ChemicalBook >> CAS DataBase List >>N-Hydroxyurethane

N-Hydroxyurethane

CAS No.
589-41-3
Chemical Name:
N-Hydroxyurethane
Synonyms
NHU;SQ 16819;NSC-83629;NSC-71045;85.0%(GC&HYDROXYURETHAN;Hydroxyurethane;N-HYDROXYURETHAN;N-HYDROXYURETHANE;N-Hydroxyurethane>
CBNumber:
CB2725765
Molecular Formula:
C3H7NO3
Molecular Weight:
105.09
MDL Number:
MFCD00002108
MOL File:
589-41-3.mol
Last updated:2023-06-08 17:06:36

N-Hydroxyurethane Properties

Boiling point 113-116 °C3 mm Hg(lit.)
Density 1.3895 (rough estimate)
refractive index n20/D 1.445(lit.)
Flash point >230 °F
storage temp. -20°C
solubility Diethyl Ether, Dimethyl Sulfoxide, Water
form Oil
pka 9.30±0.23(Predicted)
color Yellow
BRN 1747529
CAS DataBase Reference 589-41-3(CAS DataBase Reference)
FDA UNII QWI3C4ASI7
NIST Chemistry Reference Carbamic acid, hydroxy-, ethyl ester(589-41-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332
Precautionary statements  P501-P261-P270-P271-P264-P280-P362+P364-P301+P312+P330-P302+P352+P312-P304+P340+P312
Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  2
RTECS  FB1750000
HS Code  2928009090
Toxicity LD50 intraperitoneal in rat: 800mg/kg
NFPA 704
1
0 1

N-Hydroxyurethane price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 119474 N-Hydroxyurethane 589-41-3 5g $246 2023-06-20 Buy
Sigma-Aldrich 119474 N-Hydroxyurethane 589-41-3 25g $531 2022-05-15 Buy
TCI Chemical H0618 N-Hydroxyurethane >85.0%(GC)(N) 589-41-3 1g $31 2024-03-01 Buy
TCI Chemical H0618 N-Hydroxyurethane >85.0%(GC)(N) 589-41-3 5g $109 2024-03-01 Buy
TRC H991050 Hydroxyurethane 589-41-3 25g $395 2021-12-16 Buy
Product number Packaging Price Buy
119474 5g $246 Buy
119474 25g $531 Buy
H0618 1g $31 Buy
H0618 5g $109 Buy
H991050 25g $395 Buy

N-Hydroxyurethane Chemical Properties,Uses,Production

Chemical Properties

Yellow Oil

Uses

Reactant involved in:

  • Synthesis of molecules used for intermolecular Sharpless aminohydroxylation reactions
  • Intermolecular ortho-C-H amidation of anilides
  • Cinchona alkaloid-catalyzed asymmetric cycloaddition
  • Allylic arylation

Uses

Hydroxyurethane is a metabolite of carcinogenic Urethane (U825300).

Biochem/physiol Actions

N-Hydroxyurethane causes the chromosomal fragmentation at millimolar concentrations and cell toxicity in cultured normal human leukocytes.

N-Hydroxyurethane Preparation Products And Raw materials

Raw materials

Preparation Products

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n-hydroxyethylcarbamate NSC-71045 NSC-83629 SQ 16819 N-HYDROXYURETHAN N-HYDROXYURETHANE N-HYDROXYURETHAN 94+% Ethyl hydroxycarbamate 97% HYDROXYURETHAN N-hydroxycarbamic acid ethyl ester N-Hydroxycarbamic acid ethyl ETHYL HYDROXYCARBAMATE ETHYL N-HYDROXYCARBAMATE HYDROXYCARBAMIC ACID ETHYL ESTER Ethylester kyseliny N-hydroxykarbaminove Ethyl Hydroxycarbamate Hydroxycarbamic Acid Ethyl Ester N-Hydroxyurethane ethylesterkyselinyn-hydroxykarbaminove hydroxy-carbamicaciethylester Hydroxyurethane N-Carbethoxyhydroxylamine NHU N-Hydroxy ethyl carbamate N-Hydroxyurethane> 85.0%(GC& Carbamic acid, N-hydroxy-, ethyl ester 589-41-3 HONHCOOCH2CH3 Hydroxylamines Hydroxylamines (N-Substituted) Organic Building Blocks Nitrogen Compounds Protected Amines Building Blocks Amines Mutagenesis Research Chemicals Aliphatics Hydroxylamines Hydroxylamines (N-Substituted)