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Diisopropyl peroxydicarbonate

CAS No.
105-64-6
Chemical Name:
Diisopropyl peroxydicarbonate
Synonyms
Peroyl IPP;Luperox IPP;Perkadox IPP;ISOPROPYLPERCARBONATE;Isopropyl peroxycarbonate;Isopropyl Peroxydicarbonate;diisopropyl peroxydiformate;Diisopropylperoxydicarbonat;Diisopropyl peroxydicabonate;Diisopropyl peroxydicarbonate
CBNumber:
CB2851684
Molecular Formula:
C8H14O6
Molecular Weight:
206.19
MDL Number:
MFCD01708854
MOL File:
105-64-6.mol
MSDS File:
SDS
Last updated:2023-05-04 15:16:10

Diisopropyl peroxydicarbonate Properties

Melting point 12°C
Boiling point 265.04°C (rough estimate)
Density 1.080
vapor pressure 17.1hPa at 20℃
refractive index 1.4034
Odor Disagreeable; pungent.
Water Solubility 30.5mg/L at 20℃
Exposure limits No exposure limit is set. Because of low toxicity and vapor pressure, the health hazard from its exposure does not arise.
Stability Shock-sensitive. Highly reactive. Heat sensitive. May explode or ignite in contact with organic material.
LogP 2.73 at 25℃
Indirect Additives used in Food Contact Substances ISOPROPYL PEROXYDICARBONATE
FDA 21 CFR 175.105; 176.170
EWG's Food Scores 1
FDA UNII MF2YWK190R
EPA Substance Registry System Peroxydicarbonic acid, C,C'-bis(1-methylethyl) ester (105-64-6)

SAFETY

Risk and Safety Statements

Diisopropyl peroxydicarbonate price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Biosynth Carbosynth FD152046 Diisopropylperoxydicarbonate 105-64-6 100mg $58 2021-12-16 Buy
Biosynth Carbosynth FD152046 Diisopropylperoxydicarbonate 105-64-6 250mg $115 2021-12-16 Buy
Biosynth Carbosynth FD152046 Diisopropylperoxydicarbonate 105-64-6 500mg $200 2021-12-16 Buy
Biosynth Carbosynth FD152046 Diisopropylperoxydicarbonate 105-64-6 1g $350 2021-12-16 Buy
American Custom Chemicals Corporation CHM0967696 DIISOPROPYL PEROXYDICARBONATE 95.00% 105-64-6 5MG $500.82 2021-12-16 Buy
Product number Packaging Price Buy
FD152046 100mg $58 Buy
FD152046 250mg $115 Buy
FD152046 500mg $200 Buy
FD152046 1g $350 Buy
CHM0967696 5MG $500.82 Buy

Diisopropyl peroxydicarbonate Chemical Properties,Uses,Production

Chemical Properties

White crystalline solid with a mild characteristicodor; mp 8–10°C (46.4–50°F); density1.080 at 15°C (59°F); slightly soluble inwater, 0.04% at 25°C (77°F), soluble in ether,chloroform, benzene, hexane, and isooctane.

Uses

It is used as a catalyst to initiate polymerizationreactions to produce polymers fromethylene, styrene, vinyl acetate, vinyl chloride,and vinyl esters. Polymers of increasedlinearity and better properties can be obtainedby optimizing its concentration, temperature,and pressure conditions.

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 1254, 1950 DOI: 10.1021/ja01159a052

General Description

A white solid (shipped packed in Dry Ice to stabilize) with a sharp unpleasant odor. Insoluble in sater and sinks in water. Used as polymerization catalyst.

Air & Water Reactions

Highly flammable. Insoluble in water. Spontaneous decomposition at room temperature releases flammable toxic products.

Reactivity Profile

ISOPROPYL PEROXYDICARBONATE decomposes violently or explosively at temperatures 0-10°C owing to self- accelerating exothermic decomposition; Several explosions were due to shock, heat, or friction; amines and certain metals can cause accelerated decomposition [Bretherick 1979 p. 156]. Spontaneous decomposition possible at room temperature to release flammable and corrosive products (presence of stabilizer reduces this possibility). A strong oxidizing agent. May ignite organic compounds on contact, hence a fire risk. Strongly reduced material such as sulfides, nitrides, and hydrides can react explosively. Reacts at least to produce heat when mixed with members of most chemical classes. These reactions often generate gases (toxic and nontoxic). Subject to decomposition, buildup of heat and even an explosion if contaminated with a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium or a salt of a transition metal).

Health Hazard

Inhalation overexposure unlikely, but prolonged exposure may cause lung edema. Contact with eyes may cause irritation. Solutions are severe primary skin irritants.

Health Hazard

Diisopropyl peroxydicarbonate is a moderateskin irritant. The irritation can be severe onrabbit skin. Eye contact can cause conjunctivitisand corneal ulcerations, which, however,are fully recoverable in 1–2 weeks. Itstoxicity is very low. There is no report of itsill effect on humans. It may cause dermatitison sensitive skin.
LD50 value, oral (rats): 21,410 mg/kg.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: May decompose with the formation of oxygen when in contact with metals; Stability During Transport: Unstable at temperatures above 0°F with the formation of oxygen gas; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

Moderately toxic by ingestion and skin contact. A severe eye irritant. Very dangerous fire hazard. Dangerously unstable above 10°C. An impactand heat-sensitive explosive. Solutions may spontaneously explode (the hazard increases with concentration). Storage in sealed containers map be dangerous. Explodes on contact with amines or potassium iodide. May explode on contact with organic matter. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, ORGANIC

Waste Disposal

Larger quantities can be disposed of by scatteringin a disposal area where it melts andgradually decomposes. Small quantities aredestroyed by adding slowly to 5% alcoholicKOH. Solutions in small amount may be disposedof in porous sandy soils.

Diisopropyl peroxydicarbonate Preparation Products And Raw materials

Global( 37)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
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CONIER CHEM AND PHARMA LIMITED
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career henan chemical co
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Dayang Chem (Hangzhou) Co.,Ltd.
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CD Chemical Group Limited
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Henan Alfa Chemical Co., Ltd
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ShanDong Look Chemical Co.,Ltd.
+8617653113219 sales01@sdlookchemical.com China 2739 58

View Lastest Price from Diisopropyl peroxydicarbonate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Diisopropyl peroxydicarbonate pictures 2020-03-06 Diisopropyl peroxydicarbonate
105-64-6
US $1.00 / KG 1KG 99% 200kgs Career Henan Chemical Co
Diisopropyl peroxydicarbonate bisisopropyl peroxydicarbonate Isopropyl Peroxydicarbonate Isopropyl peroxycarbonate Peroxydicarbonic acid, diisopropyl ester ISOPROPYLPERCARBONATE Diisopropylperoxydicarbonat diisopropyl peroxydiformate Peroxydicarbonic acid, bis(1-methylethyl) ester Diisopropyl peroxydicabonate diisopropyl peroxydicarbonate, <= 52% solution diisopropyl peroxydicarbonate, technical pure Luperox IPP Perkadox IPP Peroyl IPP Propan-2-yl propan-2-yloxycarbonyloxy carbonate [α,β-Peroxy]dicarbonic acid diisopropyl Isopropoxyformic acid isopropoxyperformic anhydride Peroxybis(formic acid isopropyl) ester carbonic acid isopropoxycarbonyloxy isopropyl ester propan-2-yl propan-2-yloxycarbonyloxy carbonate[52% < content ≤100%] Diisopropyl peroxydicarbonate[content ≤52%, with type B diluent ≥48%] Diisopropyl peroxydicarbonate[content ≤32%, with type A diluent ≥68%] Peroxydicarbonic acid, C,C'-bis(1-methylethyl) ester 105-64-6 C3H7OCOO2