (R)-MONOPHOS -N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine (11bR)-N,N-Dimethyl-dinaphtho[2,1-d:1',2'-f][1,3,2] dioxaphosphepin-4-amine,99%e.e. (R)-(-)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DI-NAPHTHALEN-4-YL)DIMETHYLAMINE (R)-(-)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE (S)-(+)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DI-NAPHTHALEN-4-YL)DIMETHYLAMINE (R)-MONOPHOS (S)-MONOPHOS 3,4-a']dinaphthalen-4-yl)dimethylamine, R-MonoPhos (11bR)-N,N-Dimethyl-dinaphtho[2,1-9d8:1%',21'-5f]7[418,38,-26]5d-i8ox Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-dimethyl-, (11bR)- (R)-(-)-[4-N,N-Dimethylamino]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinapht... (R)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 157488-65-8 422509-53-5 Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis Privileged Ligands DSM MonoPhos Phosphoramidites Chiral Phosphine CPN SF160006