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Diethylenetriamine

Diethylenetriamine
Diethylenetriamine structure
CAS No.
111-40-0
Chemical Name:
Diethylenetriamine
Synonyms
DETA;DIEN;chs-p1;ChS-P 1;Epicure T;D.E.H. 20;D.E.H. 52;D.E.H. 58;Barsamide 115;Texacure EA-20
CBNumber:
CB2852838
Molecular Formula:
C4H13N3
Formula Weight:
103.17
MOL File:
111-40-0.mol

Diethylenetriamine Properties

Melting point:
-40 °C
Boiling point:
206 °C
Density 
0.955 g/mL at 25 °C(lit.)
vapor density 
3.6 (vs air)
vapor pressure 
0.08 mm Hg ( 20 °C)
refractive index 
n20/D 1.484(lit.)
Flash point:
90 °C
storage temp. 
Store below +30°C.
form 
Liquid
pka
pK1:4.42(+3);pK2:9.21(+2);pK3:10.02(+1) (25°C)
color 
Clear
Odor
Strong ammoniacal; mildly ammoniacal.
PH
>12 (100g/l, H2O, 20℃)
explosive limit
1-10%(V)
Water Solubility 
miscible
Sensitive 
Air Sensitive
BRN 
605314
Stability:
Stable, but absorbs carbon dioxide from the air. Incompatible with strong oxidizing agents, copper and its alloys.
InChIKey
RPNUMPOLZDHAAY-UHFFFAOYSA-N
CAS DataBase Reference
111-40-0(CAS DataBase Reference)
NIST Chemistry Reference
1,2-Ethanediamine, N-(2-aminoethyl)-(111-40-0)
EPA Substance Registry System
1,2-Ethanediamine, N-(2-aminoethyl)-(111-40-0)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  C,T+
Risk Statements  21/22-34-43-37-26
Safety Statements  26-36/37/39-45-28
RIDADR  UN 2079 8/PG 2
WGK Germany  2
RTECS  IE1225000
Autoignition Temperature 676 °F
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29212900
Hazardous Substances Data 111-40-0(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 1540 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H312 Harmful in contact with skin Acute toxicity,dermal Category 4 Warning P280,P302+P352, P312, P322, P363,P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Sensitisation, respiratory Category 1 Danger P261, P285, P304+P341, P342+P311,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H360 May damage fertility or the unborn child Reproductive toxicity Category 1A, 1B Danger
H402 Harmful to aquatic life Hazardous to the aquatic environment, acute hazard Category 3
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

NFPA 704

Diamond Hazard Value Description
1
3 0
HEALTH   3 Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
FIRE  1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
REACT   0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
SPEC. HAZ. 

(NFPA, 2010)

Diethylenetriamine price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich D93856 Diethylenetriamine ReagentPlus , 99% 111-40-0 1l $61.5 2018-11-13 Buy
Sigma-Aldrich D93856 Diethylenetriamine ReagentPlus , 99% 111-40-0 2.5l $117 2018-11-13 Buy
TCI Chemical D0493 Diethylenetriamine >98.0%(GC)(T) 111-40-0 25mL $16 2018-11-22 Buy
TCI Chemical D0493 Diethylenetriamine >98.0%(GC)(T) 111-40-0 500mL $26 2018-11-22 Buy
Alfa Aesar A11033 Diethylenetriamine, 99% 111-40-0 500ml $28.5 2018-11-13 Buy

Diethylenetriamine Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Production Methods

Diethylenetriamine is produced by the reaction of ethylene dichloride with ammonia.

General Description

A yellow liquid with an ammonia-like odor. Less dense than water. Corrosive to metals and tissue. Vapors heavier than air. Burns, although possibly difficult to igntie. Toxic oxides of nitrogen produced during combustion. Used as a solvent for plastics and dyes and in chemical synthesis.

Air & Water Reactions

Soluble in water.

Reactivity Profile

Diethylenetriamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

Prolonged breathing of vapors may cause asthma. Liquid burns skin and eyes. A skin rash can form.

Health Hazard

Brief contact with concentrated diethylenetriamine can produce severe local injury to the eyes and skin resembling the effect from strong base. Human subjects are susceptible to sensitization responses either as dermatitis or an asthma-like response. A time-weighted average of 1 p.p.m. is recommenced for diethylenetriamine (ACGIH 1986).

Fire Hazard

Flash Point (°F): 200 ℃; Flammable Limits in Air (%): 1-10; Fire Extinguishing Agents: Water spray, alcohol foam, carbon dioxide, or dry chemical; Fire Extinguishing Agents Not To Be Used: Water or foam may cause frothing; Special Hazards of Combustion Products: Irritating vapors are generated when heated; Behavior in Fire: Not pertinent; Ignition Temperature (°F): 676; Electrical Hazard: Not pertinent; Burning Rate: Data not available.

Fire Hazard

Special Hazards of Combustion Products: Irritating vapors are generated when heated.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No hazardous reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Flush with water; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Industrial uses

Diethylenetriamine is used as an intermediate in the production of reactive polyamide resins, and in the production of aminoamides and imidazolines from fatty acids. It is also used in the production of paper wet strength resins and piperazine. Diethylenetriamine serves as a solvent for sulfur, acid gases, resins and dyes (HSDB 1989).

Contact allergens

Diethylenetriamine is a hardener in epoxy resins of the Bisphenol A type. It has been reported to be a sensitizer when used in an ultrasonic bath for cleaning jewels, in synthetic lubricants, or in carbonless copy paper.

Safety Profile

Poison by skin contact and intraperitoneal routes. Moderately toxic by ingestion. Corrosive. A severe skin and eye irritant. High concentration of vapors causes irritation of respiratory tract, nausea, and vomiting. Repeated exposures can cause asthma and sensitization of skin. Combus uble when exposed to heat or flame; can react with oxidizing materials. Mxture with nitromethane is a shock-sensitive explosive. Ignites on contact with cellulose nitrate of high surface area. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.

Metabolism

Diethylenetriamine is readily absorbed through the gastrointestinal tract and 96% of the administered dose is excreted within 48 h (USEPA 1983a). Roughly equal amounts are excreted in the feces and urine with at least 4 metabolites being detected (but not identified) in the latter. Only a small proportion (<2%) was recovered as expired carbon dioxide. Any residual remaining in the animal was found primarily in kidney, liver, bladder and large intestine.

Purification Methods

Dry the amine with Na and distil, preferably under reduced pressure, or in a stream of N2. [Beilstein 4 IV 1284.]

Diethylenetriamine Preparation Products And Raw materials

Raw materials

Preparation Products


Diethylenetriamine Suppliers

Global( 221)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22043 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20786 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32651 55
Hangzhou FandaChem Co.,Ltd.
0086 158 5814 5714 (Mobile; WhatsApp; Telegram)
+86-571-56059825 fandachem@gmail.com CHINA 2444 55
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 24118 58
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20243 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19997 58
Shanghai Chen Yu Chemical Co., Ltd. 13012824065
021-60488310 121597535@qq.com China 166 58
Jinan Century Tongda Chemical Co., Ltd. 13370556116 0531-58051019
3350933950@qq.com China 27 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76

View Lastest Price from Diethylenetriamine manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-08-03 Diethylenetriamine
111-40-0
US $1.00 / KG 1KG 99% 200KG career henan chemical co

Diethylenetriamine Spectrum


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