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1,1'-Bis(diphenylphosphino)ferrocene

Reaction
1,1'-Bis(diphenylphosphino)ferrocene
1,1'-Bis(diphenylphosphino)ferrocene
CAS No.
12150-46-8
Chemical Name:
1,1'-Bis(diphenylphosphino)ferrocene
Synonyms
DPPF;98% DPPF;12150-46-8;1,1'-Bis(diphenylpho;Zirconium ionophore I ;Bis(diphenylphosphino)ferrocene;Cyclopentadienyldiphenylphosphine;1,1-(twophenylphosphine)Er Maotie;1'-Bis(diphenylphosphino)ferrocene;1,1'-bis(diphenyphosphino)ferrocene
CBNumber:
CB2746748
Molecular Formula:
C34H28FeP2 10*
Formula Weight:
554.38
MOL File:
12150-46-8.mol

1,1'-Bis(diphenylphosphino)ferrocene Properties

Melting point:
181-182 °C (dec.)(lit.)
storage temp. 
2-8°C
form 
crystal
color 
yellow to orange
Water Solubility 
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
Sensitive 
Air Sensitive
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
12150-46-8(CAS DataBase Reference)
NIST Chemistry Reference
1,1'-Bis(diphenylphosphino)ferrocene(12150-46-8)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,Xi,Xn
Risk Statements  25-36/37/38-20/21/22
Safety Statements  22-24/25-45-28A-36-26-36/37/39
RIDADR  3467
WGK Germany  3
10-23
TSCA  No
HazardClass  IRRITANT
HS Code  29319090
Symbol(GHS):
Signal word:
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

1,1'-Bis(diphenylphosphino)ferrocene price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 177261 1,1′-Bis(diphenylphosphino)ferrocene 97% 12150-46-8 1g $29.2 2018-11-13 Buy
Sigma-Aldrich 177261 1,1′-Bis(diphenylphosphino)ferrocene 97% 12150-46-8 10g $188 2018-11-13 Buy
TCI Chemical B2027 1,1'-Bis(diphenylphosphino)ferrocene >96.0%(T) 12150-46-8 1g $10 2018-11-22 Buy
TCI Chemical B2027 1,1'-Bis(diphenylphosphino)ferrocene >96.0%(T) 12150-46-8 5g $12 2018-11-22 Buy
Alfa Aesar B21166 1,1'-Bis(diphenylphosphino)ferrocene, 97% 12150-46-8 1g $34.4 2018-11-13 Buy

1,1'-Bis(diphenylphosphino)ferrocene Chemical Properties,Uses,Production

Reaction

  1. Ligand for Pd-catalyzed cross-coupling.
  2. Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures.
  3. Ligand for Ni-catalyzed amination of aryl chlorides.
  4. Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles.
  5. Ligand for Ni-catalyzed Suzuki reactions.
  6. Ni-catalyzed hydroamination of 1,3-dienes.
  7. Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene.
  8. Pd-catalyzed γ-arylation of β,γ-unsaturated ketones.
  9. Ligand for Ru-catalyzed reduction of nitriles to primary amines.
  10. Ligand for Rh-catalyzed alkyne head-to-tail dimerization.
  11. Ligand for Rh-catalyzed cross-coupling
  12. Ligand for Rh-catalyzed olefin isomerization
  13. Ligand for Ni or Rh-catalyzed borylation
  14. Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes.


Chemical Properties

deep yellow crystalline powder

Uses

suzuki reaction

Uses

Commonly used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which i s a popular reagent for palladium-catalyzed coupling reactions.

Purification Methods

Wash it with distilled H2O and dry it in a vacuum. Dissolve it in ca 5 parts of hot dioxane and cool to give orange crystals m 181-183o. Recrystallisation from *C6H6/heptane (1:2) gives a product with m 183-184o. [Bishop et al. J Organomet Chem 27 241 1971.]

1,1'-Bis(diphenylphosphino)ferrocene Preparation Products And Raw materials

Raw materials

Preparation Products


1,1'-Bis(diphenylphosphino)ferrocene Suppliers

Global( 333)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22058 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20795 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32764 55
ATK CHEMICAL COMPANY LIMITED
+86 21 5161 9050/ 5187 7795
+86 21 5161 9052/ 5187 7796 ivan@atkchemical.com CHINA 14297 60
AB PharmaTech,LLC
323-480-4688
323-480-4688 sales01@abpharmatechusa.com United States 991 55
Kono Chem Co., Ltd
+86-132 8924 6953
info@konochemical.com CHINA 2164 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 20001 58
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30308 84
Puyang Huicheng Electronic Material Co. Ltd. 0086-393-8910800
0086-393-8912775 info@huichengchem.com China 376 64
Henan Tianfu Chemical Co.,Ltd. 0371-55170693/55170694/55170695/55170691
0371-55170690/55170692 admin@tianfuchem.com China 4725 55

View Lastest Price from 1,1'-Bis(diphenylphosphino)ferrocene manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-08-09 1,1'-Bis(diphenylphosphino)ferrocene
12150-46-8
US $1.00 / KG 1KG 99% 1000KG career henan chemical co

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